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4,4',4''-(Benzene-1,3,5-triyltris(ethyne-2,1-diyl))tribenzaldehyde

CAS Number 2289758-98-9

Carbaldehyde Monomers, Chemistry Building Blocks, COF Ligands, Monomers, Porous Organic Frameworks


Product Code B3831-500mg
Price $138 ex. VAT

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Covalent Organic Frameworks (COFs) Phenylethynylbenzene Ligand

A formyl functional ligand linker for COFs in application of carbon dioxide reduction and photocatalytic H2O2 production


C3-type electron-rich monomer 4,4',4''-(Benzene-1,3,5-triyltris(ethyne-2,1-diyl))tribenzaldehyde (BTETBA) is consisted of three 4-formylphenylethynyl functional groups sitting on the meta positions of a benzene ring.

Metal-free covalent organic framework, BTETBA-COF was obtained by incorporating ethynyl groups into the conjugated skeleton. The bridging with the ethynyl groups afforded a significant improvement in π-conjugation and photogenerated charge separation and transfer, promoting CO2 photoreduction in a solid-gas mode with only water vapor and CO2. The CO production rate with BTETBA-COF as the photocatalyst reached as high as 382.0 µmol g−1 h−1, ranking as one of the best among all additive-free CO2 photoreduction catalysts. Another BTETBA-TRz-COF, with spatially separated triazine and acetylene units, was engaged for photocatalytic H2O2 production. The spatial separation of triazine and acetylene cores leads to efficient charge separation and suppressed charge recombination, and carbon-carbon double bond linkage facilitates electrons transport over the skeletons.

MOF and COF ligands

MOF and COF ligands

Aldehyde ligand for cross-linked COF networks

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High purity 2289758-98-9

High purity

>97% High purity

Facile reactions

Facile reactions

Aldehyde possesses excellent reactivity

General Information

CAS Number 2289758-98-9
Chemical Formula C33H18O3
Full Name 4,4',4''-(Benzene-1,3,5-triyltris(ethyne-2,1-diyl))tribenzaldehyde
Molecular Weight 462.49 g/mol
Synonyms BTETBA, BTEA, TPEB-CHO, BTTA, 1,3,5-tris(4-formylphenylethynyl)benzene
Classification / Family Phenylethynylbenzene, COF ligands

Chemical Structure

2289758-98-9 - 4,4',4''-(benzene-1,3,5-triyltris(ethyne-2,1-diyl))tribenzaldehyde chemical structure
4,4',4''-(Benzene-1,3,5-triyltris(ethyne-2,1-diyl))tribenzaldehyde (BTETBA) Chemical Structure, 2289758-98-9

Product Details

Purity >97%
Melting Point N/A
Appearance White to off-white powder to fibres/crystals

MSDS Documentation

4,4',4''-(Benzene-1,3,5-triyltris(ethyne-2,1-diyl))tribenzaldehyde4,4',4''-(Benzene-1,3,5-triyltris(ethyne-2,1-diyl))tribenzaldehyde MSDS Sheet

Literature and Reviews

  1. Constructing Synergistic Triazine and Acetylene Cores in Fully Conjugated Covalent Organic Frameworks for Cascade Photocatalytic H2O2 Production, L. Zhao et al., Chem. Mater., 34 (11), 5232–5240 (2022); DOI: 10.1021/acs.chemmater.2c00910.
  2. Regulating π-Conjugation in sp2-Carbon-Linked Covalent Organic Frameworks for Efficient Metal-Free CO2 Photoreduction with H2O, L. Yang et al., Small, 19 (27), 2208118 (2023); DOI: 10.1002/smll.202208118.
  3. Engineering active sites in two dimensional covalent organic frameworks boosts the capture of iodine, L. Yang et al., Sep. Purif. Technol., 328, 125054 (2024); DOI: 10.1016/j.seppur.2023.125054.
  4. A general design approach toward covalent organic frameworks for highly efficient electrochemiluminescence, Y. Li et al., Nat. Commun., 12, 4735 (2021); DOI: 10.1038/s41467-021-25013-8.
  5. Metal–organic frameworks and covalent organic frameworks as photocatalysts for H2O2 production from oxygen and water, J. Sun et al., J. Mater. Chem. A,11, 21516-21540 (2023); DOI: 10.1039/D3TA04581A.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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