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Product Code M2150A11-100mg
Price $500 ex. VAT

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PM6, for high performance OPV devices

High purity and available for priority dispatch


PBDB-T-2F is a PBDB-T family member and, like others, has a high OPV device performance. Polymer solar cells with PBDB-T-2F as the donor and ITIC-2F as the acceptor have achieved a power conversion efficiency (PCE) of over 13%.

By introducing two fluorine atoms to each thiophene unit of the benzodithiophene (BDT) side chains in PBDB-T, the HOMO/LUMO energy levels are pulled. Complete phase separation is observed in the PBDB-T-2F:ITIC-2F blend due to the distinct surface tension difference between PBDB-T-2F and ITIC-2F, resulting in a high domain purity in the blend.

A certified efficiency of 14.9% has been demonstrated using PBDB-T-2F (PM6) as the electron donor and Y6 as an acceptor in a single junction non-fullerene polymer solar cell (NF-PSC) [2].

Conjugated semiconducting polymer

Conjugated semiconducting polymer

As electron donor for high efficient OPV applications

Luminosyn™

Luminosyn™

High purity, batch-specific GPC data, available larger batch orders and higher molecular weight

Worldwide shipping for 1802013-83-7

Worldwide shipping

Quick and reliable shipping

Green energy material

Green energy materials

Processable in non-halogenated solvents

Ossila's PBDB-T-2F used in a high-impact paper

PBDB-T-2F from Ossila was used in the high-impact paper (IF 18.81), Stretchable and Transparent Conductive PEDOT:PSS-Based Electrodes for Organic Photovoltaics and Strain Sensors Applications, E. Dauzon et al., Adv. Fun. Mater., 30 (28), 2001251 (2020); DOI: 10.1002/adfm.202001251.

Luminosyn™ PBDB-T-2F

Luminosyn™ PBDB-T-2F is now available.

High purity
PBDB-T-2F is purified via Soxhlet extraction with acetone, hexane, and chlorobenzene under an argon atmosphere

Large quantity orders
Plan your experiments with polymers from the same batch

General Information

Full name Poly[(2,6-(4,8-bis(5-(2-ethylhexyl-3-fluoro)thiophen-2-yl)-benzo[1,2-b:4,5-b’]dithiophene))-alt-(5,5-(1’,3’-di-2-thienyl-5’,7’-bis(2-ethylhexyl)benzo[1’,2’-c:4’,5’-c’]dithiophene-4,8-dione)]
Synonyms PBDB-T-F, PBDB-TF, PM6
Chemical formula (C68H76F2O2S8)n
CAS number 1802013-83-7
HOMO / LUMO HOMO = -5.45 eV, LUMO = -3.65 eV [1]
Processing solvents o-xylene, chloroform, chlorobenzene and dichlorobenzene
Classification / Family Organic semiconducting materials, Medium bandgap polymers, Organic photovoltaics, Polymer solar cells, Perovskite solar cells, Hole-transport layer materials, NF-PSCs, All-polymer solar cells (all-PSCs).

Chemical Structure

pbdb-t-2f, pbdb-t-f chemical structure
Chemical structure of PBDB-T-2F, CAS No. 2239295-71-5

MSDS Documentation

PBDB-T-2F MSDSPBDB-T-2F MSDS sheet

Pricing

Batch Quantity Price
M2150A 100 mg £400
M2150A 250 mg £800
M2150A 500 mg £1300
M2150A 1 g £2400

Batch details

Batch* Mw Mn PDI Stock Info
M2150A5 126,690 60,551 2.09 Discontinued
M2150A6 107,004 29,644 3.61 Discontinued
M2150A7 100,180 44,778 2.24 Discontinued
M2150A8 81,082 36,635 2.22 Discontinued
M2150A9 72,090 27,534 2.62 Discontinued
M2150A10 87,278 25,955 3.36 Discontinued
M2150A11 102,029 39,556 2.58 In stock

*Older batch information available on request.

Literature and Reviews

  1. Over 14% Efficiency in Organic Solar Cells Enabled by Chlorinated Nonfullerene Small-Molecule Acceptors, H. zhang et al., Adv.Mater., 30, 1800613 (2018); DOI: 10.1002/adma.201800613.
  2. Single-Junction Organic Solar Cell with over 15% Efficiency Using Fused-Ring Acceptor with Electron-Deficient Core, J. Yuan et al., Joule (2019); doi: 10.1016/j.joule.2019.01.004.
  3. Over 14% Efficiency in Polymer Solar Cells Enabled by a Chlorinated Polymer Donor, S. Zhang et al., Adv. Mater., 30, 1800868 (2018); DOI: 10.1002/adma.201800868.
  4. High efficiency non-fullerene organic solar cells without electron transporting layers enabled by Lewis base anion doping, R. Wang et al., Nano Energy 51, 736–744 (2018) ; doi: org/10.1016/j.nanoen.2018.07.022.
  5. Fluorination vs. chlorination: a case study on high performance organic photovoltaic materials, Y. Zhang et al., Sci. China Chem., 61 (10), 1328–1337 (2018); doi: 10.1007/s11426-018-9260-2.
  6. Highly Efficient Flexible Polymer Solar Cells with Robust Mechanical Stability, L. Tan et al., Adv. Sci., 1801180 (2019); DOI: 10.1002/advs.201801180 .
  7. 15% Efficiency Tandem Organic Solar Cell Based on a Novel Highly Efficient Wide‐Bandgap Nonfullerene Acceptor with Low Energy Loss, G. Liu et al., Adv. Energy Mater., 1803657 92019); DOI: 10.1002/aenm.201803657.

Technical Data

Product Code Soluble solvents Recommended Processing Solvents at 10mg/ml
M2150A4

Chloroform, chlorobenzene and dichlorobenzene

Chlorobenzene
M2150A5

Chlorobenzene and dichlorobenzene

Dichlorobenzene
M2150A7 Chloroform, chlorobenzene and dichlorobenzene

Dichlorobenzene or Chlorobenzene : dichlorobenzene (v/v = 1:1)

M2150A8/9/10

 

o-Xylene, chloroform, chlorobenzene and dichlorobenzene

o-Xylene (8 mg/ml), chloroform, chlorobenzene
M2150A11

Chloroform, chlorobenzene and dichlorobenzene

Chloroform, chlorobenzene
PBDB-TF solubility in o-xylene and chloroform
M2150A8 in o-Xylene (8 mg/ml) and in chloroform (10mg/ml)

For polymer with higher molecular weights, it is suggested that lower concentration should be used with lower spin-coating speed for solution processing.

UV-Vis Absorption

UV-Vis absorption of pbdb-t-2f-pm6 of different molecular weights
UV-Vis absorption of PBDB-T-2F of different molecular weights in film


To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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