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Product Code B861-250mg
Price $325 ex. VAT

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High purity IDTTB6-2Sn available to buy online

Intermediate for the synthesis of non-fullerene acceptors or low bandgap semiconducting polymers


6,6,12,12-tetrakis(4-hexylphenyl)-s-indacenodithieno[3,2-b]thiophene-bis(trimethylstannane) (IDTTB6-2Sn), or 6,6,12,12-tetrakis(4-hexylphenyl)-s-indacenodithieno[3,2-b]thiophene-bis(trimethylstannane), is an useful intermediate for the synthesis of either non-fullerene acceptors (NFAs) or low bandgap semiconducting polymers. Polymer L1057 nanoparticles, which are used for NIR-II bioimaging-guided photothermal cancer therapy, has IDTTB6-2Sn as one of its building blocks [2].

IDTTB6-2Sn has a fused indacenodithieno[3,2-b]thiophene (IDTT) back-bone with out-of-plane hexylphenyl side chains. Trimethylstannyl end functional groups provide access to C-C formation via Stille coupling reaction.

Part of our range of non-fullerene acceptor monomers, high purity (>98%) IDTTB6-2Sn is available for priority dispatch (lead times may apply for large quantities) and qualifying orders ship free.

Enabling facile coupling reaction

Enabling facile coupling reaction

with trimethylstannyl end groups

High purity IDTTB6-2Sn

High purity

98% IDTTB6-2Sn Purity

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Electron-rich 1420071-65-3 building block

Electron-rich building block

For the preparation of low bandgap non-fullerene acceptors (NFAs)

General Information

CAS Number 1420071-65-3
Chemical Formula C74H90S4Sn2
Molecular Weight 1345.17 g/mol
Full Name 6,6,12,12-tetrakis(4-hexylphenyl)-s-indacenodithieno[3,2-b]thiophene-bis(trimethylstannane)
Synonyms

BT-IDT-nC6

3,9-bis(trimethylstannane)-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d:2′,3′-d′]-s-indaceno[1,2-b:5,6-b′]-dithiophene

6,6,12,12-Tetrakis(4-hexylphenyl)-6,12-dihydrodithieno[2,3-d:2',3'-d']-s-indaceno[1,2-b:5,6-b']dithiophene-2,8-bis(trimethylstannane)

Classification / Family Indacenodithieno[3,2-b]thiophene (IDTT), monomer and intermediates, non-fullerene acceptors (NFAs), NFA-OSCs, printing electronics

Chemical Structure

IDTTB6-2Sn chemical structure
Chemical structure of IDTTB6-2Sn, CAS 1420071-65-3

Product Details

Purity >98% (by NMR)
Melting Point N/A
Appearance Yellow crystalline powder

MSDS Documentation

IDTTB6-2Sn MSDSIDTTB6-2Sn MSDS Sheet

Literature and Reviews

  1. Enhanced Performance of Organic Solar Cells with Increased End Group Dipole Moment in Indacenodithieno[3,2-b]thiophene-Based Molecules, J. Intemann et al., Adv. Funct. Mater., 25 (30), 4889-4897 (2015); DOI: 10.1002/adfm.201501600.
  2. Semiconducting Polymer Nanoparticles as Theranostic System for Near-Infrared-II Fluorescence Imaging and Photothermal Therapy under Safe Laser Fluence, Y. Yang et al., ACS Nano, 14, 2, 2509–2521 (2020); DOI: 10.1021/acsnano.0c00043.
  3. Effect of backbone structure on the thermoelectric performance of indacenodithiophene-based conjugated polymers, C. Wei et al., React. Funct. Polym., 142, 1-6 (2019); DOI: 10.1016/j.reactfunctpolym.2019.05.015.
  4. Photoacoustic Imaging and Photothermal Therapy of Semiconducting Polymer Nanoparticles: Signal Amplification and Second Near-Infrared Construction, X. Zhen et al., Small 17 (6), 2004723 (2021); DOI: 10.1002/smll.202004723.
  5. The Chemistry of Organic Contrast Agents in the NIR-II Window, J. Mu et al., Angew. Chem. Int. Ed., e202114722 (2021); DOI: 10.1002/anie.202114722.
  6. Light: A Magical Tool for Controlled Drug Delivery, Y. Tao et al., Adv. Funct. Mater., 30 (49), 2005029 (2020); DOI: 10.1002/adfm.201501600.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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