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Product Code M2256A1-100mg
Price $500 ex. VAT

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PBBTCD, high quality semiconducting polymer

High purity and available online for priority dispatch


PBBTCD, polybenzobisthiadiazole-dithienocyclopentane, is a small bandgap copolymer (Eg = ~ 0.6 eV) with a backbone alternating electron donating cyclopentadithiophene (CDT) and electron accepting fused-ring benzobisthiadiazole (BBT) units.

High charge mobilities were observed to be 0.076 cm2 V-1 s-1 for electrons and 0.10 cm2 V-1 s-1 for holes for PBBTCD due to its planar structure and orderly packed structure in film. The balanced ambipolarity of the BBT moiety of the polymer makes it a good candidate for logic circuit applications.

Luminosyn™ PBBTCD

Luminosyn™ PBBTCD is now available.

High purity
PBBTCD is purified via Soxhlet extraction with acetone, hexane, and chlorobenzene under an argon atmosphere

Large quantity orders
Plan your experiments with polymers from the same batch

General Information

Full name Poly[(4,7-bis(3-hexylthien-2-yl)- 2λ4δ2-benzo[1,2-c;4,5-c′]bis[1,2,5] thiadiazole)-alt-(3,3-bis(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b′]dithiophene)]
Synonyms PBBTCD
Chemical formula (C51H64N4S6)n
CAS number 1334032-14-2
HOMO / LUMO HOMO = -4.80 eV, LUMO = -4.00 eV; Eg = 0.6 eV [1]
Solubility Chloroform, chlorobenzene and dichlorobenzene
Processing solvent Chloroform, chlorobenzene and dichlorobenzene
Classification / Family Organic semiconducting materials, Very low-bandgap polymers, Ambipolar semiconducting polymers, OFET polymers, High charge mobility polymers, Photodetectors, Thin-film Transistors

Chemical Structure

Chemical structure of PBBTCD, CAS 1334032-14-2
Chemical structure of PBBTCD, CAS 1334032-14-2

UV-Vis-NIR Absorption

pbbtcd uv-vis-nir absorption in chloroform
UV-Vis-NIR absorption of PBBTCD in chloroform.

MSDS Documentation

PBBTCD MSDSPBBTCD MSDS sheet

Pricing

Batch Quantity Price
M2256A1 100 mg £400
M2256A1 250 mg £800
M2256A1 500 mg £1450
M2256A1 1 g £2600
M2256A1 5 g / 10 g* Please contact us for details

*for 5 - 10 grams order quantity, the lead time is 4-6 weeks.

Batch details

Batch Mw Mn PDI Stock Info
M2256A1 17,762 7,733 2.30 In stock

Literature and Reviews

  1. Ambipolarity in Benzobisthiadiazole-Based Donor–Acceptor Conjugated Polymers, J. D. Yuen et al., Adv. Mater., 23, 3780–3785 (2011); DOI: 10.1002/adma.201101134.
  2. Infrared spectroscopy of narrow gap donor-acceptor polymer-based ambipolar transistors, O. Khatib et al., Phys. Rev. B 86, 195109 (2012); DOI: 10.1103/PhysRevB.86.195109.
  3. Organic Transistors in the New Decade: Toward n-Channel, Printed, and Stabilized Devices, S. Kola et al., J. Polym. Sci. B: Polym. Phys., 50, 1090–1120 (2012); DOI: 10.1002/polb.23054.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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