4,4',4''-(Benzene-1,3,5-triyltris(ethyne-2,1-diyl))tribenzaldehyde

CAS Number 2289758-98-9

Carbaldehyde Monomers, Chemistry Building Blocks, COF Ligands, Materials, Monomers, Porous Organic Frameworks

4,4',4''-(Benzene-1,3,5-triyltris(ethyne-2,1-diyl))tribenzaldehyde MSDS

4,4',4''-(Benzene-1,3,5-triyltris(ethyne-2,1-diyl))tribenzaldehyde CAS 2289758-98-9

Covalent Organic Frameworks (COFs) Phenylethynylbenzene Ligand

A formyl functional ligand linker for COFs in application of carbon dioxide reduction and photocatalytic H₂O₂ production

Overview
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C3-type electron-rich monomer 4,4',4''-(Benzene-1,3,5-triyltris(ethyne-2,1-diyl))tribenzaldehyde (BTETBA), CAS number 2289758-98-9, is consisted of three 4-formylphenylethynyl functional groups sitting on the meta positions of a benzene ring.

Metal-free covalent organic framework, BTETBA-COF was obtained by incorporating ethynyl groups into the conjugated skeleton. The bridging with the ethynyl groups afforded a significant improvement in π-conjugation and photogenerated charge separation and transfer, promoting CO₂ photoreduction in a solid-gas mode with only water vapor and CO₂. The CO production rate with BTETBA-COF as the photocatalyst reached as high as 382.0 µmol g⁻¹ h⁻¹, ranking as one of the best among all additive-free CO₂ photoreduction catalysts. Another BTETBA-TRz-COF, with spatially separated triazine and acetylene units, was engaged for photocatalytic H₂O₂ production. The spatial separation of triazine and acetylene cores leads to efficient charge separation and suppressed charge recombination, and carbon-carbon double bond linkage facilitates electrons transport over the skeletons.

MOF and COF ligands

Aldehyde ligand for cross-linked COF networks

Worldwide shipping

Quick and reliable shipping

High purity

>97% High purity

Facile reactions

Aldehyde possesses excellent reactivity

General Information

CAS Number	2289758-98-9
Chemical Formula	C₃₃H₁₈O₃
Full Name	4,4',4''-(Benzene-1,3,5-triyltris(ethyne-2,1-diyl))tribenzaldehyde
Molecular Weight	462.49 g/mol
Synonyms	BTETBA, BTEA, TPEB-CHO, BTTA, 1,3,5-tris(4-formylphenylethynyl)benzene
Classification / Family	Phenylethynylbenzene, COF ligands

Chemical Structure

Product Details

Purity	>97%
Melting Point	N/A
Appearance	White to off-white powder to fibres/crystals

MSDS Documentation

4,4',4''-(Benzene-1,3,5-triyltris(ethyne-2,1-diyl))tribenzaldehyde MSDS Sheet

Literature and Reviews

Constructing Synergistic Triazine and Acetylene Cores in Fully Conjugated Covalent Organic Frameworks for Cascade Photocatalytic H2O2 Production, L. Zhao et al., Chem. Mater., 34 (11), 5232–5240 (2022); DOI: 10.1021/acs.chemmater.2c00910.
Regulating π-Conjugation in sp2-Carbon-Linked Covalent Organic Frameworks for Efficient Metal-Free CO2 Photoreduction with H2O, L. Yang et al., Small, 19 (27), 2208118 (2023); DOI: 10.1002/smll.202208118.
Engineering active sites in two dimensional covalent organic frameworks boosts the capture of iodine, L. Yang et al., Sep. Purif. Technol., 328, 125054 (2024); DOI: 10.1016/j.seppur.2023.125054.
A general design approach toward covalent organic frameworks for highly efficient electrochemiluminescence, Y. Li et al., Nat. Commun., 12, 4735 (2021); DOI: 10.1038/s41467-021-25013-8.
Metal–organic frameworks and covalent organic frameworks as photocatalysts for H2O2 production from oxygen and water, J. Sun et al., J. Mater. Chem. A,11, 21516-21540 (2023); DOI: 10.1039/D3TA04581A.

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