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CAS Number 1447947-87-6

Boronates, Chemistry Building Blocks, COF Ligands, Materials, Porous Organic Frameworks

Product Code B3981-1g
Price £73 ex. VAT

Covalent Organic Frameworks (COFs) Triazine Ligand

An ethynyl functionalised bridging ligand linker for COFs in application hydrogen evolution reaction and supercapacitors

Specifications | MSDS | Literature and Reviews

2,4,6-Tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine (TBPTRz), CAS number 1447947-87-6, is the pinacol boronate of 2,4,6-triphenyl-1,3,5-triazine. TBPTRz is mainly engaged in the construction of conjugated microporous polymers (CMPs)

Porous aromatic framework material (PAF) LNU-18-800, prepared via a Suzuki coupling reaction of 2,4,6-tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine with tris(4-bromophenyl)amine, and then evaluated in an alkali environment (6 M KOH), gave a maximum specific capacitance of 269 F g−1 at a current density of 0.5 A g−1 as electrode material.

Pyrene and 2,4,6-triphenyl-1,3,5-triazine-based conjugated microporous polymers (CMPs), TzSPy and TzPy, synthesized from 2,4,6-tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine and dibromopyrenes, exhibited good hydrogen evolution rates of 10.3 mmol g−1 h−1 and 6.93 mmol g−1 h−1, respectively, under simulated sunlight (AM1.5G). Albeit the 1,6-linked TzSPy skeleton possesses a larger torsional angle compared to the 2,7-linked TzPy, it has a higher degree of conjugation to absorb visible light across a broader wavelength range.

MOF and COF ligands

MOF and COF ligands

Bpin ligand for cross-linked COF networks

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High purity 1447947-87-6

High purity

>97% High purity

Facile reactions

Facile reactions

Bpin possesses excellent reactivity

General Information

CAS Number 1447947-87-6
Chemical Formula C39H98B3N3O6
Full Name 2,4,6-Tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine
Molecular Weight 687.25 g/mol
Synonyms TBPTRz, 1,3,5-Triazine, 2,4,6-tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-
Classification / Family Triazines, COF ligands

Chemical Structure

1447947-87-6 - 2,4,6-tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine chemical structure
2,4,6-Tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine (TBPTRz) Chemical Structure, 1447947-87-6

Product Details

Purity >97%
Melting Point N/A
Appearance White powder to fibres/crystals

MSDS Documentation

1447947-87-6 - 2,4,6-tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine2,4,6-Tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine MSDS Sheet

Literature and Reviews

  1. Pyrene- and 1,3,5-triazine-based D–A two-dimensional polymers for sunlight-driven hydrogen evolution: the influence of the linking pattern, J. Yang et al., Polym. Chem., 13, 5769-5774 (2022); DOI: 10.1039/D2PY00807F.
  2. Structure-property relationships for covalent triazine-based frameworks: The effect of spacer length on photocatalytic hydrogen evolution from water, C. Meier et al., Polymer, 126, 283-290 (2017); DOI: 10.1016/j.polymer.2017.04.017.
  3. A carbonized porous aromatic framework to achieve customized nitrogen atoms for enhanced supercapacitor performance, Y. Zhao et al., New J. Chem., 43, 18158-18164 (2019); DOI: 10.1039/C9NJ04038B.
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