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Product Code M2338A1-100mg
Price $313 ex. VAT

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DCzTRZ, has a structure of two electron donating carbazole moieties attached to one of the phenyl rings of an electron deficient 1,3,5-triphenyltriazine unit.

Like TCzTRZ, DCzTRZ is used as a bipolar blue dopant material in highly efficient TADF-OLED devices. The only difference between DCzTRZ and TCzTRZ is that DCzTRZ is relatively blue shifted in absorption and emission, while TCzTRZ has one more carbazole unit.

As an electron acceptor, DCzTRZ can form exciplex with electron donor DMAC-DPS for green TADF-OLED devices with high photoluminescence quantum yield and high quantum efficiency.

General Information

CAS number 1106730-48-6
Full name 9,9'-(5-(4,6-Diphenyl-1,3,5-triazin-2-yl)-1,3-phenylene)bis(9H-carbazole)
Chemical formula C45H29N5
Molecular weight 639.75 g/mol
Absorption λmax 337 nm (in toluene)
Phosphorescene λmax 449 nm (in toluene)
HOMO/LUMO HOMO = 5.88 eV, LUMO = 2.86 eV [1]
Synonyms 9-(3-(9H-Carbazol-9-yl)-5-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9H-carbazole
Classification / Family Triazine derivatives, Light-emitting diodes, Organic electronics, TADF blue emitter, Exciplex green emitter, Sublimed materials.

Product Details

Purity Sublimed >99.0% (HPLC)
Melting point Tg = 160 ℃, Td (Temperature at 5% weight loss) = 397 ℃.
Appearance Pale yellow powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.

Chemical Structure

DCzTRZ chemical structure, 1106730-48-6

Chemical structure of DCzTRZ, CAS# 1808158-40-8.

Device Structure(s)

Device structure ITO/PEDOT:PSS/TAPC/mCP/25 wt% DCzTRZ:DPEPO/TSPO1/TPBI/LiF/Al [1]
Colour Blue blue
Max. Current Efficiency 26.8 cd/A
Max. Power Efficiency 22.4 lm W-1
Max. EQE 17.8%

 *For chemical structure information, please refer to the cited references.

Pricing

Grade Order Code Quantity Price
Sublimed (>99.0% purity) M2338A1 100 mg £250
Sublimed (>99.0% purity) M2338A1 250 mg £500
Sublimed (>99.0% purity) M2338A1 500 mg £850
Sublimed (>99.0% purity) M2338A1 1 g £1400

MSDS Documentation

DCzTRZ MSDSDCzTRZ MSDS Sheet

Literature and Reviews

  1. Stable Blue Thermally Activated Delayed Fluorescent Organic Light-Emitting Diodes with Three Times Longer Lifetime than Phosphorescent Organic Light-Emitting Diodes, M. Kim et al., Adv. Mater., 27 (15), 2515-2520 (2015); DOI: 10.1002/adma.201500267.
  2. Efficient and Stable Deep Blue Thermally Activated Delayed Fluorescence Molecules Based on a Bipyridine Acceptor Core, C. Cheng et al., J. Mater. Chem. C, 9, 3088-3095 (2021); DOI: 10.1039/D0TC05395C.
  3. Design Strategy for 25% External Quantum Efficiency in Green and Blue Thermally Activated Delayed Fluorescent Devices, D. Lee et al., Adv. Mater., 27 (39), 5861-5867 (2015); DOI: 10.1002/adma.201502053.
  4. Degradation Mechanisms in Blue Organic Light-Emitting Diodes, D. Wang et al., CCS Chem., 2 (4), 1278–1296 (2020); DOI: 10.31635/ccschem.020.202000271.
  5. Recent advancements of high efficient donor–acceptor type blue small molecule applied for OLEDs, Y. Li et al., Mater. Today, 20 (5), 258-266 (2017); DOI: 10.1016/j.mattod.2016.12.003.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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