1,2-Bis(4-ethynylphenyl)-1,2-diphenylethene
CAS Number 1240785-42-5
Chemistry Building Blocks, COF Ligands, Materials, Non-Heterocyclic Building Blocks, Porous Organic Frameworks
Covalent Organic Frameworks (COFs) Tetraphenylethylene Ligand
used for the synthesis of macromolecules and COFs with photoluminescence and aggregation-induced emission
Overview | Product Information | Related Products
1,2-Bis(4-ethynylphenyl)-1,2-diphenylethene (CAS number 1240785-42-5) features a tetraphenylethylene core with two ethynyl groups. Tetraphenylethylene building blocks are widely used for the synthesis of aggregation-induced emission (AIE) materials. The propeller shape of tetraphenylethylene hinders the π–π stacking and eliminates the aggregation-caused quenching effect. The ethynyl groups enable 1,2-Bis(4-ethynylphenyl)-1,2-diphenylethene to undergo multiple reactions such as Sonogashira coupling reaction and azide-alkyne cycloaddition (click chemistry).
Polydiynes of 1,2-bis(4-ethynylphenyl)-1,2-diphenylethene are prepared from iodination of the ethynyl group followed by a KI-mediated metal-free homo-polycoupling reaction. The polydiynes exhibit UV-tuneable refractive indices (n = 1.77 to 2.11).
MOF and COF ligands
Tetraphenylethylene ligand for cross-linked COF/MOF networks
Facile reactions
Ethynyl groups possesses excellent reactivity
High purity
> 98% pure
Worldwide shipping
Quick and reliable shipping
General Information
| CAS Number | 1240785-42-5 |
|---|---|
| Chemical Formula | C30H20 |
| Full Name | 1,2-Bis(4-ethynylphenyl)-1,2-diphenylethene |
| Molecular Weight | 380.49 g/mol |
| Synonyms | 1,2-Bis(4-ethynylphenyl)-1,2-diphenylethylene |
| Classification or Family | Tetraphenylethylene building blocks, COFs, Photoluminescence, AIE |
Chemical Structure
Product Details
| Purity | > 98% |
|---|---|
| Melting Point | N/A |
| Appearance | Pale yellow powder |
MSDS Documentation
1,2-Bis(4-ethynylphenyl)-1,2-diphenylethene MSDS Sheet
References
- Aggregation-induced emission polymer systems with circularly polarized luminescence, H. Yan et al., Aggregate, 4, e331 (2023); DOI: 10.1002/agt2.331.
- AIE-active conjugated polymer nanoparticles with red-emission for in vitro and in vivo imaging, D. Yang et al., RSC Adv., 6, 114580 (2016); DOI: 10.1039/c6ra18678e.
- Development of transition metal-free polymerization route to functional conjugated polydiynes from haloalkyne-based organic reaction, Y. Zhang et al., Polym. Chem., 7, 2492–2500 (2016); DOI: 10.1039/C6PY00050A.
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