Luminosyn™
High purity and good solubility - PDPP3T is purified by soxhlet extraction with methanol, hexane and chlorobenzene under argon atmosphere -polymer at its pure best
Batch-specific GPC data - so you have confidence in what you are ordering and GPC data is always convenient for your thesis and publications
Larger quantity orders - so you can plan your experiments with polymer from the same batch
Pricing
Batch Quantity Price
M991 100 mg
£196.00
M991 250 mg
£388.00
M991 500 mg
£698.00
M991 1 g
£1230.00
M991 5 g / 10 g*
Please enquire
*for 5 - 10 grams order quantity, the lead time is 4-6 weeks.
Batch details
Batch Mw Mn PDI Stock Info
M991
66,759
31,505
2.12
In stock
General Information
Full name Poly{2,2′-[(2,5-bis(2-hexyldecyl)-3,6-dioxo-2,3,5,6- tetrahydropyrrolo[3,4-c ]pyrrole-1,4-diyl)dithiophene]- 5,5′-diyl-alt-thiophen-2,5-diyl}
Synonyms PDPP3T, DPP3T
Chemical formula (C50 H72 N2 O2 S3 )n
CAS number 1198291-01-8
HOMO / LUMO HOMO = -5.17 eV, LUMO = -3.61 eV [1]
Solubility Toluene, chloroform, chlorobenzene, dichlorobenzene
Classification / Family Pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione, Heterocyclic five-membered ring, Organic semiconducting materials, Low band gap polymers, Organic Photovoltaics, Polymer Solar Cells, OFETs
Chemical structure and product image of PDPP3T; Chemical formula:(C50 H72 N2 O2 S3 )n ; CAS# 1198291-01-8.
Applications
PDPP3T is used as active layer material for OPV devices with 6.71% PCE reported when a solvent mixture of DCB/Chloroform/DIO was used.
Being electron rich, PDPP3T is also used as an effective spiro-OMeTAD replacement hole-transport layer material for perovskite solar cells [1], as well as in organic field-effect transistors [2, 3] and printed electronics.
Literature and Reviews
Solution processed pristine PDPP3T polymer as hole transport layer for efficient perovskite solar cells with slower degradation, A. Dubey et al., Sol. Energ. Mat. Sol. Cells 145, 193–199 (2016);DOI : 10.1016/j.solmat . 2015.10.008 .
Optimization of charge carrier transport balance for performance improvement of PDPP3T-based polymer solar cells prepared using a hot solution, J. Wang et al., Phys. Chem. Chem. Phys. 17, 9835--9840 (2015); DOI: 10.1039/c5cp00963d.
Effects of 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane doping on diketopyrrolopyrrole-based, low crystalline, high mobility polymeric semiconductor, S. Yoon et al., Appl. Phys. Lett. 107, 133302 (2015); doi: 10.1063/1.4932530.
