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2,4,6-Tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine

CAS Number 1447947-87-6

Boronates, Chemistry Building Blocks, COF Ligands, Materials, Porous Organic Frameworks


Product Code B3981-250mg
Price $75 ex. VAT

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Covalent Organic Frameworks (COFs) Triazine Ligand

An ethynyl functionalised bridging ligand linker for COFs in application hydrogen evolution reaction and supercapacitors


2,4,6-Tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine (TBPTRz) is the pinacol boronate of 2,4,6-triphenyl-1,3,5-triazine. TBPTRz is mainly engaged in the construction of conjugated microporous polymers (CMPs)

Porous aromatic framework material (PAF) LNU-18-800, prepared via a Suzuki coupling reaction of 2,4,6-tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine with tris(4-bromophenyl)amine, and then evaluated in an alkali environment (6 M KOH), gave a maximum specific capacitance of 269 F g−1 at a current density of 0.5 A g−1 as electrode material.

Pyrene and 2,4,6-triphenyl-1,3,5-triazine-based conjugated microporous polymers (CMPs), TzSPy and TzPy, synthesized from 2,4,6-tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine and dibromopyrenes, exhibited good hydrogen evolution rates of 10.3 mmol g−1 h−1 and 6.93 mmol g−1 h−1, respectively, under simulated sunlight (AM1.5G). Albeit the 1,6-linked TzSPy skeleton possesses a larger torsional angle compared to the 2,7-linked TzPy, it has a higher degree of conjugation to absorb visible light across a broader wavelength range.

MOF and COF ligands

MOF and COF ligands

Bpin ligand for cross-linked COF networks

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High purity 1447947-87-6

High purity

>97% High purity

Facile reactions

Facile reactions

Bpin possesses excellent reactivity

General Information

CAS Number 1447947-87-6
Chemical Formula C39H98B3N3O6
Full Name 2,4,6-Tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine
Molecular Weight 687.25 g/mol
Synonyms TBPTRz, 1,3,5-Triazine, 2,4,6-tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-
Classification / Family Triazines, COF ligands

Chemical Structure

1447947-87-6 - 2,4,6-tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine chemical structure
2,4,6-Tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine (TBPTRz) Chemical Structure, 1447947-87-6

Product Details

Purity >97%
Melting Point N/A
Appearance White powder to fibres/crystals

MSDS Documentation

1447947-87-6 - 2,4,6-tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine2,4,6-Tris[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1,3,5-triazine MSDS Sheet

Literature and Reviews

  1. Pyrene- and 1,3,5-triazine-based D–A two-dimensional polymers for sunlight-driven hydrogen evolution: the influence of the linking pattern, J. Yang et al., Polym. Chem., 13, 5769-5774 (2022); DOI: 10.1039/D2PY00807F.
  2. Structure-property relationships for covalent triazine-based frameworks: The effect of spacer length on photocatalytic hydrogen evolution from water, C. Meier et al., Polymer, 126, 283-290 (2017); DOI: 10.1016/j.polymer.2017.04.017.
  3. A carbonized porous aromatic framework to achieve customized nitrogen atoms for enhanced supercapacitor performance, Y. Zhao et al., New J. Chem., 43, 18158-18164 (2019); DOI: 10.1039/C9NJ04038B.
  4. A Strategy for the Construction of Triply Interlocked Organometallic Cages by Rational Design of Poly-NHC Precursors, Y. Zhang et al., J. Am. Chem. Soc., 142 (31), 13614–13621 (2020); DOI: 10.1021/jacs.0c06470.
  5. Structurally Diverse Covalent Triazine-Based Framework Materials for Photocatalytic Hydrogen Evolution from Water, C. Meier et al., Chem. Mater., 31 (21), 8830–8838 (2019); DOi: 10.1021/acs.chemmater.9b02825.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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