2,4,6-Tris(4-hydrazinylphenyl)-1,3,5-triazine
CAS Number 804548-56-9
Chemistry Building Blocks, COF Ligands, Heterocyclic Building Blocks, Monomers, Porous Organic Frameworks
Covalent Organic Frameworks (COFs) Triazine Ligand
Triangular hydrazine bridging ligand for the synthesis of COFs in the applications of dye absorption and photocatalytic reactions.
Overview | Product Information | Related Products
2,4,6-Tris(4-hydrazinylphenyl)-1,3,5-triazine (CAS number 804548-56-9) is a ligand for covalent organic frameworks (COFs), featuring a triazine core and three hydrazinophenyl groups. With three reaction sides, 2,4,6-tris(4-hydrazinylphenyl)-1,3,5-triazine can form highly cross-linked COFs with ketone/aldehyde derivatives. The resulting COFs have hydrazone linkages, exhibiting a coplanar structure. These COFs have relatively weak interlayer interactions, which allows them to be exfoliated into 2D polymer sheets.
2,4,6-Tris(4-hydrazinylphenyl)-1,3,5-triazine reacts with 4,4',4''-(1,3,5-triazine-2,4,6-triyl)tribenzaldehyde, yielding a COF with pore volume of 0.434 cm3/g and surface area of 458 m2/g. The resulting COF shows high absorption ability for methyl orange due to the hydrogen bonding interaction between the hydrazone linker and the azo groups of methyl orange.
MOF and COF ligands
hydrazine ligand for cross-linked COF/MOF networks
Facile reactions
Hydrazine possesses excellent reactivity
High purity
> 97% pure
Worldwide shipping
Quick and reliable shipping
General Information
| CAS Number | 804548-56-9 |
|---|---|
| Chemical Formula | C21H21N9 |
| Full Name | 2,4,6-Tris(4-hydrazinophenyl)-1,3,5-triazine |
| Molecular Weight | 399.45 g/mol |
| Synonyms | Tris(4-hydrazinylphenyl)-1,3,5-triazine |
| Classification or Family | COFs, Trihydrazines, Triazines |
Chemical Structure
Product Details
| Purity | ≥ 97% |
|---|---|
| Melting Point | N/A |
| Appearance | Pale orange powder |
MSDS Documentation
2,4,6-Tris(4-hydrazinophenyl)-1,3,5-triazine MSDS Sheet
References
- Covalent organic frameworks: fundamentals, mechanisms, modification, and applications in photocatalysis, Z. Liang et al., Chem. Catalysis, 2, 2157–2228 (2022); DOI: 10.1016/j.checat.2022.06.006.
- Covalent organic framework photocatalysts: structures and applications, H. Wang et al., Chem. Soc. Rev., 49, 4135–4165 (2020); DOI:10.1039/D0CS00278J.
- Targeted synthesis of visible-light-driven covalent organic framework photocatalyst via molecular design and precise construction, S. He et al., Appl. Catal., B, 239, 147–153 (2018); DOI: 10.1016/j.apcatb.2018.08.005.
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