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CAS Number 425629-22-7

Chemistry Building Blocks, COF Ligands, Materials, Porous Organic Frameworks

Product Code B3781-1g
Price £80 ex. VAT

Covalent Organic Frameworks (COFs) Triazine Ligand

An ethynyl ligand linker for COFs in application of carbon dioxide and hydrogen adsorption, aggregation-induced electrochemiluminescence, photocatalyst and sensors

Specifications | MSDS | Literature and Reviews

2,4,6-Tris(4-ethynylphenyl)-1,3,5-triazine (TEPT), CAS number 425629-22-7, featuring a nitrogen rich electron deficient triazine core with three 4-ethynylphenyl side arms. The ethynyl functional groups extend the structure by forming covalent organic frameworks (COFs) via Sonogashira–Hagihara cross-coupling reaction, or by click polymerisation reaction with azides to form microporous organic polymers.

Obtained from 2,4,6-tris(4-ethynylphenyl)-1,3,5-triazine unit and aromatic azide linkers by click polymerization reaction, microporous organic polymer CMOP-1 exhibited a Brunauer–Emmett–Teller (BET) surface area of 431 m2·g−1 and a narrow pore size distribution under 1.2 nm. CMOP-1 demonstrated a superior CO2 uptake level of 1.85 mmol·g−1 at 273 K/1.0 bar, H2 uptake of up to 2.94 mmol·g−1 at 77 K/1.0 bar, and I2 vapor adsorption load of 160 wt.%, owing to the rich nitrogen content.

MOF and COF ligands

MOF and COF ligands

Ethyne ligand for cross-linked COF networks

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High purity 425629-22-7

High purity

>98% High purity

Facile reactions

Facile reactions

Readily for click reaction and Sonogashira reaction

General Information

CAS Number 425629-22-7
Chemical Formula C27H15N3
Full Name 2,4,6-Tris(4-ethynylphenyl)-1,3,5-triazine
Molecular Weight 381.43 g/mol
Synonyms TEPT
Classification / Family Triazine, COF ligands

Chemical Structure

425629-22-7 - 2,4,6-tris(4-ethynylphenyl)-1,3,5-triazine chemical structure
2,4,6-Tris(4-ethynylphenyl)-1,3,5-triazine (TEPT) Chemical Structure, 425629-22-7

Product Details

Purity >98%
Melting Point N/A
Appearance Yellow to orange powder/crystals

MSDS Documentation

425629-22-7 - 2,4,6-tris(4-ethynylphenyl)-1,3,5-triazine2,4,6-Tris(4-ethynylphenyl)-1,3,5-triazine MSDS Sheet

Literature and Reviews

  1. Synthesis of Nitrogen-Rich Polymers by Click Polymerization Reaction and Gas Sorption Property, Molecules, J. Song et al., 23, 1732 (2018); DOI:10.3390/molecules23071732.
  2. Tetraphenylenthene-Based Conjugated Microporous Polymer for Aggregation-Induced Electrochemiluminescence, L. Cui et al., ACS Appl. Mater. Interfaces, 12 (7), 7966–7973 (2020); DOI: 10.1021/acsami.9b21943.
  3. Twinned Growth of Metal-Free, Triazine-Based Photocatalyst Films as Mixed-Dimensional (2D/3D) van der Waals Heterostructures, D. Schwarz et al., Adv. Mater., 29 (40), 1703399 (2017); DOI: 10.1002/adma.201703399.
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