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SimCP CAS 850221-63-5
Product Code M2294A1-250mg
Price £330 ex. VAT
£ GBP

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SimCP, phosphorescent host for blue, green and white emitting OLED devices

Posesses the best bipolarity and current efficiency compared to mCP and SimCP2

SimCP, 3,5-bis(9-carbazolyl) triphenylsilane, is an arylsilane derivative with an mCP structure attached. SimCP shows a higher glass transition temperature (Tg = 101 °C) than the more commonly used host material, mCP.

SimCP is widely used as a phosphorescent host for blue, green and white emitting OLED devices. SimCP hosts possess the best bipolarity when compared to mCP or SimCP2; the best current efficiency should be expected when SimCP is used as host, especially when it is solution processed to give a homogeneous film of the host-guest blend.

General Information

CAS number 850221-63-5
Chemical formula C48H34N2Si
Molecular weight 666.88 g/mol
Absorption* λmax 345 nm (THF)
Photoluminescence λem 446 nm (446)
HOMO/LUMO HOMO = 6.1 eV, LUMO = 2.5 eV; ET = 3.02 eV [1]
Chemical name 3,5-Bis(9-carbazolyl) tetraphenylsilane
Synonyms
  • 9,9'-(5-(triphenylsilyl)-1,3-phenylene)bis(9H-carbazole)
  • [3,5-Di(9H-carbazol-9-yl)phenyl]triphenylsilane
Classification / Family Arylsilane derivatives, Phosphorescent host materials, Sublimed materials, Semiconducting small molecules

* Measurable with an optical spectrometer, see our spectrometer application notes.

Product Details

Purity Sublimed* >99.0% (HPLC)
Melting point Tg = 101°C (lit.)
Appearance White powder/crystals

* Sublimation is a technique used to obtain ultra pure-grade chemicals, see sublimed materials.

Chemical Structure

SimCP chemical structure
Chemical structure of bis[3,5-di(9H -carbazol-9-yl)phenyl]diphenylsilane (SimCP)

Device Structure(s)

Device structure ITO/NPB (30 nm)/SimCP:FIrpic (30 nm, 7%)/TPBi (30 nm)/LiF/Al [2]
Colour blue light emitting device Blue
Max. EQE 14.4
Max. Power Efficiency 11.9 Im/W
Max. Luminance 39,500 cd/m2
Device structure ITO/TAPC/SimCP:6 wt% Ir(tfmppy)2(tpip)/TPBi/LiF/Al [3]
Colour green light emitting device Green
Max. EQE 23.6%
Max. Current Efficiency 47.1 cd/A
Max. Power Efficiency 15.3 Im/W
Max. Luminance 38, 674 cd/m2

Pricing

Grade Order Code Quantity Price
Sublimed (>99.0% purity) M2294A1 250 mg £330
Sublimed (>99.0% purity) M2294A1 500 mg £520
Sublimed (>99.0% purity) M2294A1 1 g £850

MSDS Documentation

SimCP MSDSSimCP MSDS sheet

Literature and Reviews

  1. High-efficiency blue organic light-emitting diodes using a 3,5-di(9H-carbazol-9-yl)tetraphenylsilane host via a solution-process, J.-H. Jou et al., J. Mater. Chem., 20, 8411–8416 (2010); DOI: 10.1039/C0JM01163K.
  2. New Dopant and Host Materials for Blue-Light-Emitting Phosphorescent Organic Electroluminescent Devices, S.-J. Yeh et al., Adv. Mater., 17 (3), 285-289 (2005); DOI: 10.1002/adma.200401373.
  3. Green and Bluish-green Phosphorescent OLEDs with High Efficiency at High Brightness, Chinese J. Luminescence, 34 (1), 92-97 (2013).
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