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Poly(1,1,1,3,3,3-hexafluoroisopropyl methacrylate-co-glycidyl methacrylate) 90/10

Optoelectronic Materials, Photonic and Optical Materials

Product Code M2368A1-500mg
Price $275 ex. VAT

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Poly(1,1,1,3,3,3-hexafluoroisopropyl methacrylate-co-glycidyl methacrylate), glycidyl methacrylate 10 mol% for cladding layer in optical waveguides

Low refractive index, photocrosslinkable polymer designed for applications in the field of coating and optical electronics

Poly(1,1,1,3,3,3-hexafluoroisopropyl methacrylate-co-glycidyl methacrylate) (HFIPMA-co-GMA) is a random copolymer of hexafluoroisopropyl methacrylate (HFIPMA) and photocrosslinkable glycidyl methacrylate (GMA) repeating units as the backbone. 

Hexafluoroisopropyl methacrylate is super-hydrophobic and corrosion resistive. With glycidyl methacrylate incorporated into the main structure, HFIPMA-co-GMA can be used as a coating agent to improve the stability of stainless steel and to create super-hydrophobic cotton cloth. With its low refractive index, the polymer also finds application in optical electronics, i.e. cladding layer in optical waveguides.

Fluorinated copolymer

Fluorinated copolymer

For optielectronic applications

Hydrophobic and corrosion resistive

Hydrophobic and corrosion resistive

Owing to the hexafluoroisopropyl pendant groups

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High purity

High purity

>98% High purity

Chemical Structure

Poly(1,1,1,3,3,3-hexafluoroisopropyl methacrylate-co-glycidyl methacrylate) chemical structure, HFIPMA
Chemical structure of poly(1,1,1,3,3,3-hexafluoroisopropyl methacrylate-co-glycidyl methacrylate)

General Information

CAS Number N/A
Chemical Formula (C7H6F6O2F6)y(C7H10O3)x
Full Name Poly(1,1,1,3,3,3-hexafluoroisopropyl methacrylate-co-glycidyl methacrylate), glycidyl methacrylate 10 mol%
Purity >98% (1HNMR)
Form White powder/crystals
Solubility Acetone, chlorinated solvents, DMF, MEK, NEP, THF
Melting Point N/A
Synonyms Poly(1,1,1,3,3,3-hexafluoroisopropyl methacrylate-co-2,3-epoxypropyl methacrylate methacrylate), HFIPMA-co-GMA
Composition Glycidyl methacrylate 10 mol %, x = 0.08-0.12, y = 0.88-0.92
Classification / Family Fluoroalkyl Methacrylates, Glycidyl methacrylate copolymers, Cross-linkable polymers, Photonic and optical materials

MSDS Documentation

Poly(1,1,1,3,3,3-hexafluoroisopropyl methacrylate-co-glycidyl methacrylate) MSDSPoly(1,1,1,3,3,3-hexafluoroisopropyl methacrylate-co-glycidyl methacrylate) MSDS Sheet


Batch Quantity Price
M2368A1 500 mg £220
M2368A1 1 g
M2368A1 5 g £1250

Batch details

Batch Mw Mn PDI Stock Info
M2368A1 268,000 124,000 2.1 In stock

Literature and Reviews

  1. Influence of the Composition of Graft Copolymers of Fluoroalkyl Methacrylates on Stability of the Superhydrophobic State of Stainless Steel Surface, V. Klimov et al., Polym. Sci. Ser. B 61, 725–734 (2019); DOI: 10.1134/S156009041906006X.
  2. Graft polymerization of fluoroalkyl methacrylates on the surface of cotton cloth for creation of superhydrophobic materials, E. Bryuzgin et al., Prot Met Phys Chem Surf 53, 248–252 (2017); DOI: 10.1134/S2070205117020071.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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