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Eu(dbm)3(Phen)


Product Code M2296A1
Price £249.00 ex. VAT

Eu(dbm)3(Phen) - tris(dibenzoylmethane)phenanthroline europium(III) - is a typical tenary Eu3+complex with a ligand 1,3- diphenylpropane-1,3-dione and a secondary phenanthroline ligand coordinating to the europium core. Eu(dbm)3(Phen) displays red-orange phosphorescence emission at 615 nm with a narrow bandwidth (color purity) FWHM smaller than 100 cm-1 in OLEDs. Eu(dbm)3(Phen) is preferably co-deposited with a charge transport material to reduce the chance of self-quenching (concentration quenching) and to improve charge carrier mobilities.

Eu(dbm)3(Phen) is also frequently embedded in polyvinylcarbazole (PVK) or mesoporous silica nanoparticles for electroluminescence studies to improve its efficiency and photo stability.

General Information

CAS number 17904-83-5
Full name Tris(dibenzoylmethane)phenanthroline europium(III)
Chemical formula C57H41N2O6Eu
Molecular weight 1001.93 g/mol
Absorption λmax 257 nm, 355 nm in THF
Fluorescence λem 615 nm in THF
HOMO/LUMO HOMO = 5.22 eV, LUMO = 2.93 eV [1]
Synonyms Tris(dibenzoylmethane) mono(1,10-phenanthroline)europium(lll)
Classification / Family Europium complexes, Organic electronics, Red dopant, Sublimed materials.

Product Details

Purity Sublimed: >99.0% (HPLC)
Melting point Mp (onset) =199°C (DTA), TGA:  234.6 °C (0.5% weight loss)
Appearance Yellow powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.

Chemical Structure

Chemical structure of Eu(dbm)3(Phen)
Chemical structure of Eu(dbm)3(Phen)

Device Structure(s)

Device structure ITO/PEDOT:PSS/TAPC (50 nm)/PVK:20 wt% Eu(dbm)3(Phen)/b-PBD/Al [2]
Colour Pinkish Red Red device structure
Luminous efficiency@29 V 26 cd/mA

*For chemical structure information, please refer to the cited references.

Pricing

Grade Order Code Quantity Price
Sublimed (>99.0% purity) M2296A1 250 mg £249.00
Sublimed (>99.0% purity) M2296A1 500 mg £399.00
Sublimed (>99.0% purity) M2296A1 1 g £649.00

MSDS Documentation

Eu(dbm)3(Phen) MSDSEu(dbm)3(Phen) MSDS sheet

Literature and Reviews

  1. Preparation and characteristics of Eu(DBM)3phen: Synthesis, single-crystal structure and spectroscopic analysis, L. Ruan et al., J. Mol. Struct., 1149, 265-272 (2017); DOI: 10.1016/j.molstruc.2017.08.003.
  2. The dependence of OLED external efficiency on the mass concentration of europium(III) dispersed in PVK, G. Santos et al., ECS Trans., 39 (1), 475-480 (2011); DOI:10.1149/1.3615229.
  3. Optical amplification of Eu(DBM)3Phen-doped polymer optical fiber, H. Liang et al., Opt. Lett., 29 (6), 447-449 (2004); DOI:10.1364/OL.29.000477.
  4. Electroluminescence from europium(III) complexes, H. Xu et al., Coord. Chem. Rev., 293-294, 228-249 (2015); DOI: 10.1016/j.ccr.2015.02.018.
  5. Concentration quenching and photostability in Eu (dbm)3phen embedded in mesoporous silica nanoparticles, E. Moretti et al., J. Luminescence, 146:178-185 (2014); DOI: 10.1016/j.jlumin.2013.09.059.
  6. Phosphorescent materials for application to organic light emitting devices, M. Baldo et al., Pure Appl. Chem., 71 (11), 2095-2106 (1999); DOI:10.1351/pac199971112095.

To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.

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