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PNDI(2OD)2T


Product Code M1201A3-100mg
Price £298.00 ex. VAT

PNDI(2OD)2T, a copolymer of naphthalene diimide (NDI) and bithiophene unit, has been intensively studied for use as an electron acceptor in polymer solar cells. This is due to its high electron mobility, high electron affinity, and broad light absorption. All polymer solar cells with PNDI(2OD)2T as an acceptor and J51 as a donor (fullerene-free) have demonstrated a power conversion efficiency over 8% [1].

PNDI(2OD)2T is also known as a high-mobility n-type polymer semiconductor. PNDI(2OD)2T-based OFET devices have electron mobilities up to 0.45–0.85 cm2V-1 s-1[2].

PNDI(2OD)2T from Ossila was used in the high-impact paper (IF 18.81), Tuning Contact Resistance in Top-Contact p-Type and n-Type Organic Field Effect Transistors by Self-Generated Interlayers, T. Sarka et al., Adv. Funct. Mater., 1805617 (2020); DOI: 10.1002/adfm.201805617.

The synthesis of the polymer P(NDI2OD-T2) is described here and we also have PNDI(2HD)T, PNDI(2HD)T2 and PNDI(2OD)2T-2F available.

Luminosyn™ PNDI(2OD)2T

Luminosyn™ PNDI(2OD)2T is now available.

High molecular weight and high purity
PNDI(2OD)2T is purified by Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere

Batch-specific GPC data
Have confidence in what you are ordering; batch-specific GPC data for your thesis or publications

Large quantity orders
Plan your experiments with confidence with polymers from the same batch

General Information

Full name Poly{[N,N'-bis(2-octyldodecyl)naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-5,5'-(2,2'-bithiophene)}
Synonyms
  • P(NDI2OD-T2)
  • PNDI-2T
  • Polynaphtalene-bithiophene
Chemical formula (C62H88N2O4S2)n
CAS number 1100243-40-0
HOMO / LUMO HOMO = -5.77 eV, LUMO = -3.84 eV [1]
Classification / Family PNDI polymers, Organic n-type semiconducting materials, Organic photovoltaics, Polymer solar cells, Electron-acceptor polymers, OFETs, Perovskite solar cells.
Solubility Soluble in chloroform, chlorobenzene, dichlorobenzene

Chemical Structure

chemical structure of P(NDI2OD-T2)
Chemical structure of PNDI(2OD)2T

MSDS Documentation

PNDI(2OD)2T MSDSPNDI(2OD)2T MSDS sheet

Pricing

Batch Quantity Price
M1201A 100 mg £298.00
M1201A 250 mg £597.00
M1201A 500 mg £1070.00
M1201A 1 g £1930.00

Batch details

Batch Mw Mn PDI Stock Info
M1201 ≥30,000 3.0 Discontinued
M1202 168,138 92,338 1.82 Discontinued
M1203 289,730 150,497 1.93 Discontinued
M1204 123,320 67,167 1.84 Discontinued
M1201A1 132,276 31,079 4.26 Discontinued
M1201A2 125,059 54,373 2.3 Discontinued
M1201A3 202,261 90,982 2.22 In Stock

Literature and Reviews

  1. All-Polymer Solar Cells Based on Absorption-Complementary Polymer Donor and Acceptor with High Power Conversion Efficiency of 8.27%, L. Gao et al., Adv. Mater., 28, 1884–1890 (2016); DOI: 10.1002/adma.201504629.
  2. A high-mobility electron-transporting polymer for printed transistors, H. Yan et al., Nature, 457 (2009); doi:10.1038/nature07727.
  3. Highly efficient charge-carrier generation and collection in polymer/polymer blend solar cells with a power conversion efficiency of 5.7%, D. Mori et al., Energy Environ. Sci., 7, 2939-2943 (2014); DOI: 10.1039/C4EE01326C.
  4. Bulk Electron Transport and Charge Injection in a High Mobility n-Type Semiconducting Polymer, R. Steyrleuthner et al., Adv. Mater., 22, 2799–2803 (2010); DOI: 10.1002/adma.201000232.n2200.
  5. High-performance ternary blend all-polymer solar cells with complementary absorption bands from visible to near-infrared wavelengths, H. Benten et al., Energy Environ. Sci., 9, 135-140 (2016); DOI: 10.1039/C5EE03460D.
  6. High efficiency all-polymer tandem solar cells, J. Yuan et al., Sci. Reports 6, 26459 (2016); doi:10.1038/srep26459.
  7. Regioregular narrow-bandgap-conjugated polymers for plastic electronics, L. Ying et al., Nature Commun., 8:14047 (2017); DOI: 10.1038/ncomms14047.
  8. Naphthalene Diimide-Based Polymer Semiconductors: Synthesis, Structure−Property Correlations, and n-Channel and Ambipolar Field-Effect Transistors, X. Guo et al., Chem. Mater., 24, 1434−1442 (2012); DOI: 10.1021/cm2034273.

To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.

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