FREE shipping to on qualifying orders when you spend or more, processed by Ossila BV. All prices ex. VAT. Qualifying orders ship free worldwide! Fast, secure, and backed by the Ossila guarantee. It looks like you are visiting from , click to shop in or change country. Orders to the EU are processed by our EU subsidiary.

It looks like you are using an unsupported browser. You can still place orders by emailing us on info@ossila.com, but you may experience issues browsing our website. Please consider upgrading to a modern browser for better security and an improved browsing experience.


Product Code M2402A1-100g
Price $207 ex. VAT

Quality assured

Expert support

Volume discounts

Worldwide shipping

Fast and secure


Spinel LiMn2O4 Powder, Battery Materials

With improved ion transport and power capability as lithium-ion battery cathode material


Lithium manganese oxide (LMO) has a chemical formula of LiMn2O4. It is a promising candidate to replace layered Ni or Co oxide materials as the cathode in lithium-ion batteries for its intrinsic low-cost, environmental friendliness, high abundance, and better safety. Lithium manganese oxide can improve ion transport and power capability especially at high rates with higher nominal voltage (4.0 V) than the benchmark cathode material LiCoO2.

improved ion transport 12057-17-9

High voltage

Improve ion transport at higher rates with High Voltage

Environmentally friendly Lithium Manganese Oxide (LMO) Powder

Environmentally friendly

Improved environmental friendliness

Low Cost Lithium Nickel Manganese Oxide

Low Cost

Intrinsic low-cost

safe 12057-17-9

Safety

Better safety

Lithium manganese oxide has a spinel crystal structure with space group of Fd3m. Closely packed oxygen array allocates cations in octahedral and tetrahedral sites. The same amount of Mn3+ and Mn4+ occupies the octahedral sites while lithium occupies the tetrahedral sites.

lithium manganese oxide crystal structure
Lithium manganese oxide (LiMn2O4) crystal structure, CAS 12057-17-9

Like LiCoO2, LiMn2O4 also suffers from capacity fading caused by a combination of structural transformation and transition metal cation dissolution. The so called Jahn–Teller distortion, occurred at the discharge state of Mn3+, causes a symmetry distortion of the octahedra complex and transforms the spinel into a tetragonal with large anisotropic volume change. The structure distortion is peaked at high current rate when Li+ diffusion rate into the electrolyte is greater than inside the domain of the crystal structure.

Technical Data

CAS Number 12057-17-9
Chemical Formula LiMn2O4
Molecular Weight 180.81 g/mol
Chemical Name Lithium Manganese Oxide
Synonyms Lithium manganese oxide spinel powder
Classification / Family 2D semiconducting materials, Battery materials, Metal oxides, Cathode materials
Colour Black to grey powder

Lithium Manganese Oxide Powder

Product Code M2402A1
Average Particle Size (APS) D50: 23 – 27 μm
Specific Surface Area (SSA) 0.4 – 1.0 m2/g
Coin Cell Capacity 1 C (3.0 – 4.3 V) ~105 mAh/g
True Density 4 – 5 g/cm3
Melting Point 400 °C

MSDS Documents

Lithium Manganese Oxide (LiMn2O4) Powder MSDSLithium Manganese Oxide (LMO) Powder MSDS Sheet

Pricing Table

Product Code Weight Price
M2402A1 100 g £165
M2402A1 250 g £330
M2402A1 500 g £560

*For larger orders please email us to discuss prices.

Literatures

  • High Performance LiMn2O4 Cathode Materials Grown with Epitaxial Layered Nanostructure for Li-Ion Batteries, M. Lee et al., Nano Lett., 14 (2), 993–999 (2014); DOI: 10.1021/nl404430e.
  • High-rate cyclability and stability of LiMn2O4 cathode materials for lithium-ion batteries from low-cost natural β−MnO2, J. Abou-Rjeily et al., Energy Stor. Mater., 26, 423-432 (2020); DOI: 10.1016/j.ensm.2019.11.015.
  • Core-shell structure of LiMn2O4 cathode material reduces phase transition and Mn dissolution in Li-ion batteries, C. Tomon et al., Commun. Chem., 5, 54 (2022): DOI: 10.1038/s42004-022-00670-y.
  • LiMn2O4 spinel and substituted cathodes, M. Thackeray et al., Nat. Energy, 6, 566 (2021); DOI: 10.1038/s41560-021-00815-8.
  • Nano LiMn2O4 as cathode material of high rate capability for lithium ion batteries, W. Tang et al., J. Power Sources, 198, 308-311 (2012); DOI: 10.1016/j.jpowsour.2011.09.106.
  • On the Manganese Dissolution Process from LiMn2O4 Cathode Materials, Y. Tesfamhret et al., ChemElectroChem, 8, 1516–152 (2021); DOI: 10.1002/celc.202001496.
  • Ordered Mesoporous Spinel LiMn2O4 by a Soft-Chemical Process as a Cathode Material for Lithium-Ion Batteries, J. Luo et al., Chem. Mater., 19 (19), 4791–4795 (2007); DOI: 10.1021/cm0714180.
  • Spinel LiMn2O4 nanohybrid as high capacitance positive electrode material for supercapacitors, F. Wang et al., J. Power Source, 246, 19-23 (2014); DOI: 10.1016/j.jpowsour.2013.07.046.
  • Synthesis of Single Crystalline Spinel LiMn2O4 Nanowires for a Lithium Ion Battery with High Power Density, E. Hosono et al., Nano Lett., 9 (3), 1045–1051 (2009); DOI: 10.1021/nl803394v.
  • Improving Thermodynamic Stability of nano-LiMn2O4 for Li-Ion Battery Cathode, K. Nakajima et al., Chem. Mater., 33 (11), 3915–3925 (2021); DOI: 10.1021/acs.chemmater.0c04305.
  • Surface Structure Evolution of LiMn2O4 Cathode Material upon Charge/Discharge, D. Tang et al., Chem. Mater., 26, 535−3543 (2014); DOI: 10.1021/cm501125e.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

Return to the top