1,2,4,5-Tetrakis(4-formylphenyl)benzene
CAS Number 883835-33-4
Carbaldehyde Monomers, Chemistry Building Blocks, COF Ligands, Materials, Monomers, Porous Organic Frameworks
Covalent Organic Frameworks (COFs) Terphenyl Ligand
A formyl functional ligand linker for COFs in application of iodine uptake, photocatalytic hydrogen evolution (PHE), high-performance supercapacitors and heterogeneous catalysis
Specifications | MSDS | Literature and Reviews
1,2,4,5-Tetrakis(4-formylphenyl)benzene (TFPB), CAS number 883835-33-4, is a cross-like terphenyl linker with four 4-formylphenyl functional groups attached to a benzene ring at 1,2,4,5-positions.
Constructed by the condensation reaction between 2,5-diaminobenzene-1,4-dithiol (DABDT) and 1,2,4,5-tetrakis-(4-formylphenyl)benzene, thiol-decorated covalent organic framework SH-COF-2 showed a high surface area of 227 m2 g−1 and enhanced electrochemical performance with a capacitance of 118 mF cm−2 and a capacitance retention >95% after 1000 cycles.
Highly conjugated two-dimensional covalent organic framework TFPB-PyTTA-COF, alternating 4,4',4'',4'''-(pyrene-1,3,6,8-tetrayl)tetraaniline (PyTTA) as the nodes and 1,2,4,5-tetrakis(4-formylphenyl)benzene as the bridging linker units, possessed high chemical and physical stability. TFPB-PyTTA-COF exhibited an excellent iodine uptake value of up to 5.6 g g−1, superior to most reported COF-based adsorbents for the adsorption of iodine.
COF-TPE-TPB-B, obtained via a [4 + 2] pathway with unreacted dangling formyl groups from the monomers TFPB and 1,1,2,2-tetra(4-aminophenyl)ethylene (TPE-NH2), exhibited photocatalytic hydrogen evolution (PHE) activity with improved hydrophilicity and better charge separation and transportation.
MOF and COF ligands
Aldehyde ligand for cross-linked COF networks
Worldwide shipping
Quick and reliable shipping
High purity
>98% High purity
Facile reactions
Aldehyde possesses excellent reactivity
General Information
| CAS Number | 883835-33-4 |
|---|---|
| Chemical Formula | C34H22O4 |
| Full Name | 1,2,4,5-Tetrakis(4-formylphenyl)benzene |
| Molecular Weight | 494.54 g/mol |
| Synonyms | TFPB, 4-[2,4,5-Tris(4-formylphenyl)phenyl]benzaldehyde, [1,1:2,1-Terphenyl]-4,4-dicarboxaldehyde,4,5-bis(4-formylphenyl)- |
| Classification / Family | Terphenyl, COF ligands |
Chemical Structure
Product Details
| Purity | >98% |
|---|---|
| Melting Point | 152°C ~ 156 °C |
| Appearance | White or off-white powder/crystals |
MSDS Documentation
1,2,4,5-tetrakis(4-formylphenyl)benzene MSDS Sheet
Literature and Reviews
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Thiol-decorated covalent organic frameworks as multifunctional materials for high-performance supercapacitors and heterogeneous catalysis, D. Pakulski et al., J. Mater. Chem. A, 10, 16685-16696 (2022); DOI: 10.1039/D2TA03867F.
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Synthesis of a magnetic covalent organic framework as sorbents for solid-phase extraction of aflatoxins in food prior to quantification by liquid chromatography-mass spectrometry, L. Li et al., Food Chem., 387, 132821 (2022); DOI: 10.1016/j.foodchem.2022.132821.
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Platinum Nanoparticles Uniformly Dispersed on Covalent Organic Framework Supports for Selective Synthesis of Secondary Amines, N. Wang et al., ChemCatChem, 14 (5), e202101587 (2022); DOI: 10.1002/cctc.202101587.