(4-(1,2,2-Triphenylvinyl)phenyl)methanol
CAS Number 1015082-83-3
Chemistry Building Blocks, COF Ligands, Non-Heterocyclic Building Blocks, Porous Organic Frameworks
Covalent Organic Frameworks (COFs) Tetraphenylethylene Ligand
Used as a building block for macromolecules in the applications of AIE, DSSCs, and liquid crystal materials
Overview | Product Information | MSDS | Related Products
(4-(1,2,2-Triphenylvinyl)phenyl)methanol (CAS number 1015082-83-3) is a tetraphenylethylene building block functionalised with a hydroxymethyl group. Due to its propeller shape, (4-(1,2,2-triphenylvinyl)phenyl)methanol is commonly used for the synthesis of aggregation-induced emission (AIE) macromolecules. The fully conjugated core of (4-(1,2,2-triphenylvinyl)phenyl)methanol makes it ideal for end-capping macromolecules in dyes used for dye-sensitized solar cells (DSSCs). These DSSCs demonstrate a power conversion efficiency of 6.29% and an open-circuit photovoltage of 804 mV.
(4-(1,2,2-Triphenylvinyl)phenyl)methanol is also employed as a pendant group in liquid crystals through ionic interaction. (4-(1,2,2-Triphenylvinyl)phenyl)methanol-liquid crystal exhibits polarized fluorescent emission at 475 nm (excitation at 360 nm).
MOF and COF Ligands
Tetraphenylethylene ligand for COF/MOF networks
AIE Material
Propeller-shaped molecular structure
High Purity
>97% pure
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General Information
| CAS Number | 1015082-83-3 |
|---|---|
| Chemical Formula | C27H22O |
| Full Name | [4-(Triphenylvinyl)phenyl]methanol |
| Molecular Weight | 362.46 g/mol |
| Synonyms | 4-(1,2,2-Triphenylethenyl)benzenemethanol, [4-(1,2,2-triphenylethenyl)phenyl]methanol, TPE-MeOH |
| Classification or Family | Porous organic frameworks, COFs, Macromolecules, AIEs, DSSCs, Liquid crystals |
Chemical Structure
Product Details
| Purity | > 97% |
|---|---|
| Melting Point | N/A |
| Appearance | White powder |
MSDS Documentation
(4-(1,2,2-Triphenylvinyl)phenyl)methanol MSDS Sheet
References
- Endo- and Exo-functionalized tetraphenylethylene M12L24 nanosphere fluorescence emission inside a confined space, X. Yan et al., J. Am. Chem. Soc., 141 (24), 9673–9679 (2019); DOI: 10.1021/jacs.9b03885.
- Effect of polyphenyl-substituted ethylene end-capped groups in metal-free organic dyes on performance of dye-sensitized solar cells, C. Chen et al., RSC Advances, 2, 7788–7797 (2021); DOI: 10.1039/c2ra20819a.
- The impact of aggregation of AIE and ACQ moiety-integrating material on the excited state dynamic, G.-Y. Wu et al., RSC Adv., 13, 33911 (2023); DOI: 10.1039/d3ra06359c.
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