Benzene-1,3,5-triyltriboronic acid

CAS Number 89641-21-4

Chemistry Building Blocks, COF Ligands, MOF Ligands, Porous Organic Frameworks

Benzene-1,3,5-triyltriboronic acid CAS 89641-21-4

Covalent organic frameworks (COFs) benzenetriboronic acid ligand

used to synthesise COFs and MOFs for applications in sensors and battery cathodes

Overview
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Benzene-1,3,5-triyltriboronic acid (CAS number 89641-21-4) is a benzene derivative substituted with three boronic acid groups at the meta-position. Benzene-1,3,5-triyltriboronic acid reacts with various ligands to synthesise COFs. These reactions include dehydration reaction with boronic acids to form boroxine linkers, boronate esterification with diols to produce boronate ester linkers and Suzuki cross-coupling reaction with aryl halides. A conjugated COF, synthesised from benzene-1,3,5-triyltriboronic acid and dibromoanthraquinone, is used for sodium-ion battery cathodes. The resulting material delivers a high capacity of 200 mAh/g and rate performance of 105 mAh/g at 200 °C.

Benzene-1,3,5-triyltriboronic acid also reacts with copper sulfate for a 2D MOF material with well-defined supramolecular structures. The 2D MOF exhibits a conductivity of 0.087 S/cm.

Facile reactions

Readily for boronic acid condensation and Suzuki reaction

High Purity

>98% Purity

Worldwide shipping

Quick and reliable shipping

MOF and COF ligands

Boronic acid ligand for cross-linked COF networks

General Information

CAS Number	89641-21-4
Chemical Formula	C₆H₉B₃O₆
Full Name	Benzene-1,3,5-triyltriboronic acid
Molecular Weight	209.57 g/mol
Synonyms	1,3,5-benzenetriboronic acid, B,B',B''-1,3,5-benzenetriyltris-boronic acid, BTBA, BTPA
Classification / Family	Boronic acids, COFs, MOFs, Conjugated, Sensors, Battery cathodes, Porous materials

Chemical Structure

Product Details

Purity	98%
Melting Point	N/A
Appearance	White powder

MSDS Documentation

Benzene-1,3,5-triyltriboronic acid MSDS Sheet

Literature and Reviews

Highly sensitive and selective fluorescence chemosensors containing phenanthroline moieties for detection of Zn²⁺ and Cd²⁺ ions, C. Quan et al., Chem. Pap., 74, 485–497 (2020); DOI: 10.1007/s11696-019-00893-9.
Electrochemical synthesis of large area two-dimensional metal-organic framework films on copper anodes, Y. Liu et al., Angew. Chem. Int. Ed., 60 (6), 2887–2891 (2021); DOI: 10.1002/anie.202012971.
Nanoscale covalent organic frameworks as theranostic platforms for oncotherapy: synthesis, functionalization, and applications, Q. Guan et al., Nanoscale Adv., 2, 3656 (2020); DOI: 10.1039/d0na00537a.
Pyrene-based fluorescent porous organic polymers for recognition and detection of pesticides, Z. Yan et al., Molecules, 27, 126 (2022); DOI: 10.3390/molecules27010126.
Synthetic control of electronic property and porosity in anthraquinone-based conjugated polymer cathodes for high-rate and long cycle-life Na-organic batteries, L.-W. Luo et al., ACS Nano, 16 (9), 14590–14599 (2022); DOI: 10.1021/acsnano.2c05090.

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