4TCzBN is yet another family members of carbazolyl benzonitrile derivatives which are widely used in either white or blue highly efficient TADF-OLED devices.
The carbazolyl groups are electron donating and nitrile group is electron with-drawing while the extended tert-butyl units can serve as an encapsulation shell to the luminophore in 4TCzBN. It is believed that the introduction of the tert-butyl units we can effectively separate molecules thus reduce the chance of triplet-polaron annihilation (TPA) to greatly improve the device efficiency and stability.
|Molecular weight||1212.73 g/mol|
|Absorption||λmax 295 nm, 345 nm and 417 nm in toluene|
|Fluorescene||λem 483 nm in toluene|
|HOMO/LUMO||HOMO = 5.48 eV, LUMO = 2.73 eV, T1 = 2.60 eV |
|Classification / Family||Carbazole, Phthalonitrile, TADF materials, Blu dopant materials, Sublimed materials|
|Purity||Sublimed >99.0% (1H NMR)|
Tg = 322 °C (lit.)
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.
|Device structure||ITO/HATCN (5 nm)/NPB (30 nm)/TCTA (10 nm)/mCP (10 nm)/4TCzBN:2,4-2CzBN* (30 nm)/DPEPO (10 nm)/Bphen (30 nm)/LiF (0.5 nm)/Al (150 nm) |
|Max. Power Efficiency||42.0 Im/W|
|Device structure||ITO/HATCN (5 nm)/NPB (30 nm)/TCTA (10 nm)/mCP (10 nm)/4TCzBN:3,5-2CzBN* (30 nm)/DPEPO (10 nm)/Bphen (30 nm)/LiF (0.5 nm)/Al (150 nm) |
|Max. Power Efficiency||34.5 Im/W|
*For chemical structure information, please refer to the cited references.
|Sublimed (>99.0% purity)||M2218A1||250 mg||£316.00|
|Sublimed (>99.0% purity)||M2218A1||500 mg||£536.00|
|Sublimed (>99.0% purity)||M2218A1||1 g||£858.00|
Literature and Reviews
- Highly efficient blue thermally activated delayed fluorescent OLEDs with record-low driving voltages utilizing high triplet energy hosts with small singlet–triplet splittings, D. Zhang et al., Chem. Sci., 7, 3355 (2016); DOI: 10.1039/c5sc04755b.
- Modulation of Förster and Dexter Interactions in Single-Emissive-Layer All-Fluorescent WOLEDs for Improved Efficiency and Extended Lifetime, P. Wei et al., Adv. Funct. Mater., 2019; DOI: 10.1002/adfm.201907083.
Highly efficient and stable blue thermally activated delayed fluorescence emitters, D. Zhang et al., SPIE (2016); DIO: 10.1117/2.1201611.006797.
To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.