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Product Code B3941-250mg
Price $82 ex. VAT

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Covalent Organic Frameworks (COFs) Pyrene Ligand

An aldehyde functionalised bridging ligand linker for COFs in application of photocatalytic water splitting, gas uptake and energy storage

1,3,6,8-Tetrakis(4-formylphenyl)pyrene (TFPPY) tecton has a pyrene core with four side 4-formylphenyl functional groups which grows the structure via condensations reactions.

Constructed from 1,3,6,8-tetrakis(4-formylphenyl)pyrene and 4,4'-(5,6-dichlorobenzo[c][1,2,5]thiadiazole-4,7-diyl)dianiline as the building blocks, two-dimensional (2D) covalent organic framework, namely Py-ClTP-BT-COF, showed great solar-to-hydrogen energy conversion efficiency with photocatalytic H2 evolution rates of 177.50 μmol h−1 and a high apparent quantum efficiency (AQE) of 8.45%.

With the introduction of oxygen atoms into the framework to increase the number of photogenerated electrons, pyrene-based amide COF, TFPPy–DP, demonstrated photocatalytic reduction and removal of toxic uranyl under visible light with 82% removal percentage of 238 ppm uranyl at pH 3 in 2 h of irradiation.

Microporous carbon material, Py-PDT POP-600, obtained by the carbonization of Py-PDT POP with 6,6′-(1,4-phenylene)bis(1,3,5-triazine-2,4-diamine) (PDA-4NH2) and 1,3,6,8-tetrakis(4-formylphenyl)pyrene repeating units, showed  a high nitrogen content with high surface area of 314 m2 g−1, high pore volume, and good thermal stability. Py-PDT POP-600 demonstrated excellent performance in CO2 uptake of 2.7 mmol g−1 at 298 K and a high specific capacitance of 550 F g−1 at 0.5 A g−1.

MOF and COF ligands

MOF and COF ligands

Aldehyde ligand for cross-linked COF networks

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High purity 1415238-25-3

High purity

>97% High purity

Facile reactions

Facile reactions

Aldehyde possesses excellent reactivity

General Information

CAS Number 1415238-25-3
Chemical Formula C44H26O4
Full Name 1,3,6,8-Tetrakis(4-formylphenyl)pyrene
Molecular Weight 618.67 g/mol
Synonyms TFPPy, 4,4',4'',4'''-(pyrene-1,3,6,8-tetrayl)tetrabenzaldehyde
Classification / Family Pyrenes, COF ligands

Chemical Structure

1415238-25-3 - 1,3,6,8-tetrakis(4-formylphenyl)pyrene chemical structure
(TFPPY) Chemical Structure, 1415238-25-3.

Product Details

Purity >97%
Melting Point N/A
Appearance Yellow to orange powder/crystals

MSDS Documentation

1415238-25-3 - 1,3,6,8-tetrakis(4-formylphenyl)pyrene1,3,6,8-Tetrakis(4-formylphenyl)pyrene MSDS Sheet

Literature and Reviews

  1. Modulating Benzothiadiazole-Based Covalent Organic Frameworks via Halogenation for Enhanced Photocatalytic Water Splitting, W. Chen et al., Angew. Chem. Int. Ed., 132 (39), 17050-17057 (2020); DOI: 10.1002/ange.202006925.
  2. Amide Linkages in Pyrene-Based Covalent Organic Frameworks toward Efficient Photocatalytic Reduction of Uranyl, J. Kang et al., ACS Appl. Mater. Interfaces, 14 (51), 57225–57234 (2022); DOI: 10.1021/acsami.2c16702.
  3. Carbonized Aminal-Linked Porous Organic Polymers Containing Pyrene and Triazine Units for Gas Uptake and Energy Storage, A. Mousa et al., Polymers, 15(8), 1891 (2023); DOI: 10.3390/polym15081891.
  4. Synthesis of Stable Thiazole-Linked Covalent Organic Frameworks via a Multicomponent Reaction, K. Wang et al., J. Am. Chem. Soc., 142 (25), 11131–11138 (2020); DOI: 10.1021/jacs.0c03418.
  5. Conjugated microporous polymers as an ideal platform for tunable emission via π-conjugation, Y. Zhang et al., New J. Chem., 45, 20091-20094 (2021); DOI: 10.1039/D1NJ03500B.
  6. Polymorphic Covalent Organic Frameworks: Molecularly Defined Pore Structures and Iodine Adsorption Property, C. Wang et al., Molecules, 28(1), 449 (2023); DOI: 10.3390/molecules28010449.
  7. Linkages Make a Difference in the Photoluminescence of Covalent Organic Frameworks, Y. Wang et al., Angew. Chem. Int. Ed., 135 (42), e202310794 (2023); DOI: 10.1002/ange.202310794.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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