PNDI(2OD)2T (high mobility n-type polymer)

Order Code: M1203
MSDS sheet

Price

(excluding Taxes)

£298.30


 PNDI(2OD)2T is now available, featuring:

  • Higher molecular weights and high purityPNDI(2OD)2T is purified by Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere
  • Batch-specific GPC data (so you have confidence in what you are ordering. Also, GPC data is always convenient for your thesis and publications)
  • Large-quantity orders (so you can plan your experiments with polymers from the same batch)

Pricing

Batch Quantity Price
M1203 100 mg £298.3
M1203 250 mg £596.6
M1203 500 mg £1073.9
M1203 1 g £1933

 

Batch details

Batch Mw Mn PDI Stock Info
M1201 >=30,000 >= 10,000 <=3.0 Out of stock
M1202 168,138 92,338 1.82 Out of stock
M1203 289,730 150,497 1.93 In stock

 

General Information

Full name Poly{[N,N'-bis(2-octyldodecyl)naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-5,5'-(2,2'-bithiophene)}
Synonyms
  • P(NDI2OD-T2)
  • PNDI-2T
  • Polynaphtalene-bithiophene
Chemical formula (C62H88N2O4S2)n
CAS number 1100243-40-0
HOMO / LUMO HOMO = -5.77 eV, LUMO = -3.84 eV [1]
Classification / Family Organic n-type semiconducting materials, Organic photovoltaics, Polymer solar cells, Electron-acceptor polymers, OFETs, Perovskite solar cells.
Solubility Soluble in chloroform, chlorobenzene, dichlorobenzene
chemical structure of P(NDI2OD-T2), pndi(2od)2t
Chemical structure and product image of PNDI(2OD)2T; Chemical formula: (C62H88N2O4S2)n.

Applications

PNDI(2OD)2T, a copolymer of naphthalene diimide (NDI) and bithiophene unit, has been intensively studied for use as an electron acceptor in polymer solar cells. This is due to its high electron mobility, high electron affinity, and broad light absorption. All polymer solar cells with PNDI(2OD)2T as an acceptor and J51 as a donor (fullerene-free) have demonstrated a power conversion efficiency over 8% [1].

PNDI(2OD)2T is also known as a high-mobility n-type polymer semiconductor. PNDI(2OD)2T-based OFET devices have electron mobilities up to 0.45–0.85 cm2V-1 s-1[2].

The synthesis of the polymer P(NDI2OD-T2) is described here and we also have PNDI(2HD)T, PNDI(2HD)T2 and PNDI(2OD)2T-2F available.

Literature and Reviews

  1. All-Polymer Solar Cells Based on Absorption-Complementary Polymer Donor and Acceptor with High Power Conversion Efficiency of 8.27%, L. Gao et al., Adv. Mater., 28, 1884–1890 (2016); DOI: 10.1002/adma.201504629.
  2. A high-mobility electron-transporting polymer for printed transistors, H. Yan et al., Nature, 457 (2009); doi:10.1038/nature07727.
  3. Highly efficient charge-carrier generation and collection in polymer/polymer blend solar cells with a power conversion efficiency of 5.7%, D. Mori et al., Energy Environ. Sci., 7, 2939-2943 (2014); DOI: 10.1039/C4EE01326C.
  4. Bulk Electron Transport and Charge Injection in a High Mobility n-Type Semiconducting Polymer, R. Steyrleuthner et al., Adv. Mater., 22, 2799–2803 (2010); DOI: 10.1002/adma.201000232.n2200.
  5. High-performance ternary blend all-polymer solar cells with complementary absorption bands from visible to near-infrared wavelengths, H. Benten et al., Energy Environ. Sci., 9, 135-140 (2016); DOI: 10.1039/C5EE03460D.
  6. High efficiency all-polymer tandem solar cells, J. Yuan et al., Sci. Reports 6, 26459 (2016); doi:10.1038/srep26459.
  7. Regioregular narrow-bandgap-conjugated polymers for plastic electronics, L. Ying et al., Nature Commun., 8:14047 (2017); DOI: 10.1038/ncomms14047.

 



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