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Product Code M2150A12-100mg
Price £400 ex. VAT

PM6, for high performance OPV devices

High purity and available for priority dispatch


Overview | Specifications | Pricing and Options  | MSDS | Literature and Reviews


PBDB-T-2F (CAS number 1802013-83-7) is a PBDB-T family member and, like others, has a high OPV device performance. Polymer solar cells with PBDB-T-2F as the donor and ITIC-2F as the acceptor have achieved a power conversion efficiency (PCE) of over 13%.

By introducing two fluorine atoms to each thiophene unit of the benzodithiophene (BDT) side chains in PBDB-T, the HOMO/LUMO energy levels are pulled. Complete phase separation is observed in the PBDB-T-2F:ITIC-2F blend due to the distinct surface tension difference between PBDB-T-2F and ITIC-2F, resulting in a high domain purity in the blend.

A certified efficiency of 14.9% has been demonstrated using PBDB-T-2F (PM6) as the electron donor and Y6 as an acceptor in a single junction non-fullerene polymer solar cell (NF-PSC) [2].

Conjugated semiconducting polymer

Conjugated semiconducting polymer

As electron donor for high efficient OPV applications

Luminosyn™

Luminosyn™

High purity, batch-specific GPC data, available larger batch orders and higher molecular weight

Worldwide shipping for 1802013-83-7

Worldwide shipping

Quick and reliable shipping

Green energy material

Green energy materials

Processable in non-halogenated solvents

Ossila's PBDB-T-2F used in a high-impact paper

PBDB-T-2F from Ossila was used in the high-impact paper (IF 18.81), Stretchable and Transparent Conductive PEDOT:PSS-Based Electrodes for Organic Photovoltaics and Strain Sensors Applications, E. Dauzon et al., Adv. Fun. Mater., 30 (28), 2001251 (2020); DOI: 10.1002/adfm.202001251; and paper (IF 29.37), Design Rules for Polymer Blends with High Thermoelectric Performance, O. Zapata-Arteaga et al., Adv. Energy Mater., 12, 2104076 (2022); DOI: 10.1002/aenm.202104076.

Luminosyn™ PBDB-T-2F

Luminosyn™ PBDB-T-2F is now available.

High Purity

Purified by Soxhlet extraction with methanol, hexane, and chlorobenzene under an argon atmosphere

Batch-Specific GPC data

Precise molecular weights are always available to provide a reliable reference in your thesis or publication

Large Quantity Orders

Plan and conduct your experiments
with confidence using polymers from the same batch

General Information


Full name Poly[(2,6-(4,8-bis(5-(2-ethylhexyl-3-fluoro)thiophen-2-yl)-benzo[1,2-b:4,5-b’]dithiophene))-alt-(5,5-(1’,3’-di-2-thienyl-5’,7’-bis(2-ethylhexyl)benzo[1’,2’-c:4’,5’-c’]dithiophene-4,8-dione)]
Synonyms PBDB-T-F, PBDB-TF, PM6
Chemical formula (C68H76F2O2S8)n
CAS number 1802013-83-7
HOMO / LUMO HOMO = -5.45 eV, LUMO = -3.65 eV [1]
Processing solvents o-xylene, chloroform, chlorobenzene and dichlorobenzene
Classification / Family Organic semiconducting materials, Medium bandgap polymers, Organic photovoltaics, Polymer solar cells, Perovskite solar cells, Hole-transport layer materials, NF-PSCs, All-polymer solar cells (all-PSCs).

Technical Data


Product Code Soluble solvents Recommended Processing Solvents at 10mg/ml
M2150A4

Chloroform, chlorobenzene and dichlorobenzene

Chlorobenzene
M2150A5

Chlorobenzene and dichlorobenzene

Dichlorobenzene
M2150A7 Chloroform, chlorobenzene and dichlorobenzene

Dichlorobenzene or Chlorobenzene : dichlorobenzene (v/v = 1:1)

M2150A8/9/10

 

o-Xylene, chloroform, chlorobenzene and dichlorobenzene

o-Xylene (8 mg/ml), chloroform, chlorobenzene
M2150A11/12

Chloroform, chlorobenzene and dichlorobenzene

Chloroform, chlorobenzene

Chemical Structure


pbdb-t-2f, pbdb-t-f chemical structure
Chemical structure of PBDB-T-2F, CAS No. 2239295-71-5

Pricing


Batch Quantity Price
M2150A 100 mg £400
M2150A 250 mg £800
M2150A 500 mg £1300
M2150A 1 g £2400

Batch details


Batch* Mw Mn PDI Stock Info
M2150A5 126,690 60,551 2.09 Discontinued
M2150A6 107,004 29,644 3.61 Discontinued
M2150A7 100,180 44,778 2.24 Discontinued
M2150A8 81,082 36,635 2.22 Discontinued
M2150A9 72,090 27,534 2.62 Discontinued
M2150A10 87,278 25,955 3.36 Discontinued
M2150A11 102,029 39,556 2.58 Low stock
M2150A12 112,729 42,619 2.65 In stock

*Older batch information available on request.

MSDS Documentation


PBDB-T-2F MSDSPBDB-T-2F MSDS sheet

Literature and Reviews


  1. Over 14% Efficiency in Organic Solar Cells Enabled by Chlorinated Nonfullerene Small-Molecule Acceptors, H. zhang et al., Adv.Mater., 30, 1800613 (2018); DOI: 10.1002/adma.201800613.
  2. Single-Junction Organic Solar Cell with over 15% Efficiency Using Fused-Ring Acceptor with Electron-Deficient Core, J. Yuan et al., Joule (2019); doi: 10.1016/j.joule.2019.01.004.
  3. Over 14% Efficiency in Polymer Solar Cells Enabled by a Chlorinated Polymer Donor, S. Zhang et al., Adv. Mater., 30, 1800868 (2018); DOI: 10.1002/adma.201800868.

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