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Product Code M0991A1-100mg
Price £260 ex. VAT

Specifications | Pricing and Options | MSDS | Literature and Reviews

PDPP3T (CAS number 1198291-01-8) is used as active layer material for OPV devices with 6.71% PCE reported when a solvent mixture of DCB/Chloroform/DIO was used.

Being electron rich, PDPP3T is also used as an effective spiro-OMeTAD replacement hole-transport layer material for perovskite solar cells [1], as well as in organic field-effect transistors [2, 3] and printed electronics.

Luminosyn™ PDPP3T

Luminosyn™ PDPP3T is now available.

High purity and good solubility
PDPP3T is purified by soxhlet extraction with methanol, hexane and chlorobenzene under argon atmosphere

Batch-specific GPC data
Have confidence in what you are ordering; batch-specific GPC data for your thesis or publications

Large quantity orders
Plan your experiments with confidence with polymers from the same batch

General Information

Full name Poly{2,2′-[(2,5-bis(2-hexyldecyl)-3,6-dioxo-2,3,5,6- tetrahydropyrrolo[3,4-c ]pyrrole-1,4-diyl)dithiophene]- 5,5′-diyl-alt-thiophen-2,5-diyl}
Synonyms PDPP3T, DPP3T
Chemical formula (C50H72N2O2S3)n
CAS number 1198291-01-8
HOMO / LUMO HOMO = -5.17 eV, LUMO = -3.61 eV [1]
Solubility Toluene, chloroform, chlorobenzene, dichlorobenzene
Classification / Family Pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione, Heterocyclic five-membered ring, Organic semiconducting materials, Low band gap polymers, Organic Photovoltaics, Polymer Solar Cells, OFETs

Chemical Structure

pdpp3t chemical strucutre
Chemical structure and product image of PDPP3T


Batch Quantity Price
M0991A 100 mg £260
M0991A 250 mg £500
M0991A 500 mg £950
M0991A 1 g £1650
M0991A 5 g / 10 g* Please enquire

*for 5 - 10 grams order quantity, the lead time is 4-6 weeks.

Batch details

Batch Mw Mn PDI Stock Info
M991 66,759 31,505 2.12 Discontinued
M0911A1 63,931 34,736 1.84
Low stock
M0911A2 57,572 31,072 1.85 In stock

MSDS Documentation


Literature and Reviews

  1. Solution processed pristine PDPP3T polymer as hole transport layer for efficient perovskite solar cells with slower degradation, A. Dubey et al., Sol. Energ. Mat. Sol. Cells 145, 193–199 (2016);DOI: 10.1016/j.solmat.2015.10.008.
  2. Optimization of charge carrier transport balance for performance improvement of PDPP3T-based polymer solar cells prepared using a hot solution, J. Wang et al., Phys. Chem. Chem. Phys. 17, 9835--9840 (2015); DOI: 10.1039/c5cp00963d.
  3. Effects of 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane doping on diketopyrrolopyrrole-based, low crystalline, high mobility polymeric semiconductor, S. Yoon et al., Appl. Phys. Lett. 107, 133302 (2015); doi: 10.1063/1.4932530.
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