FREE shipping to on qualifying orders when you spend or more, processed by Ossila BV. All prices ex. VAT. Qualifying orders ship free worldwide! Fast, secure, and backed by the Ossila guarantee. It looks like you are visiting from , click to shop in or change country. Orders to the EU are processed by our EU subsidiary.

It looks like you are using an unsupported browser. You can still place orders by emailing us on, but you may experience issues browsing our website. Please consider upgrading to a modern browser for better security and an improved browsing experience.


CAS Number 1221509-80-3

Carbaldehyde Monomers, COF Ligands, Materials, Porous Organic Frameworks

Product Code B4611-1g
Price £85 ex. VAT

Covalent Organic Frameworks (COFs) Triazine Ligand

A trigonal ligand linker for covalent polymeric frameworks (CPFs) in application of heterogeneous catalyst, photocatalyst for hydrogen evolution reactions (HERs), sensors and energy storage devices 

Specifications | MSDS | Literature and Reviews

4',4''',4'''''-(1,3,5-triazine-2,4,6-triyl)tris([1,1'-biphenyl]-4-carbaldehyde) (TFBPTz) is triangularly shaped with three 4-formylbiphenyl units sitting on a central triazine core.

Porous crystalline bipyridine-based Bpy-COF, constructed from Schiff base condensation of 4',4''',4'''''-(1,3,5-triazine-2,4,6-triyl)tris([1,1'-biphenyl]-4-carbaldehyde) and 5,5'-diamino-2,2'-bipyridine, shows great BET surface area of 1864 m2 g−1 with uniform mesopore  size of 4.0 nm. With retained ordered porous structure, copper loaded Cu(I)-Bpy-COF heterogeneous catalyst demonstrates high conversion rate of cycloaddition reactions within a short time of 40 min at 25 °C in water medium. POP-2, a COF with sp2-C linkage derived from 4',4''',4'''''-(1,3,5-triazine-2,4,6-triyl)tris([1,1'-biphenyl]-4-carbaldehyde) shows a dual response of colour and fluorescence under acidic conditions. It exhibits a red shift of nearly 100 nm in aqueous hydrochloric acid at a concentration of 1 M.

MOF and COF ligands

MOF and COF ligands

Aldehyde ligand for cross-linked COF networks

Worldwide shipping for 910231-21-9

Worldwide shipping

Quick and reliable shipping

High purity 910231-21-9

High purity

>97% High purity

Facile reactions

Facile reactions

Readily for polycondensation to form imine COF linkages

Ionic vinylene-linked 2D covalent organic framework TFBPTz-ETMP-COF, obtained by a quaternization-promoted Knoevenagel condensation between N-ethyl-2,4,6-trimethylpyridinium halide and 4',4''',4'''''-(1,3,5-triazine-2,4,6-triyl)tris(([1,1'-biphenyl]-4-carbaldehyde)), shows  high crystallinity and BET surface areas of 1343 m2 g−1. The positively charged COF can be uniformly composited with linear polyethylene oxide and lithium salt, displaying ionic conductivity as high as 2.72×10−3 S cm−1.

Highly crystalline, π-conjugated, and hydrophilic ionic covalent organic frameworks ZVCOF-2, a COF obtained from N-(3-sulfopropyl)-2,4,6-(trimethyl)pyridinium, inner salt (PSTMP) and TFBPTz with a green hydrothermal approach, shows an ultrahigh sacrificial photocatalytic hydrogen evolution rate of 2052 μmol h–1 under visible light irradiation with an apparent quantum yield up to 47.1% at 420 nm.

General Information

CAS Number 1221509-80-3
Chemical Formula C42H27N3O3
Full Name 4',4''',4'''''-(1,3,5-Triazine-2,4,6-triyl)tris([1,1'-biphenyl]-4-carbaldehyde)
Molecular Weight 621.68 g/mol
Synonyms TFBPTz, TABPT, 1,3,5-Tris-(4′-formyl-biphenyl-4-yl)triazine,  2,4,6-Tri-(4-formyl-biphenyl-4-yl)-1,3,5-triazine 
Classification / Family Triazines, Aldehydes, COF ligands

Chemical Structure

1221509-80-3 - 4',4''',4'''''-(1,3,5-triazine-2,4,6-triyl)tris([1,1'-biphenyl]-4-carbaldehyde)
4',4''',4'''''-(1,3,5-Triazine-2,4,6-triyl)tris([1,1'-biphenyl]-4-carbaldehyde) (TFBPTz) Chemical Structure, 1221509-80-3

Product Details

Purity > 97%
Melting Point n.a.
Appearance Off-white powder/crystals

MSDS Documentation

1221509-80-3 - 4',4''',4'''''-(1,3,5-triazine-2,4,6-triyl)tris([1,1'-biphenyl]-4-carbaldehyde)4',4''',4'''''-(1,3,5-Triazine-2,4,6-triyl)tris([1,1'-biphenyl]-4-carbaldehyde) MSDS Sheet

Literature and Reviews

  1. Copper Dispersed Covalent Organic Framework for Azide–Alkyne Cycloaddition and Fast Synthesis of Rufinamide in Water, F. Xue et al., Small, 2307796 (2024); DOI: 10.1002/smll.202307796.
  2. Trimethyltriazine-derived olefin-linked covalent organic framework with ultralong nanofibers, F. Zhang et al., Sci. Bull., 65 (19), 1659-1666 (2020); DOI: /10.1016/j.scib.2020.05.033.
  3. A fast acid-responsive fluorescent porous polymer for acid-modified gas detection and optical anti-counterfeiting, W. Zhong et al., Eur. Polym, J. 193, 112102 (2023); DOI: 10.1016/j.eurpolymj.2023.112102.
Return to the top