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CAS Number 118688-53-2

Chemistry Building Blocks, COF Ligands, Porous Organic Frameworks

Product Code B3591-1g
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Covalent organic frameworks (COFs) triphenylbenzene ligand

for the synthesis of COFs applied in sensors, CO2 adsorption and photocatalytic hydrogen evolution

1,3,5-Tris(4-formylphenyl)benzene (CAS number 118688-53-2) is a ligands with a triphenylbenzene core functionalised with three aldehyde groups. 1,3,5-Tris(4-formylphenyl)benzene readily reacts with amine derivatives for imine linkage COFs that are used for CO2 capture. One example of such a COF is benzothiazole COF, which is prepared using this method. This COF exhibits a surface area of 328 m2/g with CO2 adsorption of 7.8 wt% at 273 K/bar. It also demonstrates excellent thermal stability up to 450 °C under a N2 atmosphere.

A two-dimensional semiconducting COF (2D COF) can be synthesised from 1,3,5-tris(4-formylphenyl)benzene and benzyl cyanide derivatives through Knoevenagel condensation. The resulting 2D COF has been studied for H2 evolution with a production rate of 2.9 μmol/h.

Facile reactions

Facile reactions

Aldehyde possesses excellent reactivity

High Purity 118688-53-2

High Purity

>98% Purity

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MOF and COF ligands

MOF and COF ligands

Aldehyde ligand for cross-linked COF networks

General Information

CAS Number 118688-53-2
Chemical Formula C27H18O3
Full Name 5'-(4-Formylphenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarbaldehyde
Molecular Weight 390.44 g/mol
Synonyms TFPB, 1,3,5-Tris(4',4'',4'''-formylphenyl)benzene, 3',5'-Bis(4-formylphenyl)-[1,1'-biphenyl]-4-carbaldehyde
Classification / Family COFs, Aldehyde building blocks, sensors, CO2 adsorption, Semiconducting COFs, Hydrogen evolution

Chemical Structure

1,3,5-Tris(4-formylphenyl)benzene chemical structure, CAS 118688-53-2.
1,3,5-Tris(4-formylphenyl)benzene chemical structure, CAS 118688-53-2

Product Details

Purity 98%
Melting Point N/A
Appearance Off-white powder

MSDS Documentation

1,3,5-Tris(4-formylphenyl)benzene1,3,5-Tris(4-formylphenyl)benzene MSDS Sheet

Literature and Reviews

  1. Synthesis of a benzothiazole nanoporous polymer for selective CO2 adsorption, V. Neti et al., RSC Adv., 4, 9669 (2014); DOI: 10.1039/c3ra47587e.
  2. Temperature-responsive covalent organic framework-encapsulated carbon dot-based platform for pyrethroid detection via fluorescence response and smartphone readout, Y. Zhang et al., J. Agric. Food Chem., 70 (20), 6059–6071 (2022); DOI: 10.1021/acs.jafc.2c01568.
  3. Mechanistic investigations into the cyclization and crystallization of benzobisoxazole-linked two-dimensional covalent organic frameworks, D. Pyles et al., Chem. Sci., 9, 6417–6423 (2018); DOI: 10.1039/c8sc01683f.
  4. [3+3] Imine and b-ketoenamine tethered fluorescent covalent-organic frameworks for CO2 uptake and nitroaromatic sensing, D. Kaleeswaran et al., J. Mater. Chem. C, 3, 7159–7171 (2015); DOI: 10.1039/c5tc00670h.
  5. Two-dimensional semiconducting covalent organic frameworks via condensation at arylmethyl carbon atoms, S. Bai et al., Nat. Common., 10, 2467 (2019); DOI: 10.1038/s41467-019-10504-6.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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