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Lithium Nickel Manganese Oxide (LNMO) Powder

CAS Number 12031-75-3

2D Semiconductor Materials, Battery Materials, Cathode Active Materials, Low Dimensional Materials


Product Code M2403A1-50g
Price $182 ex. VAT

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Spinel LiNi0.5Mn1.5O4 Powder, Battery Materials

High voltage, good rate capability and cycling stability as lithium-ion battery cathode material


Lithium Nickel Manganese Oxide (LNMO) is a promising active cathode material for lithium-ion batteries (LIBs) with specific theoretical capacities up to 146.8 mAh g-1, a theoretical energy density of 650 Wh kg-1 and an operating voltage of 4.7 V. (vs. Li/Li+). LNMO can be fully lithiated and delithiated during the processes of charging and discharging without any evident structural change.

With a relatively low cost and excellent thermal stability, LNMO cathode presents great advantages over the conventional LiFePO4 and LiCoO2 cathodes. Also, as one of those cathode materials with a low nickel content, LNMO holds great potential to be deployed in hybrid electrical vehicles (HEVs).

Due to the intrinsically fast lithium cation diffusion within the three-dimensional spinel structure, N-doped LNMO cathode exhibits an impressive rate and the state-of-the-art cycling capability, delivering a high capacity of 103 mA h g-1 at 25 °C after 8000 cycles. Even at a high operating temperature of 60 °C, the capacity retention remains at 92% after 1000 cycles.

High voltage 12031-75-3

High voltage

Operating voltage of 4.7 V

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Low Cost Lithium Nickel Manganese Oxide

Low Cost

Competitive pricing

Thermal stability 12031-75-3 (LNMO) Powder

Stability

Excellent thermal stability

Technical Data

CAS Number 12031-75-3
Chemical Formula LiNi0.5Mn1.5O4
Molecular Weight 660.30 g/mol
Chemical Name Lithium Nickel Manganese Oxide
Synonyms Lithium Manganese Nickel Oxide
Classification / Family 2D semiconducting materials, Battery materials, Metal oxides, Cathode materials
Colour Black to grey powder

Lithium Nickel Manganese Oxide Powder

Product Code M2403A1
Li 4.0 ± 0.2%
Ni 15.1 ± 1%
Mn 44.2 ± 1.2%
BET 0.23 m2/g
Tap Density 1.78 m2/g
Compact Density 3.1 g/cm3
pH 9.22

MSDS Documents

Lithium Nickel Manganese Oxide (LNMO) Powder MSDSLithium Nickel Manganese Oxide (LNMO) Powder MSDS Sheet

Pricing Table

Product Code Weight Price
M2403A1 50 g £145
M2403A1 100 g £230
M2403A1 250 g £460

*For larger orders please email us to discuss prices.

Literatures

  • N-doped engineering of a high-voltage LiNi0.5Mn1.5O4 cathode with superior cycling capability for wide temperature lithium–ion batteries, M. Li et al., Phys. Chem. Chem. Phys., 24, 12214-12225 (2022); DOI: 10.1039/D2CP00835A.
  • On the Composition of LiNi0.5Mn1.5O4 Cathode Active Materials, P. Stuble et al., Adv. Energy Mater., 13 (10), 2203778 (2023); DOI: 10.1002/aenm.202203778.
  • Enhanced rate performance of LiNi0.5Mn1.5O4 fibers synthesized by electrospinning, R. Xu et al., Nano Energy, 15, 616-624 (2015); DOI: 10.1016/j.nanoen.2015.05.023.
  • Long-life LiNi0.5Mn1.5O4/graphite lithium-ion cells with an artificial graphite-electrolyte interface, F. Zhou et al., Energy Stor. Mater., 43, 499-508 (2021); DOI: 10.1016/j.ensm.2021.09.033.
  • Extreme fast charging characteristics of zirconia modified LiNi0.5Mn1.5O4 cathode for lithium ion batteries, U. Nisar et al., J. Power Sources, 396, 774-781 (2018); DOI: 10.1016/j.jpowsour.2018.06.065.
  • Enabling a Co-Free, High-Voltage LiNi0.5Mn1.5O4 Cathode in All-Solid-State Batteries with a Halide Electrolyte, J. Jang et al., ACS Energy Lett., 7, 8, 2531–2539 (2022); DOI: 10.1021/acsenergylett.2c01397.
  • Developing high-voltage spinel LiNi0.5Mn1.5O4 cathodes for high-energy-density lithium-ion batteries: current achievements and future prospects, G. Liang et al., J. Mater. Chem. A, 8, 15373-15398 (2020); DOI: 10.1039/D0TA02812F.
  • Synthesis of LiNi0.5Mn1.5O4 cathode material with improved electrochemical performances through a modified solid-state method, L. Wang et al., Powder Technol., 292, 203-209 (2016); DOI: 10.1016/j.powtec.2016.02.002.
  • Investigation on preparation and performance of spinel LiNi0.5Mn1.5O4 with different microstructures for lithium-ion batteries, Y. Xue et al., Sci. Rep., 5, 13299 (2015); DOI: 10.1038/srep13299.
  • High-Performance LiNi0.5Mn1.5O4 Spinel Controlled by Mn3+ Concentration and Site Disorder, J. Xiao et al., Adv. Mater., 24 (16), 2109-2116 (2012); DOI: 10.1002/adma.201104767.
  • LiNi0.5Mn1.5O4 Hollow Structures as High-Performance Cathodes for Lithium-Ion Batteries, L. Zhou et al., Angew. Chem., Int. Ed., 51 (1), 239-241 (2012); DOI: 10.1002/anie.201106998.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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