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Product Code M2282A1-100mg
Price $500 ex. VAT

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PBDB-TCl-T1, used to achieve high open voltages in polymer solar cell devices

High quality and available for fast, secure dispatch


PBDB-TCl-T1 is a cholorinated version of PBDB-TF-T1 which obtains better solubility in non-halogenated solvents, i.e. o-xylene while still maintaining high device performance efficiencies over 16%.

Comparing with PBDB-TF-T1, both HOMO and LUMO energy levels of PBDB-TCl-T1 should be lowered due to the fact that electron density can be delocalised more effectively to the chlorine atom than the fluorine atom on the BDT (benzodithiophene) backbone unit. Higher open voltage can thus be expected PBDB-TCl-T1 in polymer solar cell devices.

PBDB-TCl-T1 was first developed at Ossila as part of Green Energy Materials project for polymer semiconducting materials to be processed in larger area in non-halogenated solvents by inkjet printing or doctor blade techniques.

Conjugated semiconducting polymer

Conjugated semiconducting polymer

For high efficient OPV applications

Luminosyn™

Luminosyn™

High purity, batch-specific GPC data, available larger batch orders and higher molecular weight

Worldwide shipping for PBDB-TCl-T1

Worldwide shipping

Quick and reliable shipping

Green energy material

Green energy materials

Processable in non-halogenated solvents

Luminosyn™ PBDB-TCl-T1

Luminosyn™ PBDB-TCl-T1 is now available.

High purity

PBDB-TCl-T1 is purified by Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere

Batch-specific GPC data

Batch specific GPC data is always available for your thesis or publication

Large-quantity orders

Plan your experiments with confidence with polymers from the same batch

General Information

Full name Poly[(2,6-(4,8-bis(5-(2-ethylhexyl-3-chloro)thiophen-2-yl)-benzo[1,2-b:4,5-b’]dithiophene))-alt-(5,5-(1’,3’-di-2-thienyl-5’,7’-bis(2-ethylhexyl)benzo[1’,2’-c:4’,5’-c’]dithiophene-4,8-dione)]-ran-poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)-benzo[1,2-b:4,5-b’]dithiophene))-alt-(2,2-ethyl-3(or4)-carboxylate-thiophene)]
Synonyms T1-Cl
Chemical formula [(C68H76Cl2O2S8)0.8(C41H44F2O2S5)0.2]n
CAS number n.a.
HOMO / LUMO HOMO = -5.59 eV, LUMO = -3.50 eV (cyclic voltammetry measurement)
Solubility o-xylene, chloroform, chlorobenzene and dichlorobenzene
Processing solvent o-xylene, chloroform, chlorobenzene
Classification / Family Organic semiconducting materials, Medium band-gap polymers, Organic Photovoltaics, Polymer solar cells, NF-PSCs, All-polymer solar cells (all-pscs).

Chemical Structure

Chemical structure of PBDB-TCl-T1
Chemical structure of PBDB-TCl-T1

MSDS Documentation

PBDB-TCl-T1 MSDSPBDB-TCl-T1 MSDS sheet

Pricing

Batch Quantity Price
M2282A1 100 mg £400
M2282A1 250 mg £800
M2282A1 500 mg £1300
M2282A1 1 g £2400
M2282A1 5 g / 10 g* Please enquire

*for 5 - 10 grams order quantity, the lead time is 4-6 weeks.

Batch details

Batch Mw Mn PDI Stock Info
M2282A1 157,117 43,015 3.65 In stock

Literature and Reviews

  1. Achieving Over 15% Efficiency in Organic Photovoltaic Cells via Copolymer Design, Y. Cui et al., Adv. Mater., 31 (14), 1808356 (2019); DOI: 10.1002/adma.201808356.
  2. Eco-Compatible Solvent-Processed Organic Photovoltaic Cells with Over 16% Efficiency, L Hong et al., Adv. Mater., 31 (39), 1903441 (2019); DOI: 10.1002/adma.201903441.

Characterisations

UV-Vis Absorption

PBDB-TCl-T1 absorption and solubility in o-xylene
UV-Vis absorption of of PBDB-TCl-T1 in chlorobenzene (CB) and in film (as-cast film on glass) and its solubility in o-xylene at 8 mg/ml.

Cyclic Voltammetry

pbdb-tcl-t1 cyclic voltammetry study
Cyclic voltammograms of the PBDB-TCl-T1 film on platinum electrode in 0.1M Bu4NClO4 in acetonitrile at a scan rate of 100 mV s−1.

The cyclic voltammograms (CV) measurements were recorded on Ossila Potentiostat by using a three-electrode system with platinum disc as the working electrode, platinum wire as the counter electrode, Ag/Agelectrode as the reference electrode with a scanning rate of 100 mV/s in a 0.1 M tetrabutylammonium perchlorate (Bu4NClO4) solution. The potential of Ag/Ag+ reference electrode was internally calibrated by using ferrocene/ferroncenium (Fc/Fc+) as the redox couple.


To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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