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Photoelectrochemical H-Cell (PECs) With Water Bath

High quality photoelectrochemical H-cell for electrochemistry studies, Jacketed photoelectrochemical cell, Double layer photoelectrochemical cell, JGS2 Quartz 0.220-2.5 (μm)


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Photoelectrochemical (PEC) H-cell with water bath is a device that allows photocatalytic reactions to convert light energy into chemical energy or electricity.

The cell features two independent, gastight high quality borosilicate glass chambers that are bridged but also well separated by an ion-exchange membrane (e.g., Nafion) to prevent the mixing of anodic and cathodic products from different chambers. The cell allows the optical access with a quartz window (commonly 20-24 mm in diameter) for uniform illumination of the photoelectrode. The integrated water jacket around the gastight chambers enables connection to an external circulating water bath, allowing the temperature to be controlled during the experiment.

This configuration is useful during long-term stability testing where the long exposure to the light source may heat the apparatus altering the kinetics of the electrochemical reaction. The water bath ensures high accuracy and the repeatability of the experiments.

Additionally, it is sometimes necessary to conduct experiments at the elevated temperatures to increase the kinetics of the electrochemical reaction or to achieve a reasonable ion transport across the membrane. The temperature of the cell can be well maintained using a water bath PEC.

Separate Electrodes

Avoid cross-contamination with ion-membrane diffusion

Temperature Control

Isolated water bath for sensitive experiments

Transparent Window(s)

Enabling in-situ observation of photocatalytic reactions

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Note: The quoted volume (100 ml) is the total volume across the H-cell set up needs to fill up to the bridge, therefore each half-cell has a volume of about 50-60 ml.

Specifications


All dimensions are in millimeters.

Dimensions

H-Type Photoelectrochemical Cell with Optical Window Specifications
Port Diameter
Gas Inlet/Outlet Ports 3 mm
Electrode Ports 6.5 mm
Sampling Window 3 mm
Membrane Inner - 15.5 mm, Outer - 40 mm
Optical Window Inner - 24 mm, Outer - 40 mm

In the photoactive half cell, there are:

  • Two electrode ports (6 mm) for working and reference electrode
  • One sampling window
  • Gas inlets/outlets tubes in both cells (3 mm)

In the other half cell, there are:

  • One electrode port (6 mm) for counter electrode
  • Gas inlets/outlets tubes in both cells (3 mm)

Screw fit lids, secure screws and O-ring seals for all ports to ensure an airtight operation. A luggin capillary is also provided with the cell along with a gas bubbler for both chambers, supporting accurate and stable measurements.

Volume

Product Code Half-cell Volume (Bridge*) Half-cell Volume (Window*) Half-cell Volume (Thread*) Half-cell Volume (Full)
C2017W1 50 ml (left), 40 ml (right) 70 ml (left), N/A (right) 90 ml (left), 80 ml (right) 105 ml (left), 90 ml (right)

*The volume of the half-cell is measured with liquid filled above the H-cell bridge (notation: Bridge), filled above the optical window (notation: Window), filled till the thread (notation: Thread) and filled till the cell is full (notation: Full). Left refers to the half cell with an optical window; right refers to the half-cell without an optical window.

Pricing and Options


Product Name Product Code Price
Photoelectrochemical H-cell With Water Bath - 100 ml C2017W1 £980


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