PDPP3T

Order Code: M991
MSDS sheet

Price

(excluding Taxes)

£176.30


PDPP3T is now available featuring:

  • High purity and high solubility (PDPP3T is purified by soxhlet extraction with methanol, hexane and chlorobenzene)
  • Batch specific GPC data necessary for your publications
  • Larger quantities now available so that you can plan your experiments with a polymer from a single batch

Pricing

    Batch Quantity Price
    M991 100 mg £176.30
    M991 250 mg £387.80
    M991 500 mg £698.10
    M991 1 g £1228.60
    M991 5 g / 10 g* Please enquire

     *for 5 - 10 grams order quantity, the lead time is 4-6 weeks.

     

    Batch details

    Batch Mw Mn PDI
    M991 66,759 31,505 2.12

     

    General Information

    Full name Poly{2,2′-[(2,5-bis(2-hexyldecyl)-3,6-dioxo-2,3,5,6- tetrahydropyrrolo[3,4-c ]pyrrole-1,4-diyl)dithiophene]- 5,5′-diyl-alt-thiophen-2,5-diyl}
    Synonyms PDPP3T
    Chemical formula (C50H72N2O2S3)n
    CAS number 1198291-01-8
    HOMO / LUMO HOMO = -5.17 eV, LUMO = -3.61 eV [1]
    Solubility Toluene, chloroform, chlorobenzene, dichlorobenzene
    Classification / Family Pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione, Heterocyclic five-membered ring, Organic semiconducting materials, Low band gap polymers, Organic Photovoltaics, Polymer Solar Cells, OFETs

     

    Chemical Structure

    chemical structure of PDPP3T
    Chemical structure of PDPP3T; Chemical formula (C50H72N2O2S3)n; CAS# 1198291-01-8.

     

    Applications

    PDPP3T is used as active layer material for OPV devices with 6.71% PCE reported when a solvent mixture of DCB/Chloroform/DIO was used.

    Being electron rich, PDPP3T is also used as an effective spiro-OMeTAD replacement hole-transport layer material for perovskite solar cells [1], as well as in organic field-effect transistors [2, 3] and printed electronics.

     

    Literature and Reviews

    1. Solution processed pristine PDPP3T polymer as hole transport layer for efficient perovskite solar cells with slower degradation, A. Dubey et al., Sol. Energ. Mat. Sol. Cells 145, 193–199 (2016);DOI: 10.1016/j.solmat.2015.10.008.
    2. Optimization of charge carrier transport balance for performance improvement of PDPP3T-based polymer solar cells prepared using a hot solution, J. Wang et al., Phys. Chem. Chem. Phys. 17, 9835--9840 (2015); DOI: 10.1039/c5cp00963d.
    3. Effects of 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane doping on diketopyrrolopyrrole-based, low crystalline, high mobility polymeric semiconductor, S. Yoon et al., Appl. Phys. Lett. 107, 133302 (2015); doi: 10.1063/1.4932530.