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Product Code M2300C1-500mg
Price £220 ex. VAT

Low price, high purity 2D metal niobium disulfide powder and crystals

For the development of next-generation electronics, optoelectronics, and nanotechnology

Technical Data | MSDS | Structure | Literature and Reviews | Related Products | Resources and Support

Niobium disulfide (NbS2), CAS number 12034-77-4, is a member of group-V transition metal dichalcogenides (TMDC). Depending the process of exfoliation and film thickness, NbS2 could have three stacking polytypes: 1T (trigonal), 2H (hexagonal), and 3R (rhombohedral) phases. 2H-NbS2 has a sandwiched layer structure, with niobium sitting in the centre half of two sulfur trigonal prismatic sites. Layers are bound by weak van de Waals forces which allows mechanical or liquid chemical exfoliation to obtain layered structures, i.e. nanoparticles or nanosheets with lower dimensions.

High Purity Niobium Disulfide Crystal

High Purity

≥99.999% Niobium Disulfide Crystal

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Low Cost 12034-77-4

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Low Cost Niobium Disulfide

Different Forms of Niobium Disulfide

Powder & Crystal

Different Forms of Niobium Disulfide

2H-NbS2 is metallic in nature with its resistance drop gradually with temperature. Clear superconducting transition is observed when the temperature moves down to 6 K. 2D NbS2 nanosheets possesses a huge number of active edge sites that allows for the application of gas sensing, chemical detection, catalyst for hydrogen evolution reaction (HER), saturable absorber, electrodes and energy storage devices.

We supply low price niobium disulfide in several different forms for a range of applications.

Niobium disulfide powder

Niobium Disulfide Powder

Can be used for preparation of niobium disulfide nanoplates and ultrathin films

Sold by weight

≥99.995% purity

From £220

Niobium disulfide crystals by size

Niobium Disulfide Crystals by Size

Can be used to produce single or few-layer niobium disulfide sheets via mechanical or liquid exfoliation

Small (≥10 mm2) or medium (≥25 mm2) crystals available*

≥99.999% purity

From £520

*Typical representative size, areas/dimensions may vary

Bulk single niobium disulfide crystals are most commonly used as sources from which single or few-layer sheets can be obtained via either mechanical or liquid exfoliation. Single niobium disulfide crystal or films produced from such crystals are suitable for study using atomic force microscopy or transmission electron microscopy.

Niobium disulfide powder can also be used to prepare NbS2 nanosheets and nanoparticles by liquid-exfoliation (normally assisted by sonication), especially when it is the case of foreign elements such as hydrated sodium cations being inserted between layers by the process of intercalation to form [Nax(H2O)yNbS2] complex for application in solid-state batteries. Liquid exfoliation can provide mass production of such products.

Technical Data

CAS number 12136-97-9
Chemical formula NbS2
Molecular weight 157.046 g/mol
Bandgap 0
Preparation Synthetic - Chemical Vapour Transport (CVT)
Structure Hexagonal (2H) and Rhombohedral (3R)
Electronic properties 2D metal and superconductor (2H and 3R phase)
Melting point n.a.
Colour Black
Synonyms Niobium (IV) sulfide, Bis(sulfanylidene)niobium
Classification / Family Transition metal dichalcogenides (TMDCs), 2D semiconductor materials, Charge Density Wave (CDW), Hydrogen Revolution Reactions (HER), Nano-electronics, Nano-photonics, Photovoltaic, Materials science

Product Details

Form Purity
Powder ≥99.995%
Crystal ≥99.999%

Pricing Table

Form Size/Weight* Product Code Price
Powder 500 mg M2300A1 £220
Powder 1 g M2300A1 £350
Crystal  (3R -NbS2) Small (≥10 mm2) M2300C1 £520 ea.
Crystal  (3R -NbS2) Medium (≥25 mm2) M2300C1 £850 ea.

*Typical representative size, areas/dimensions may vary

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MSDS Documents

Niobium disulfide powder MSDSNiobium disulfide powder

Niobium disulfide crystal MSDSNiobium disulfide crystal

Structure of Niobium Disulfide

NbS2 exhibits three stacking polytypes: 1T, 2H, and 3R phases.

The thermodynamically unfavoured 1T phase (space group: 𝑃3̅𝑚1) has one layer with a trigonal unit cell and has only been spotted in monolayer thin films, while the 2H (space group: P63/mmc) and 3R phases (space group: R3m) have two and three layers with hexagonal and rhombohedral unit cells, respectively. 2H and 3R phases have been found in multilayer films or bulk crystal and powder forms. The main difference between 2H and 3R are their stacking sequences: rotation but no in-plane translation in the 2H phase and in-plane translation but no rotation in the 3R phase. 

In its 2H metallic phase, Nb atoms are surrounded by S atoms following a trigonal prismatic coordination with Nb being located in the centre of the trigonal prismatic sites. The S-Nb-S layers that make up each packet are covalently bound. The coupling between pairs of packets is bound by van der Waals forces.

Literature and Reviews

  • Ultrahigh-current-density niobium disulfide catalysts for hydrogen evolution, J. Yang et al., Nat. Mater., 18, pages 1309–1314 (2019); DOI: 10.1038/s41563-019-0463-8.
  • Quantum Enhancement of Charge Density Wave in NbS2 in the Two-Dimensional Limit, R. Bianco et al., Nano Lett., 19, 5, 3098–3103 (2019); DOI: 10.1021/acs.nanolett.9b00504.
  • 2H-NbS2 flm as a novel counter electrode for meso-structured perovskite solar cells, F. Shao et al., Sci. Reports, 8, 7033 (2018); DOI:10.1038/s41598-018-25449-x.

We stock a wide range of 2D materials available to purchase online. Please contact us if you cannot find what you are looking for.

Resources and Support

Viscoelastic Transfer of 2D Material Using PDMS

Viscoelastic transfer using polydimethylsiloxane (PDMS) stamps is one of the methods used for the deterministic placement of 2D materials and the fabrication of van der Waals heterostructures. It relies on the viscoelasticity of PDMS, which behaves as an elastic solid on short time scales, but as a viscous fluid on long time scales.

Learn more...
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