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7-(Diethylamino)-4-(trifluoromethyl)coumarin

CAS Number 41934-47-8

Chemistry Building Blocks, Fluorinated Building Blocks, Heterocyclic Building Blocks, Monomers


Product Code B1611-250mg
Price $138 ex. VAT

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A fluorinated heterocyclic building block

Used as a synthesis intermediate for dyes in application of DSSCs, OLED, bioimaging


7-(Diethylamino)-4-(trifluoromethyl)coumarin (CAS number 41934-47-8) is a fluorinated heterocyclic compound with a diethylamine (7-position) and a trifluoromethyl (4-position) substituents. As a coumarin derivative, 7-(Diethylamino)-4-(trifluoromethyl)coumarin is commonly applied as dyes with excellent light conversion capability with quantum yield of 94.8%. It is a promising candidate to be applied in OLEDs and dye-sensitized solar cells (DSSCs).

7-(Diethylamino)-4-(trifluoromethyl)coumarin can be modified with Lawesson's reagent to thiocoumarin. The modification allows further functionalization to the molecules resulting shifts in the absorption and emission spectra. The emission of the coumarin derivatives ranges from 380 nm to 550 nm, which is ideal for bioimaging.

Multiple functional groups

Multiple functional groups

For facile synthesis

Fluorinated building block

Fluorinated coumarin building block

For drug discovery, solar cells, and OLEDs

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High purity 41934-47-8

High purity

>97% High purity

General Information

CAS Number 41934-47-8
Chemical Formula C14H14F3NO2
Full Name 7-(Diethylamino)-4-(trifluoromethyl)coumarin
Molecular Weight 285.27 g/mol
Synonyms Coumarin 481, 7-(Diethylamino)-4-(trifluoromethyl)-2H-chromen-2-one
Classification / Family Fluorinated building block, Heterocyclic building block, Dyes, OLEDs, DSSCs, Bioimaging

Chemical Structure

7-(Diethylamino)-4-(trifluoromethyl)coumarin chemical structure, CAS 41934-47-8
7-(Diethylamino)-4-(trifluoromethyl)coumarin chemical structure, CAS 41934-47-8

Product Details

Purity 97%
Melting Point Tm = 116 °C
Appearance Pale pink/beige powder

MSDS Documentation

7-(Diethylamino)-4-(trifluoromethyl)coumarin7-(Diethylamino)-4-(trifluoromethyl)coumarin MSDS Sheet

Literature and Reviews

  1. Remarkable solution and solid-state color-tunable luminescence of diethylamino-coumarin derivatives and application in warm-white LEDs, Y. Chen et al., J. Lumin., 259, 119819(2023); DOI: 10.1016/j.jlumin.2023.119819.
  2. Novel aggregation induced emission based 7-(diethylamino)-3-(4-nitrophenyl)-2H-chromen-2-one for forensic and OLEDs applications, N. Kumar et al., Appl. Surf. Sci., 5, 100095(2021); DOI: 10.1016/j.apsadv.2021.100095.
  3. Redesigning the coumarin scaffold into small bright fluorophores with far-red to Near-infrared emission and large Stokes shifts useful for cell imaging, A. Gandioso et al., J. Org. Chem., 83(3), 1185–1195(2018); DOI: 10.1021/acs.joc.7b02660.
  4. Molecular origins of optoelectronic properties in coumarin dyes: towards designer solar cell and laser applications, X. Liu et al., J. Phys. Chem. A, 116(1), 727–737(2012); DOI: 10.1021/jp209925y.
  5. Red-shifted coumarin luciferins for improved bioluminescence imaging, A. Love et al., J. Am. Chem. Soc., 145(6), 3335–3345(2023); DOI: 10.1021/jacs.2c07220.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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