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CAS Number 360575-28-6

Chemistry Building Blocks, Fluorinated Building Blocks, Materials, Monomers

Product Code B2381-5g
Price $125 ex. VAT

A fluorinated benzaldehyde derivative

A multi-functional building block for synthesizing ligands, bicyclic heterocycles and semiconductors

Specifications | MSDS | Literature and Reviews

2-Bromo-6-fluorobenzaldehyde (CAS number 360575-28-6) is a benzaldehyde substituted with a bromine and a fluorine at the ortho-positions. A 1H and 19F NMR probe, fluoro-2-formyphenyl boronic acid is synthesized from 2-bromo-6-fluorobenzaldehyde. The NMR probe can determine the enantiopurity of sulfinamides that are widely used as chiral auxiliaries for asymmetric synthesis. 2-Bromo-6-fluorobenzaldehyde is used to synthesize bicyclic heterocycles such as indazoles, through a reaction of 2-bromo-6-fluorobenzaldehyde, primary amines and sodium azide, catalysed by copper(II) oxide.

2-Bromo-6-fluorobenzaldehyde can assist self-assembly of macromolecules to fabricate nanostructures. A semiconducting thienisoindigo based nanowire is assembled with 2-bromobenzaldehyde via halogen and chalcogen bonding, showing hole mobility of 6.39×10−4 cm2/Vs.

Multiple functional groups

Multiple functional groups

For facile synthesis

Fluorinated building block

Fluorinated benzaldehyde building block

For drug discovery, NMR probes and semiconducting materials

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High purity 360575-28-6

High purity

>97% High purity

General Information

CAS Number 360575-28-6
Chemical Formula C7H4BrFO
Full Name 2-Bromo-6-fluorobenzaldehyde
Molecular Weight 203.01 g/mol
Synonyms 6-Bromo-2-fluorobenzaldehyde, 2-Fluoro-6-bromobenzaldehyde
Classification / Family Fluorinated building blocks, Benzaldehyde building block, Ligands, NMR probes, Semiconductors

Chemical Structure

2-Bromo-6-fluorobenzaldehyde chemical structure, CAS 360575-28-6
2-Bromo-6-fluorobenzaldehyde chemical structure, CAS 360575-28-6

Product Details

Purity 97%
Melting Point Tm = 43  47 °C
Appearance Beige powder

MSDS Documentation

2-Bromo-6-fluorobenzaldehyde2-Bromo-6-fluorobenzaldehyde MSDS Sheet

Literature and Reviews

  1. Thienoisoindio-based semiconductor nanowires assembled with 2-bromobenzaldehyde via both halogen and chalcogen bonding, Sci. Rep., 8, 1488(2018); DOI: 10.1038/s41598-018-32486-z.
  2. A combined kinetico-mechanistic and computational study on the competitive formation of seven versus five-membered platinacycles; the relevance of spectator halide ligands, G. Aullón et al., Dalton Trans., 44, 17968–17979(2015); DOI: 10.1039/C5DT02657A.
  3. A three-component derivatization protocol for determining the enantiopurity of sulfinamindes by1H and 19F NMR spectroscopy, R. Groleau et al., J. Org. Chem., 85, 1208–1215(2020); DOI: 10.1021/acs.joc.9b02473.
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