FL3N-2BAPE

CAS Number 953390-94-8

Boronates, Chemistry Building Blocks, Materials, Monomers

Amine functionalized fluorine boronic ester

A versatile building block for the synthesis of conjugated semiconducting polymer containing fluorine unit, FL3N-2BAPE, 3,3'-(2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-fluorene-9,9-diyl)bis(N,N-dimethylpropan-1-amine), CAS 953390-94-8

Specifications | MSDS | Literature and Reviews

FL3N-2BAPE is a fluorene derivative that bears the functionalities of two N,N-dimethylpropan-1-amines and two boronic acid pinacol esters. FL3N-2BAPE, produced from 2,7-dibromo-9,9-bis[3,3'-(N,N-dimethylamino)-propyl]fluorene, is a convenient monomer building block for the synthesis of oligomers and polymer semiconductors via Suzuki coupling reaction.

Fluorine Boronic Ester

Monomer for conjugated semiconducting polymer synthesis

Worldwide Shipping

Quick and reliable shipping

High Purity

>98% high purity material

Facile Reactions

Ideal for boronic esterification and Suzuki reactions

FL3N-2BAPE can be used for the synthesis of poly [(9,9-bis(3'-(N,N-dimethylamino)propyl)-2,7-fluorene)-alt-2,7-(9,9–dioctylfluorene)] (PFN) and poly[2,7-bis(2-ethylhexyl)-1,2,3,6,7,8-hexahydro-1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-4,9-diyl]-2,5-thiophenediyl(9,9-bis[3-(dimethylamino)propyl]-9H-fluorene-2,7-diyl)-2,5-thiophenediyl] (PNDIT-F3N). Both PFN and PNDIT-F3N are well recognized electron transport layer (ETL) materials that are engaged in highly efficient photovoltaic solar cells as the interface between the photoactive layer and the electrode.

General Information

CAS Number	953390-94-8
Chemical Formula	C₃₅H₅₄B₂N₂O₄
Full Name	3,3'-(2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-fluorene-9,9-diyl)bis(N,N-dimethylpropan-1-amine)
Molecular Weight	588.4363 g/mol
Synonyms	FL3N-2BAPE, F3N
Classification or Family	Fluorine, Boronic acid pinacol ester, Monomer, Polymer semiconductor

Chemical Structure

fl3n-2bape - 953390-94-8 - 3,3'-(2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-fluorene-9,9-diyl)bis(N,N-dimethylpropan-1-amine) — FL3N-2BAPE - 3,3'-(2,7-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-fluorene-9,9-diyl)bis(N,N-dimethylpropan-1-amine) Chemical Structure, 953390-94-8

Product Details

Purity	> 98%
Melting Point	-
Appearance	White to off-white powder/crystals

MSDS Documentation

FL3N-2BAPE MSDS Sheet

Literature and Reviews

Y. Li et al. (2022); An n-n Heterojunction Configuration for Efficient Electron Transport in Organic Photovoltaic Devices, Adv. Funct. Mater., 33 (9), 2209728; DOI: 10.1002/adfm.202209728.
Y. Qin et al. (2021); 18.4% efficiency achieved by the cathode interface engineering in non-fullerene polymer solar cells, Nanotoday, 41, 101289; DOI: 10.1016/j.nantod.2021.101289.
Z. Wu et al. (2016); n-Type Water/Alcohol-Soluble Naphthalene Diimide-Based Conjugated Polymers for High-Performance Polymer Solar Cells, J. Am. Chem. Soc., 138 (6), 2004-2013; DOI: 10.1021/jacs.5b12664.