TQ1

tq1 chemical structure, 565228-37-7
Order Code: M2076A1
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Luminosyn™ polymer TQ1 is now available, featuring:

  • High molecular weight with high solubility and high purity - TQ1 polymer is purified by soxhlet extraction with methanol, hexane and chloroform under an argon atmosphere - polymer at its pure best
  • Batch-specific GPC data - for confidence in the reliability and consistency of your materials, and useful information for your thesis/publications
  • Larger-quantity orders - so that you can plan your experiments with polymers from the same batch

Pricing

Batch Quantity Price
M2076A1 100 mg £257.6
M2076A1 250 mg £515.2
M2076A1 500 mg £927.2
M2076A1 1 g £1668.9
M2076A1 5 g / 10 g* Please enquire

 *for 5 - 10 grams order quantity, the lead time is 4-6 weeks.

Batch Details

Batch Mw Mn PDI Stock Info
M2076A1 150,244 61,571 2.44 In stock

 

General Information

Full name Poly[[2,3-bis(3-octyloxyphenyl)-5,8-quinoxalinediyl]-2,5-thiophenediyl]
Synonyms PTQ1
CAS number 565228-37-7
Chemical formula (C40H46N2O2S)n
Molecular weight See Batch Details table above
HOMO / LUMO HOMO = - 5.70 eV, LUMO = - 3.30 eV [1]
Suggesting solvents Chloroform, chlorobenzene, dichlorobenzene
Classification / Family Quinoxaline heterocyclic five-membered ring, Organic semiconducting materials, Wide band-gap polymers, Organic photovoltaics, Polymer solar cells, OFETs
polymer tq1, ptq1, 565228-37-7, luminosyn, opv
Chemical structure and product image of TQ1, CAS No. 565228-37-7.

Applications

TQ1 is an alternating copolymer based on an alkoxylated quinoxaline acceptor and a thiophene donor. It is a cost-effective medium band-gap polymer donor material used for high-performance polymer solar cells.

Over 7% device efficiency was achieved in OPV devics with PTQ1 as the polymer donor, PC71BM as the acceptor and 1-Chloronaphthalene as an additive [3]. This high efficiency was attributed to the polymer chain order and morphological effects.

Literature and Reviews

  1. An Easily Synthesized Blue Polymer for High-Performance Polymer Solar Cells, E. Wang et at., Adv. Mater., 22, 5240–5244 (2010); DOI:  10.1002/adma.201002225.
  2. Inverted all-polymer solar cells based on a quinoxaline–thiophene/naphthalene-diimide polymer blend improved by annealing, Y. Xia et al., J. Mater. Chem. A, 4, 3835-3843 (2016); DOI: 10.1039/C6TA00531D.
  3. High-efficiency polymer solar cells with a cost-effective quinoxaline polymer through nanoscale morphology control induced by practical processing additives, Y. Kim et al., Energy Environ. Sci., 6, 1909-1916 (2013); DOI: 10.1039/C3EE00110E.

 

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