PBDTT-DPP
CAS Number 1380582-98-8
Luminosyn™ Polymers, OPV Polymers, Semiconducting Polymers, Materials
Low Bandgap Semiconducting Polymer
High purity and available online for priority dispatch
Overview | Specifications | MSDS | Literature and Reviews | Technical Support
PBDTT-DPP (CAS 1380582-98-8) is a low bandgap polymer with strong photosensitivity in the range of 650 – 850 nm, with an onset absorption at 858 nm (Eg = 1.45 eV, near infrared absorption). However, it is less sensitive to visible light in the solar spectrum making it an ideal candidate for tandem solar cell structures, having achieved device performances of 8.62% (with device structure ITO/ZnO/P3HT:ICBA/PEDOT:PSS/ZnO/PBDTT-DPP:PC71BM/Ag).
Additionally, a single-layer device based on PBDTT-DPP was shown to demonstrate a power conversion efficiency of 6%.[1] It also finds application in perovskite solar cells due to its perfect energy level line-ups with perovskites.
The Luminosyn™ Range
High Purity Materials: Purified by Soxhlet extraction with methanol, hexane, and chlorobenzene under argon atmosphere.Batch-Specific Data: Confidence in your materials with batch-specific GPC data for your thesis or publications.Large Quantity Orders: Plan your experiments with confidence using polymers from the same batch.General Information
| CAS Number | 1380582-98-8 |
|---|---|
| Chemical Formula | (C72H94N2O2S6)n |
| Full Name | Poly{2,6′-4,8-di(5-ethylhexylthienyl)benzo[1,2-b;3,4-b]dithiophene-alt-5,5'-dibutyloctyl-3,6-bis(5-thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4-dione} |
| HOMO / LUMO | HOMO = -5.30 eV, LUMO = -3.63 eV [1] |
| Soluble In | Chloroform, chlorobenzene, dichlorobenzene |
| Recommended Processing Solvents at 10mg/ml | Dichlorobenzene or Chlorobenzene+dichlorobenzene (1:1 v/v) |
| Synonyms | PBDT-DPP |
| Classification or Family | Organic semiconducting materials, Low band gap polymers, Organic photovoltaics, Polymer solar cells, Tandem solar cells, Perovskite solar cells. |
Batch Details
| Batch number | MW | Mn | PDI | Stock info |
|---|---|---|---|---|
| M1401A1 | 252,834 | 53,142 | 4.8 | In Stock |
Chemical Structure
MSDS Documentation
PBDTT-DPP MSDS SheetLiterature and Reviews
- Tandem polymer solar cells featuring a spectrally matched low-bandgap polymer, L. Dou et al., Nat. Photonics 6, 180 (2012); DOI: 10.1038/NPHOTON.2011.356.
- Metal Oxide Nanoparticles as an Electron-Transport Layer in High-Performance and Stable Inverted Polymer Solar Cells, J. You et al., Adv. Mater., 24, 5267–5272 (2012); DOI: 10.1002/adma.201201958.
- Visibly Transparent Polymer Solar Cells Produced by Solution Processing, C. Chen et al., ACS Nano, 6(8), 7185-7190 (2012); DOI: 10.1021/nn3029327.