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CAS Number 2415951-75-4

Chemistry Building Blocks, COF Ligands, Materials, Porous Organic Frameworks

Product Code B3971-250mg
Price £50 ex. VAT

Covalent Organic Frameworks (COFs) Carbazolyl Ligand

An ethynyl functionalised bridging ligand linker for COFs in application of photocatalysts for organic synthesis and fluorescent detection of nitroexplosives

Specifications | MSDS | Literature and Reviews

1,3,6,8-Tetraethynyl-9H-carbazole (TECz), CAS number 2415951-75-4, has a carbazole core with four ethynyl side arms on 1,3,6,8-positions of carbazole ring. 1,3,6,8-Tetraethynyl-9H-carbazole as a fluorescent probe, is mainly engaged in the synthesis of covalent organic frameworks (COFs) or conjugated microporous polymers (CMPs).

By incorporating ferrocene into 1,3,6,8-tetraethynyl-9H-carbazole building block to promote electron and hole separation and thus accelerate generation of reactive oxygen species (ROS), conjugated microporous polymer, Fc-CBZ-CMP, can sufficiently generate reactive oxygen species (ROS) under visible light. Visible light generated ROS can effectively oxidise thus decompose the pollutants, including organic dyes and chemical warfare agents. Fc-CBZ-CMP significantly outperforms commercially available TiO2 (P25) in the degradation of methylene blue and are capable of converting 2-chloroethyl ethyl sulfide into a completely nontoxic product.

1,3,6,8-tetraethynyl-9-hexyl-9H-carbazole, derivative of 1,3,6,8-tetraethynyl-9H-carbazole, has also been used for fluorescent detection of nitroexplosives, showing great quenching of fluorescence in the presence of nitroexplosive molecules.

MOF and COF ligands

MOF and COF ligands

Ethyne ligand for end-capping COF networks

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High purity 2415951-75-4

High purity

>98% High purity

Facile reactions

Facile reactions

Readily for click reaction and Sonogashira reaction

General Information

CAS Number 2415951-75-4
Chemical Formula C20H9N
Full Name 1,3,6,8-Tetraethynyl-9H-carbazole
Molecular Weight 263.29 g/mol
Synonyms TECz, 9H-Carbazole, 1,3,6,8-tetraethynyl-
Classification / Family Carbazoles, COF ligands

Chemical Structure

2415951-75-4 - 1,3,6,8-tetraethynyl-9H-carbazole chemical structure
21,3,6,8-Tetraethynyl-9H-carbazole (TECz) Chemical Structure, 2415951-75-4.

Product Details

Purity >97%
Melting Point N/A
Appearance Light brown powder/crystals

MSDS Documentation

2415951-75-4 - 1,3,6,8-tetraethynyl-9H-carbazole1,3,6,8-Tetraethynyl-9H-carbazole MSDS Sheet

Literature and Reviews

  1. Ferrocene-Linkage-Facilitated Charge Separation in Conjugated Microporous Polymers, L. Ma et al., Angew. Chem. Int. Ed., 58 (13), 4221-4226 (2019); DOI: 10.1002/anie.201813598.
  2. Recent Progress of Amorphous Porous Organic Polymers as Heterogeneous Photocatalysts for Organic Synthesis, Y. Wang et al., Adv. Funct. Mater., 2307179 (2023); DOI: 10.1002/adfm.202307179.
  3. Highly conjugated carbazole and pyrrolo[1,2-a]quinoxaline based small molecules for fluorescent detection of nitroexplosives, A. Karpe et al., J. Photochem. Photobio. A: Chem., 431, 114004 (2022); DOI: 10.1016/j.jphotochem.2022.114004.
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