Stretchable Redox-Active Semiconducting Polymer
Designed for organic electrochemical transistors with microsecond switching speed
Overview | Specifications | MSDS | Literature and Reviews | Technical Support
P(g2T-TT) is a copolymer with a backbone alternating thienothiophene (TT) and 2,2'-bithiophene (BT) units with triethylene glycol (TEG) side chains in the 3,3′ positions of the bithiophene repeating units. The triethylene glycol side chains can facilitate hydration and ion penetration without compromising electronic mobility by shifting the mode of operation of aqueous electrolyte-gated transistors from interfacial to bulk doping/transport.
With triethylene glycol side chains, P(g2T-TT) films can uptake a much higher density of ions while showing a much lower degree of hydration than PEDOT:PSS films. The P(g2T-TT) films can also show a high degree of molecular ordering during electrochemical switching, demonstrating complete and reversible electrochromism and high volumetric capacitance at low operating biases. Bulk doping of P(g2T-TT) by hydrated ions allows for extraction of the volumetric capacitance of C*=240 F/cm3, a value almost six times higher than that of PEDOT:PSS, indicating a higher density of ion-accessible sites.
Stretchable Redox-Active Polymer
Highly desirable for OECTs
Large Batch Luminosyn™
High purity with batch-specific GPC data
Simple Worldwide Shipping
Reliable delivery via tracked courier
High Density of Ion-Accessible Sites
With low degree of hydration
The Luminosyn™ Range
High Purity Materials: Purified by Soxhlet extraction with methanol, hexane, and chlorobenzene under argon atmosphere.Batch-Specific Data: Confidence in your materials with batch-specific GPC data for your thesis or publications.Large Quantity Orders: Plan your experiments with confidence using polymers from the same batch.General Information
| CAS Number | 2058240-28-9 |
|---|---|
| Full Name | Poly[2-(3,3′-bis(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)-[2,2’-bithiophen]-5-yl)thieno[3,2-b]thiophene] |
| Chemical Formula | (C28H34O8S4)n |
| HOMO/LUMO | HOMO = 5.2 eV (Eg = 1.74 eV) [1] |
| Absorption | λmax = 597 nm (in film) |
| Form | Blue powder/fibers |
| Processing Solvents | DMF, Chloroform (typically 5 mg/ml in chloroform) |
| Synonyms | pg2T-TT, g2T-TT |
| Classification / Family | Polythiophenes, Redox-active semiconducting polymer (RASP), Organic electrochemical transistors (OECTs), Electrocardiogram (ECG) recording, Biosensors |
Batch Details
| Batch | Mw | Mn | PDI | Stock info |
|---|---|---|---|---|
| M2475A6 | 4,332 | 2,378 | 1.82 | In stock |
Chemical Structure
MSDS Documentation
P(g2T-TT) MSDS SheetLiterature and Reviews
- R. Hallani et al. (2021); Regiochemistry-Driven Organic Electrochemical Transistor Performance Enhancement in Ethylene Glycol-Functionalized Polythiophenes, J. Am. Chem. Soc., 143 (29), 11007–11018; DOI: 10.1021/jacs.1c03516.
- Y. Zhang et al. (2023); Combined Optical, Gravimetric, and Electrical Operando Investigation of Structural Variations in Polymeric Mixed Conductors, Adv. Funct. Mater., 33 (16), 2214380. DOI: 10.1002/adfm.202214380.
- A. Giovannitti et al. (2016); Controlling the mode of operation of organic transistors through side-chain engineering, PNAS, 113 (43), 12017–12022; DOI: 10.1073/pnas.1608780113.