TB-P3Cz
CAS Number 2411720-50-6
Blue Dopant Materials, Dopant Materials, High Purity Sublimed Materials, Materials, MR-TADF Materials, OLED Materials,
MR-TADF Deep Blue Dopant
Oxygen-bridged triaryl-boron MR-TADF emitter, 9′-(2,12-Di-tert-butyl-5,9-dioxa-13b-boranaphtho- [3,2,1-de]anthracen-7-yl)-9,9′′-diphenyl-9H,9′H,9′′H-3,3′:6′,3′′-tercarbazole, CAS No. 2411720-50-6, Sublimed ≥99.0%
Specifications | MSDS | Literature and Reviews | Related Products
TB-P3Cz is a deep-blue MR-TADF emitter with a symmetrical and rigid structure consisting of an oxygen-bridged boron (DOBNA) core as the electron acceptor and a tercarbazole attached to the DOBNA core at the para-position to the central boron atom as the electron donor.
TB-P3Cz exhibits not only thermally activated delayed fluorescence (TADF) but also aggregation-induced emission (AIE) properties. OLED based on non-doped TB-P3Cz as the emitter demonstrates a maximum external quantum efficiency (EQE) and Commission Internationale de l'Éclairage 6.13% and (0.15, 0.08), respectively. The non-doped TB-P3Cz based device also shows ultrahigh color purity, suggesting the great potential of TB-P3Cz as deep-blue luminogens in OLED applications.
TB-P3Cz is solution processable with neat film showing photoluminescence quantum yield (PLQY) of 97%.
General Information
| CAS Number | 2411720-50-6 |
|---|---|
| Full Name | 9′-(2,12-Di-tert-butyl-5,9-dioxa-13b-boranaphtho- [3,2,1-de]anthracen-7-yl)-9,9′′-diphenyl-9H,9′H,9′′H-3,3′:6′,3′′-tercarbazole |
| Chemical Formula | C74H56BN3O2 |
| Molecular weight | 1030.07 g/mol |
| Solubility | in THF, DCM and Toluene |
| Photoluminescence | 448 nm (in film) |
| HOMO/LUMO | HOMO = - 4.88 eV, LUMO = - 1.72 eV |
| Classification/Family | Carbazole derivatives, oxygen-bridged boron (DOBNA) derivatives, Deep blue emitter, MR-TADF Dopant |
Product Details
| Purity | Sublimed ≥99% |
|---|---|
| Melting Point | Tg = 271 °C, Td = 517 °C |
| Appearance | Yellow powder/crystals |
Chemical Structure
Device Structure(s)
| Device structure | ITO/PEDOT:PSS (40 nm)/PVK (20 nm)/TB-P3Cz/TPBi (40 nm)/LiF (1 nm)/Al (100 nm) [1] |
|---|---|
| Colour |
 Blue light emission at 448 nm |
| Turn on Voltage (Von) | 3.05 V |
| CIE coordinates | (0.15, 0.08) |
| Max Current Efficiency | 4.59 cd/A |
| Max Power Efficiency | 4.12 lm/W |
| Max EQE | 6.13% |
MSDS Documentation
TB-P3Cz MSDS sheetLiterature and Reviews
- H. Kim et al. (2020); Color-Tunable Boron-Based Emitters Exhibiting Aggregation-Induced Emission and Thermally Activated Delayed Fluorescence for Efficient Solution-Processable Nondoped Deep-Blue to Sky-Blue OLEDs, Adv. Opt. Mater., 8 (14), 1902175; DOI: 10.1002/adom.201902175.
- J. Hwang et al. (2023); Aggregation-induced emission luminogens for organic light-emitting diodes with a single-component emitting layer, Aggregate, 4, e199; DOI: DOI: 10.1002/agt2.199.
