p-6FDAP

CAS Number 129197-38-2

Chemistry Building Blocks, COF Ligands, Diamines and Dianhydrides, Fluorinated Building Blocks, Monomers, Porous Organic Frameworks

MSDS

A fluorinated diamine intermediate

For the synthesis of polyimides in application of telecommunication and high-performance polymers

Overview
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2,2-Bis[3-(4-aminobenzamido)-4-hydroxyphenyl]hexafluoropropane (CAS number 129197-38-2), known as p-6FDAP, has two terminal aminobenzamides linked to a bis(dihydroxyphenyl)hexafluoropropane. p-6FDAP is commonly used for synthesizing polyimides, especially those with low dielectric constant. A pedant group, such as biphenyl can be easily attached to the polymer backbone with the unreacted hydroxy groups. The molecular design is to obtain extra volume in bulk by the secondary relaxation behaviour of the polymers. Therefore, the dielectric constant of the grafted polyimides can reach 2.09 with dielectric loss of 0.0012 at 10 kHz. The grafted polyimides derived from p-6FDAP are ideal for telecommunication applications.

p-6FDAP based polyimides can be further functionalized by polymerizable groups, for instance acrylate, allowing they to be crosslinked for higher thermal resistance (5% decomposition temperature from 455 °C to 491 °C)

Multiple functional groups

For facile synthesis

Fluorinated diamine building block

For high-performance polymers, COFs, and polyamides

Worldwide shipping

Quick and reliable shipping

High purity

>99% High purity

General Information

CAS Number	129197-38-2
Chemical Formula	C₂₉H₂₂F₆N₄O₄
Full Name	2,2-Bis[3-(4-aminobenzamido)-4-hydroxyphenyl]hexafluoropropane
Molecular Weight	604.51 g/mol
Synonyms	4-Amino-N-[5-[2-[3-[(4-aminobenzoyl)amino]-4-hydroxyphenyl]-1,1,1,3,3,3-hexafluoropropan-2-yl]-2-hydroxyphenyl]benzamide, N,N'-((Perfluoropropane-2,2-diyl)bis(6-hydroxy-3,1-phenylene))bis(4-aminobenzamide)
Classification / Family	Fluorinated building blocks, Diamine building blocks, Polyimides, Telecommunication, High-performance polymers

Chemical Structure

Product Details

Purity	>99%
Melting Point	Not Known
Appearance	White powder/crystal

MSDS Documentation

p-6FDAP MSDS Sheet

Literature and Reviews

Facile strategy for intrinsic low-k dielectric polymers: molecular design based on secondary relaxation behavior, C. Qian et al., Macromolecules, 52(12), 4601–4609(2019); DOI: 0.1021/acs.macromol.9b00136.
Composite ferroelectric coating based on a heat-resistant polybenzoxazole polymer matrix, N. Mukhin et al., Coatings, 10, 286(2020); DOI: 10.3390/coatings10030286.
Low dielectric constant polymers for high speed communication network, L. Wang et al., Advanced Industrial and Engineering Polymer Research, 3, 138-148(2020); DOI: 10.1016/j.aiepr.2020.10.001.
Ultra-low-modulus photosensitive polybenzoxazole systems, J. Ishii et al., J. Photopolym. Sci. Technol., 28(2), 207-213(2015); DOI: 10.2494/photopolymer.28.206.

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