PBDTTTPD


Order Code: M2054A1
Price excludes taxes
Not in stock (price excludes taxes)

Luminosyn™ PBDTTTPD is now available featuring:

  • High purity - PBDTTTPD is purified by soxhlet extraction with methanol, hexane and chloroform under argon atmosphere - polymer at its pure best
  • Batch-specific GPC data - so you have confidence in what you are ordering and GPC data is always convenient for your thesis and publications
  • Larger quantity orders - so you can plan your experiments with polymer from the same batch

Pricing

Batch Quantity Price
M2054A1 100 mg £211.5
M2054A1 250 mg £433.6
M2054A1 500 mg £780.4
M2054A1 1 g £1322.5
M2054A1 5 g / 10 g* Please enquire

 *for 5 - 10 grams order quantity, the lead time is 4-6 weeks.

Batch Details

Batch Mw Mn PDI Stock Info
M2054A1 37,952 13,848 2.74 In stock

 

General Information

Full name Poly[(5,​6-​dihydro-​5-​octyl-​4,​6-​dioxo-​4H-​thieno[3,​4-​c]​pyrrole-​1,​3-​diyl)​[4,​8-​bis[5-​(2-​ethylhexyl)​-​2-​thienyl]​benzo[1,​2-​b:4,​5-​b']​dithiophene-​2,​6-​diyl]​]
Synonyms PBDTT(EH)-TPD(Oct), PBDTT-TPD
CAS number 1426534-44-2
Chemical formula (C48H57NO2S5)n
Molecular weight See Batch Details table above
HOMO / LUMO HOMO = - 5.49 eV, LUMO = - 3.47 eV [1]
Solubility Chloroform, chlorobenzene, dichlorobenzene
Classification / Family Benzodithiophene, BDT, Thienopyrrole, Heterocyclic five-membered ring, Organic semiconducting materials, Low band gap polymers, Organic photovoltaics, All-polymer solar cells, OFETs, Photodetectors
pbdtttpd chemical structure
Chemical structure and product image of PBDTTTPD, CAS No. 1426534-44-2, Chemical formula (C48H57NO2S5)n.

Applications

PBDTTTPD, poly[(5,​6-​dihydro-​5-​octyl-​4,​6-​dioxo-​4H-​thieno[3,​4-​c]​pyrrole-​1,​3-​diyl)​[4,​8-​bis[5-​(2-​ethylhexyl)​-​2-​thienyl]​benzo[1,​2-​b:4,​5-​b']​dithiophene-​2,​6-​diyl]​, has been used in the application of all polymer solar cells with PBDTTTPD as polymer donor and PNDI(2HD)T polymer acceptor providing high power-conversion efficiency of 6.64% [1]. 

PBDTTTPD shows complementary absorption with poly-naphthalene-diimides as acceptor polymers and the low-lying HOMO energy level of PBDTTTPD produces a high VOC value in all-PSCs.  Polymer-polymer solar cell with PBDTT-TPD as donor and PNF222 (PNDI(2OD)2T-2F) as acceptor has a VOC = 1.00 V, JSC = 11.68 mA cm−2 and FF = 0.52 to give a PCE 0f 6.09% [2].

Literature and Reviews

  1. Flexible, highly efficient all-polymer solar cells, T. Kim et al., Nat. Commun. 6, 8547 (2015); doi:10.1038/ncomms9547.
  2. Controlling Energy Levels and Blend Morphology for All-Polymer Solar Cells via Fluorination of a Naphthalene Diimide-Based Copolymer Acceptor, M. A. Uddin et al., Macromolecules 2016, 49, 6374−6383 (2016); DOI: 10.1021/acs.macromol.6b01414.
  3. Toward Highly Sensitive Polymer Photodetectors by Molecular Engineering, L. Zhang et al., Adv. Mater., 27, 6496–6503 (2015); DOI: 10.1002/adma.201502267.n2200.