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Product Code B781-1g
Price £520 ex. VAT

HDOQx-DBrDF, high purity (>99%) monomer

Used in low band gap semiconducting polymers for organic photovoltaic devices

Specifications | MSDS | Literature and Reviews

HDOQx-DBrDF, namely 5,8-Dibromo-6,7-difluoro-2-((2-hexyldecyl)oxy)quinoxaline (CAS number 2269476-12-0), is a fluorinated quinoxaline derivative. Quinoxaline derivatives are widely used as electron deficient units in low bandgap semiconducting polymers for organic photovoltaic devices. Further introduction of fluorine atoms on the benzene ring makes electron density in the structure even poorer, downshifting the highest occupied molecular orbital (HOMO) energy level and increasing charge mobility of the targeted polymer donors. Fluorination also achieves fast charge separation and low nonradiative recombination loss in the PSCs, resulting both high VOC and JSC. Large hexyldecyloxy (HD) group is there to enhance absorption of the polymers and to improve the targeted polymers' solubility in most of the common solvents.

HDOQx-DBrDF has been used for the synthesis of PTQ10 as a highly efficient polymer semiconductor for NF-PSCs.

Capped with bromide

Capped with bromide

for facil coupling reactions

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Fluorinated building block

Quinoxaline building block

For semiconductors, OFETs, and solar cells

High purity 2269476-12-0

High purity

>99% High purity

General Information

CAS Number 2269476-12-0
Chemical Formula C24H34Br2F2N2O
Molecular Weight 564.34 g/mol
Synonyms 5,8-Dibromo-6,7-difluoro-2-((2-hexyldecyl)oxy)quinoxaline
Classification / Family Quinoxaline, Semiconductor synthesis intermediates, Low band gap polymers, OFETs, Organic photovoltaics, polymer solar cells

Chemical Structure

5,8-Dibromo-6,7-difluoro-2-((2-hexyldecyl)oxy)quinoxaline, hdoqx-dbrdf, 2269476-12-0
Chemical structure of HDOQx-DBrDF, CAS 2269476-12-0

Product Details

Purity >99% (byHPLC, 254 nm, 1H NMR in CDCl3)
Melting Point N/A
Appearance Colorless oil

MSDS Documentation


Literature and Reviews

  1. Achieving Fast Charge Separation and Low Nonradiative Recombination Loss by Rational Fluorination for High-Efficiency Polymer Solar Cells, C. Sun et al., Adv. Mater., 31, 1905480 (2019); DOI: 10.1002/adma.201905480.
  2. Exciton and Charge Carrier Dynamics in Highly Crystalline PTQ10:IDIC Organic Solar Cells, H. Cha et al., Adv. Energy Mater., 10 (38), 2001149 (2020); DOI: 10.1002/aenm.202001149.
  3. Tailored phase conversion under conjugated polymer enables thermally stable perovskite solar cells with efficiency exceeding 21%, L. Meng et al., J. Am. Chem. Soc., 140, 49, 17255–17262 (2018); DOI: 10.1021/jacs.8b10520.
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