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PTQ11


Product Code M2277A1
Price £289.00 ex. VAT

PTQ11 is a wide bandgap copolymer alternating electron withdrawing quinoxaline and electron donating thiophene units as the backbone. Comparing to the low cost polymer donor PTQ10, PTQ11 shows stronger molecular crystallization tendency and better hole transport capability.

With zero HOMO offset, Non-fullerene polymer solar cells (NF-PSCs) based on PTQ11:TPT10 active layer shows highly efficient exciton dissociation and hole transfer, showing highly efficient device performance achieving PCE of 16.32% with a higher VOC of 0.88 V, a large JSC of 24.79 mA cm−2, and a high FF of 74.8% with the following device structure.

Device structure: ITO (indium tin oxide)/ZnO/PTQ11−TPT10/MoO3/Ag [1]

Thickness (nm) VOC (V) JSC (mA cm-2) FF (%) PCE (%)
110 nm 0.88 24.79 74.8 16.32

Luminosyn™ PTQ11

Luminosyn™ PTQ11 is now available.

High purity
PTQ11 is purified by Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere

Batch-specific GPC data
Batch specific GPC data is always available for your thesis or publication

Large-quantity orders
Plan your experiments with confidence with polymers from the same batch

General Information

Full name Poly[(thiophene)-alt-(6,7-difluoro-2-(2-hexyldecyloxy)-3-methylquinoxaline]
Synonyms PTQ11
Chemical formula (C29H38F2N2OS)n
CAS number n.a.
Absorption* λmax 548 nm, 590 nm in film (as-cast film from PTQ11 in chlorobenzene solution)
HOMO / LUMO HOMO = -5.52 eV, LUMO = -2.76 eV, Eg = 1.92 eV [1]
Solubility o-xylene, chloroform, chlorobenzene and dichlorobenzene
Processing solvent o-xylene, chloroform, chlorobenzene
Classification / Family Organic semiconducting materials, Wide band-gap polymers, Organic Photovoltaics, Polymer solar cells, NF-PSCs, All-polymer solar cells (all-pscs), Green energy materials.

* Measurable with an optical spectrometer, see our spectrometer application notes.

Chemical Structure

Chemical structure of PTQ11.

MSDS Documentation

PTQ11 MSDSPTQ11 MSDS sheet

Pricing

Batch Quantity Price
M2277A1 100 mg £289.00
M2277A1 250 mg £578.00
M2277A1 500 mg £998.00
M2277A1 1 g £1890.00
M2277A1 5 g / 10 g* Please enquire

* Lead time of 4-6 weeks.

Batch details

Batch Mw Mn PDI Stock Info
M2277A1 69,889 36,558 1.91 In stock

Literature and Reviews

  1. High Efficiency Polymer Solar Cells with Efficient Hole Transfer at Zero Highest Occupied Molecular Orbital Offset between Methylated Polymer Donor and Brominated Acceptor, C. Sun et al., J. Am. Chem. Soc., 142, 1465−1474 (2020); DOI: /10.1021/jacs.9b09939.
  2. Achieving Fast Charge Separation and Low Nonradiative Recombination Loss by Rational Fluorination for High-Efficiency Polymer Solar Cells, C. Sun et al., Adv. Mater., 31, 1905480 (2019); DOI: 10.1002/adma.201905480.

 

Characterisations

UV-Vis Absorption


UV-Vis absorption of of PTQ11 in film (as-cast film from PTQ11 solution in chlorobenzene on glass).

 

Cyclic Voltammetry

cyclic voltammetry of polymer ptq11 in film
Cyclic voltammograms of the PTQ11 film on platinum electrode in 0.1M Bu4NClO4 in acetonitrile at a scan rate of 100 mV s−1.

The cyclic voltammograms (CV) measurements were recorded on Ossila Potentiostat by using a three-electrode system with platinum disc as the working electrode, platinum wire as the counter electrode, Ag/Agelectrode as the reference electrode with a scanning rate of 100 mV/s in a 0.1 M tetrabutylammonium perchlorate (Bu4NClO4) solution. The potential of Ag/Ag+ reference electrode was internally calibrated by using ferrocene/ferroncenium (Fc/Fc+) as the redox couple.


To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.

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