PNDI-T10, PCE9

CAS Number 1977539-03-9

Luminosyn™ Polymers, Materials, OFET & OLED Polymer Materials, OPV Polymers, Semiconducting Polymers

PNDI-T10, polymer acceptor for high-efficiency all-PSCs and OFETs

High purity polymer with high electron mobility

Specifications | MSDS | Literature and Reviews

PNDI-T10 (also known as PCE9), CAS number 1977539-03-9, is a polymer acceptor used in high-efficiency all-polymer solar cells (all-PSCs) and organic field-effect transistors (OFETs).

PNDI-T10 is a family member of polynaphthalene diimide (which is a copolymer of naphthalene diimide with bithiophene and thiophene unit.)

All-PSCs have received great research interest in recent years. This is thanks to the blend of both electron donor and acceptor being polymers in the active layer, and how having complementary absorption covers a wider range of the solar spectrum. Using polymer acceptors (instead of fullerene) in all-PScs also has the advantages of greater morphological stability, superior mechanical properties, and higher capability of being processed with ink-jet printing techniques in flexible devices.

PNDI-T10 has been successfully used in ternary all-PSCs, achieving record performances with PCE of 9% [1]. PNDI-T10 is also a potential candidate for high performance OFET with high electron mobility.

Luminosyn™ PNDI-T10

Luminosyn™ PNDI-T10 is now available.

High molecular weight and high purity

PNDI-T10 is purified by Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere

Large quantity orders

Plan your experiments with the confidence of polymers from the same batch

General Information

Full name	Poly{{[N,N'-bis(2-octyldodecyl)naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-5,5'-(2,2'-bithiophene)}-ran-{[N,N'-bis(2-octyldodecyl)naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-2,5-thiophene}}
Synonyms	PCE9, PNDI-Th10, PNDI(2OD)-T10
Chemical formula	(C₆₂H₈₈N₂O₄S₂)_0.9 ▪ (C₅₈H₈₆N₂O₄S)_0.1
CAS number	1977539-03-9
HOMO / LUMO	HOMO = -6.40 eV, LUMO = -4.10 eV [1]
Classification / Family	PNDI polymers, Organic n-type semiconducting materials, PNDI polymers, Organic photovoltaics, All Polymer solar cells (all-PSCs), Electron-acceptor polymers, OFETs, Perovskite solar cells.
Soluble in	Chloroform, chlorobenzene, dichlorobenzene
Recommended Processing Solvents at 10mg/ml	Chloroform

Batch Details

Batch	M_w	PDI	Stock Info
M2086A1	189,514	2.40	Discontinued
M2086A2	103,047	2.08	In stock

Chemical Structure

pndi-t10, 1977539-03-9 — Chemical structure of PNDI-T10, CAS 1977539-03-9

MSDS Documentation

PNDI-T10 MSDS sheet

Literature and Reviews

9.0% power conversion efficiency from ternary all-polymer solar cells, Z. Li et al., Energy Environ. Sci., 10, 2212 (2017); DOI: 10.1039/c7ee01858d.
High Performance All-Polymer Solar Cells by Synergistic Effects of Fine-Tuned Crystallinity and Solvent Annealing, Z. Li et al., J. Am. Chem. Soc., 138 (34), 10935–10944 (2016); DOI: 10.1021/jacs.6b04822.
Energy-effectively printed all-polymer solar cells exceeding 8.61% efficiency, Y. Lin et al., Nano Energy 46, 428-435 (2018); https://doi.org/10.1016/j.nanoen.2018.02.035.

High-performance all-polymer solar cells based on fluorinated naphthalene diimide acceptor polymers with fine-tuned crystallinity and enhanced dielectric constants, X. Xu et al., Nano Energy 45, 368-379 (2018); https://doi.org/10.1016/j.nanoen.2018.01.012.
High‐Performance and Stable All‐Polymer Solar Cells Using Donor and Acceptor Polymers with Complementary Absorption, Z. Li et al., Adv. Energy Mater., 7 (14), 201602722 (2017); https://doi.org/10.1002/aenm.201602722
Effects of incorporating different chalcogenophene comonomers into random acceptor terpolymers on the morphology and performance of all-polymer solar cells, Y. An et al., Polym. Chem., 9, 593-602 (2018); DIO:10.1039/C7PY01907F.