BD-1
CAS Number 1252914-27-4
Blue Dopant Materials, Dopant Materials, High Purity Sublimed Materials, OLED Materials, Semiconducting Molecules
Fluorescent Blue Emitter of Pyrene Derivative
Used in highly efficient fluorescent top-emission organic light-emitting diodes, N1,N6-bis(dibenzo[b,d]furan-4-yl)-3,8-diisopropyl-N1,N6-bis(4-isopropylphenyl)pyrene-1,6-diamine, CAS No. 1252914-27-4, Sublimed ≥99.0%
Product Information | MSDS | Related Products
BD-1 is symmetrically structured with a 3,8-diisopropyl-1,6-diamine-pyrene core, and two dibenzo[b,d]furan and 4-isopropylphenyl peripheral end groups. Four isopropyl alkyl groups not only promotes greater solubility but also prevents the quenching of the excimers.
BD-1 is a fluorescent blue emitter and normally an anthracene derivative 1,2-ADN is selected as effective host for BD-1 for improving the external quantum efficiency (EQE) of fluorescent OLEDs by utilizing triplet–triplet annihilation. Top-emission organic light-emitting diodes (TEOLEDs) utilizing BD-1 as the blue emitting layer material without indium tin oxide (ITO) but a silver (Ag) layer demonstrated a high efficiency of 139.9 cd/A/CIEy at a current density of 10 mA/cm2 [1, 2].
General Information
| CAS number | 1252914-27-4 |
|---|---|
| Chemical formula | C64H56N2O2 |
| Molecular weight | 885.14 g/mol |
| HOMO/LUMO | HOMO = - 5.52 eV, LUMO = - 2.78 eV |
| Chemical name | N1,N6-bis(dibenzo[b,d]furan-4-yl)-3,8-diisopropyl-N1,N6-bis(4-isopropylphenyl)pyrene-1,6-diamine |
| Synonyms | BDFDPPDA, NFDIP, TCNBD03 |
| Classification / Family | Pyrene derivatives, Triarylamines, Blue fluorescent emitter, Sublimed materials, Semiconducting small molecules |
Product Details
| Purity | Sublimed* >99.0% (HPLC) |
|---|---|
| Melting point | n.a. |
| Appearance | Off-white powder/crystals |
* Sublimation is a technique used to obtain ultra pure-grade chemicals, see sublimed materials for OLED devices.
Chemical Structure
Device Structure(s)
| Device structure | ITO (70 nm)/Clevios HIL 1.3 N (10 nm)/HAT-CN (5 nm)/Specific HTL (30 nm)/1,2-ADN:BD-1 (5 wt%, 25 nm)/1,2-ADN (25 nm)/Py-hpp2 (1 nm)/Al [1] |
|---|---|
| Color |
 Blue |
| Max. EQE | 9.3% |
| Max. Current Efficiency | 11.0 cd/A |
| LT95 (hours) | 646 |
| Device structure | ITO (70 nm)/Clevios HIL 1.3 N (10 nm)/HAT-CN (5 nm)/Specific HTL (30 nm)/1,2-ADN:BD-1 (5 wt%, 25 nm)/DBzA:Liq (1:1, 25 nm)/Liq (1 nm)/Al [1] |
|---|---|
| Color |
Blue |
| Max. EQE | 9.5% |
| Max. Current Efficiency | 11.5 cd/A |
| LT50 (hours) | 1325 |
Pricing
| Grade | Order Code | Quantity | Price |
|---|---|---|---|
| Sublimed (>99.0% purity) | M2222A1 | 100 mg | £219 |
| Sublimed (>99.0% purity) | M2222A1 | 250 mg | £438 |
| Sublimed (>99.0% purity) | M2222A1 | 500 mg | £700 |
| Sublimed (>99.0% purity) | M2222A1 | 1 g | £1120 |
MSDS Documentation
BD-1 MSDS sheetLiterature and Reviews
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Effects of Energy-Level Alignment on Operating Voltages of Blue Organic Light-Emitting Diodes, T. Sasaki et al., Adv. Mater. Interfaces, 2201925 (2022); DOI: 10.1002/admi.202201925.
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Electron blocking materials based on dimethyl-dihydrobenzofuran derivatives for highly efficient and long-lifetime blue fluorescent organic light-emitting diodes, B. Hu et al., Org. Electron., 87, 105916 (2020); DOI: 10.1016/j.orgel.2020.105916.
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Fabrication of highly efficient blue top-emission organic light-emitting diodes on different reflective electrodes, Z. Ci et al., Org. Electron., 95, 106197 (2021); DOI: 10.1016/j.orgel.2021.106197.
- High-refractive-index capping layer improves top-light-emitting device performance, B. Hu et al., Appl. Opt., 59 (13), 4114-4121 (2020); DOI: 10.1364/AO.391419.
