Luminosyn™ Polymers
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The Luminosyn™ range by Ossila offers high-purity, batch-specific polymer semiconductor materials. By using scale-up synthesis, our collection provides consistency and reliability between experiments through access to larger batches of materials. Eliminate the inconsistency and inconvenience of obtaining different batches from different suppliers and, with a lower cost of synthesis, access materials at highly competitive prices.
Key Features and Applications
To ensure high purity, Luminosyn™ materials undergo several days of Soxhlet extraction. Under inert atmospheric conditions, they are washed repeatedly with non-solvents and solvents. They also undergo multiple precipitations to reduce oligomers, metal residues, and low molecular weight fractions.Suitable for OLED, OFET, OPV, and perovskite solar cell research applications.Our Luminosyn™ materials come with precise molecular weights for each batch. This allows you to better optimize and understand your experiments, providing a more reliable reference for those that follow your published procedures. Plus large batch orders make it possible to conduct your research using materials from the same batch.To suit a variety of research needs, some Luminosyn™ polymers are available in higher molecular weights.Browse Luminosyn™ Polymers
More on Our Luminosyn™ Polymers
Headed by Ossila’s Senior Synthetic Organic Chemist, Dr. Hunan Yi, the origin of the Luminosyn™ range began in 2015 with the scale-up synthesis of two popular photovoltaic materials, PCDTBT and DPP-DTT. Since then, we have extended the scale-up synthesis of polymer semiconductors to include higher-performance OPV materials such as PCE10 (PBDTTT-EFT), PCE11 (PffBT4T-2OD), and PCE12 (PBDB-T). We will continue to add more polymers to this range, including some of the most popular polymers already in our full range of polymers so look out for the Luminosyn™ name.
HOMO and LUMO of Luminosyn™ Polymers
The HOMO and LUMO of Luminosyn™ Polymers can play a major factors when selecting components. See the figures below for the (literature) reported HOMO and LUMO levels for our Luminosyn™ Polymers:
| Materials | HOMO | Band Gap (Eg) | LUMO | Soluble In |
| PNDI-T10 (PCE9) | -6.4 eV | 2.3 | -4.1 eV | Chloroform, chlorobenzene and dichlorobenzene |
| PNF222 | -5.99 eV | 2.09 | -3.9 eV | Chloroform, chlorobenzene and dichlorobenzene |
| Poly(9-vinylcarbazole) (PVK) | -5.8 eV | 3.6 | -2.2 eV | THF, o-xylene, chloroform, chlorobenzene and dichlorobenzene |
| PNDI(2OD)2T | -5.77 eV | 1.93 | -3.84 eV | Chloroform, chlorobenzene and dichlorobenzene |
| TQ1 (PTQ1) | -5.7 eV | 2.4 | -3.3 eV | Chloroform, chlorobenzene and dichlorobenzene |
| PClTO2 | -5.66 eV | 2.25 | -3.41 eV | THF, o-xylene, chloroform, chlorobenzene and dichlorobenzene |
| PNDI(2HD)T | -5.64 eV | 1.85 | -3.79 eV | Chloroform, chlorobenzene and dichlorobenzene |
| PBDB-TCl-T1 | -5.59 eV | 2.09 | -3.5 eV | o-xylene, chloroform, chlorobenzene and dichlorobenzene |
| PBDTTPD | -5.56 eV | 1.81 | -3.75 eV | Chloroform, chlorobenzene and dichlorobenzene |
| PTO2 | -5.56 eV | 1.89 | -3.67 eV | THF, o-xylene, chloroform, chlorobenzene and dichlorobenzene |
| D18-Cl | -5.56 eV | 2.78 | -2.78 eV | THF, o-xylene, chloroform, chlorobenzene and dichlorobenzene |
| PNDIT-F3N | -5.55 eV | 1.64 | -3.91 eV | Methanol (typically 0.5 mg/ml in methanol with 0.5% vol acetic acid) |
| PTQ10 | -5.54 eV | 2.56 | -2.98 eV | o-xylene, chloroform, chlorobenzene and dichlorobenzene |
| PBDB-T-2Cl (PM7) | -5.52 eV | 1.95 | -3.57 eV | Chloroform, chlorobenzene and dichlorobenzene |
| PTQ11 | -5.52 eV | 2.76 | -2.76 eV | o-xylene, chloroform, chlorobenzene and dichlorobenzene |
| D18 | -5.51 eV | 2.74 | -2.77 eV | o-Xylene, chloroform, chlorobenzene and dichlorobenzene |
| F8T2 | -5.5 eV | 2.4 | -3.1 eV | o-Xylene, chloroform, chlorobenzene and dichlorobenzene |
| PBDTTTPD | -5.49 eV | 2.02 | -3.47 eV | Chloroform, chlorobenzene and dichlorobenzene |
| PBDB-TF-T1 | -5.48 eV | 1.85 | -3.63 eV | o-Xylene, chloroform, chlorobenzene and dichlorobenzene |
| PBDB-T-2F (PM6) | -5.45 eV | 1.8 | -3.65 eV | o-xylene, chloroform, chlorobenzene and dichlorobenzene |
| P5TCN-F25 | -5.44 eV | 1.79 | -3.65 eV | Chloroform, chlorobenzene and dichlorobenzene |
| PBQx-TF (PCE19) | -5.41 eV | 2.59 | -2.82 eV | Chloroform, chlorobenzene and dichlorobenzene |
| PCDTBT | -5.4 eV | 1.8 | -3.6 eV | Chloroform, chlorobenzene, dichlorobenzene and trichlorobenzene |
| PJ71 | -5.4 eV | 2.16 | -3.24 eV | Chloroform, chlorobenzene and dichlorobenzene |
| PF8Cz | -5.4 eV | 3.1 | -2.3 eV | THF, Toluene, o-xylene, and Chloroform |
| PBDD4T-2F | -5.39 eV | 1.76 | -3.63 eV | Chloroform, chlorobenzene, dichlorobenzene |
| J52-Cl | -5.38 eV | 1.94 | -3.44 eV | Chloroform, chlorobenzene and dichlorobenzene |
| P4T2F-HD | -5.35 eV | 1.92 | -3.43 eV | Chloroform, chlorobenzene and dichlorobenzene |
| PBDB-T (PCE12) | -5.33 eV | 2.41 | -2.92 eV | Chloroform, chlorobenzene and dichlorobenzene |
| PBDTT-DPP | -5.3 eV | 1.67 | -3.63 eV | Chloroform, chlorobenzene and dichlorobenzene |
| PBDD4T (PBT1) | -5.3 eV | 1.76 | -3.54 eV | Chloroform, chlorobenzene and dichlorobenzene |
| PDCBT | -5.26 eV | 2.26 | -3 eV | Chloroform, chlorobenzene and dichlorobenzene |
| PTB7-Th (PCE10, PBDTTT-EFT) | -5.24 eV | 1.58 | -3.66 eV | Chloroform, chlorobenzene and dichlorobenzene |
| J52 | -5.21 eV | 2.22 | -2.99 eV | Chloroform, chlorobenzene and dichlorobenzene |
| PDPP4T | -5.2 eV | 1.2 | -4 eV | Chloroform |
| DPP-DTT (PDPP2T-TT-OD) | -5.2 eV | 1.7 | -3.5 eV | o-xylene, chloroform, chlorobenzene and dichlorobenzene |
| PolyTPD | -5.2 eV | 2.9 | -2.3 eV | THF, o-xylene, toluene, chloroform and chlorobenzene |
| PDPP3T | -5.17 eV | 1.56 | -3.61 eV | Toluene, chloroform, chlorobenzene and dichlorobenzene |
| PTB7 | -5.15 eV | 1.84 | -3.31 eV | Chloroform, Chlorobenzene and Dichlorobenzene |
| PBBTSiD | -4.8 eV | 0.7 | -4.1 eV | Chloroform, chlorobenzene and dichlorobenzene |
| PBBTCD | -4.8 eV | 0.8 | -4 eV | Chloroform, chlorobenzene and dichlorobenzene |
| P(g2T-TT) | -4.61 eV | 1.74 | -3 eV | DMF, Chloroform (typically 5 mg/ml in chloroform) |
|
P(g2T-T) |
-4.38 eV | 1.73 | -2.65 eV | DMF, Chloroform (typically 5 mg/ml in chloroform) |
Energy levels and energy gaps are taken from the literature and are provided for reference only. Reported values vary with measurement method (e.g. cyclic voltammetry, photoelectron spectroscopy, optical absorption) and sample conditions, so they should be treated as indicative.