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PBDB-TF-T1


Product Code M2259A1
Price £300.00

PBDB-TF-T1 is a randomly copolymerised conjugated semiconducting polymer with benzodithiophene (BDT), Benzodithiophene dione (BDD) and thiophene carboxylate ester as the main backbone units. PBDB-TF-T1 is a close relative in structure to PBDBT-2F (PM6) and PTO2, relatively blue shifted in absorption to PM6 and red shifted to PTO2.

PBDB-TF-T1 is also relatively more soluble in non-halogenated solvents, i.e. o-xylene, 1,2,4‐trimethylbenzene or THF than PM6. None-fullerene polymer solar cells with non-halogenated solvent additive DIO from BTP-4F-12 as acceptor and PBDB-TF-T1 as polymer donor achieved high device performance efficiencies of PCE = 16.1%.

Please refer to our collection of green energy materials for non-halogenated solvents processing choice of non-fullerene acceptors (NFAs).

Device structure: indium tin oxide (ITO)/PEDOT:PSS/T1:BTP-4F-12/PFN-Br/Al. [1]

Thickness (nm) VOC (V) JSC (mA cm-2) FF (%) PCE (%)
Not known 0.853 25.2 76 16.1

Luminosyn™ PBDB-TF-T1

Luminosyn™ PBDB-TF-T1 is now available.

High purity
PBDB-TF-T1 is purified by Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere

Batch-specific GPC data
Batch specific GPC data is always available for your thesis or publication

Large-quantity orders
Plan your experiments with confidence with polymers from the same batch

General Information

Full name Poly[(2,6-(4,8-bis(5-(2-ethylhexyl-3-fluoro)thiophen-2-yl)-benzo[1,2-b:4,5-b’]dithiophene))-alt-(5,5-(1’,3’-di-2-thienyl-5’,7’-bis(2-ethylhexyl)benzo[1’,2’-c:4’,5’-c’]dithiophene-4,8-dione)]-ran-poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)-benzo[1,2-b:4,5-b’]dithiophene))-alt-(2,2-ethyl-3(or4)-carboxylate-thiophene)]
Synonyms T1
Chemical formula [(C68H76F2O2S8)0.8(C41H44F2O2S5)0.2]n
CAS number n.a.
HOMO / LUMO HOMO = -5.48 eV, LUMO = -3.63 eV [1]
Solubility o-Xylene, chloroform, chlorobenzene and dichlorobenzene
Processing solvent o-Xylene, chloroform, chlorobenzene and dichlorobenzene
Classification / Family Organic semiconducting materials, Medium band-gap polymers, Organic Photovoltaics, Polymer solar cells, NF-PSCs, All-polymer solar cells (all-pscs).

Chemical Structure

pbdb-tf-t1 chemical structure and solubility in o-xylene

Chemical structure of PBDB-TF-T1 (T1) and its solubility in o-xylene.

    MSDS Documentation

    PBDB-TF-T1 MSDSPBDB-TF-T1 MSDS sheet

    Pricing

    Batch Quantity Price
    M2259A1 100 mg £300.00
    M2259A1 250 mg £600.00
    M2259A1 500 mg £1100.00
    M2259A1 1 g £2000.00
    M2259A1 5 g / 10 g* Please enquire

    *for 5 - 10 grams order quantity, the lead time is 4-6 weeks.

    Batch details

    Batch Mw Mn PDI Stock Info
    M2259A1 99,351 42,777 2.32 In Stock

    Literature and Reviews

    1. Achieving Over 15% Efficiency in Organic Photovoltaic Cells via Copolymer Design, Y. Cui et al., Adv. Mater., 31 (14), 1808356 (2019); DOI: 10.1002/adma.201808356.
    2. Eco-Compatible Solvent-Processed Organic Photovoltaic Cells with Over 16% Efficiency, L Hong et al., Adv. Mater., 31 (39), 1903441 (2019); DOI: 10.1002/adma.201903441..

    To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.