FREE shipping to on qualifying orders when you spend or more, processed by Ossila BV. All prices ex. VAT. Qualifying orders ship free worldwide! Fast, secure, and backed by the Ossila guarantee. It looks like you are visiting from , click to shop in or change country. Orders to the EU are processed by our EU subsidiary.
Join the Team About Ossila Contact Us |Log In Create Account| Worldwide, £ GBP   Flag

It looks like you are using an unsupported browser. You can still place orders by emailing us on info@ossila.com, but you may experience issues browsing our website. Please consider upgrading to a modern browser for better security and an improved browsing experience.

DCzTRZ CAS 1106730-48-6
Product Code M2338A1-100mg
Price £250 ex. VAT
£ GBP

How to Order | Worldwide Shipping

DCzTRZ, has a structure of two electron donating carbazole moieties attached to one of the phenyl rings of an electron deficient 1,3,5-triphenyltriazine unit.

Like TCzTRZ, DCzTRZ is used as a bipolar blue dopant material in highly efficient TADF-OLED devices. The only difference between DCzTRZ and TCzTRZ is that DCzTRZ is relatively blue shifted in absorption and emission, while TCzTRZ has one more carbazole unit.

As an electron acceptor, DCzTRZ can form exciplex with electron donor DMAC-DPS for green TADF-OLED devices with high photoluminescence quantum yield and high quantum efficiency.

General Information

CAS number 1106730-48-6
Full name 9,9'-(5-(4,6-Diphenyl-1,3,5-triazin-2-yl)-1,3-phenylene)bis(9H-carbazole)
Chemical formula C45H29N5
Molecular weight 639.75 g/mol
Absorption λmax 337 nm (in toluene)
Phosphorescene λmax 449 nm (in toluene)
HOMO/LUMO HOMO = 5.88 eV, LUMO = 2.86 eV [1]
Synonyms 9-(3-(9H-Carbazol-9-yl)-5-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9H-carbazole
Classification / Family Triazine derivatives, Light-emitting diodes, Organic electronics, TADF blue emitter, Exciplex green emitter, Sublimed materials.

Product Details

Purity Sublimed >99.0% (HPLC)
Melting point Tg = 160 ℃, Td (Temperature at 5% weight loss) = 397 ℃.
Appearance Pale yellow powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.

Chemical Structure

DCzTRZ chemical structure, 1106730-48-6

Chemical structure of DCzTRZ, CAS# 1808158-40-8.

Device Structure(s)

Device structure ITO/PEDOT:PSS/TAPC/mCP/25 wt% DCzTRZ:DPEPO/TSPO1/TPBI/LiF/Al [1]
Colour Blue blue
Max. Current Efficiency 26.8 cd/A
Max. Power Efficiency 22.4 lm W-1
Max. EQE 17.8%

 *For chemical structure information, please refer to the cited references.

Pricing

Grade Order Code Quantity Price
Sublimed (>99.0% purity) M2338A1 100 mg £250
Sublimed (>99.0% purity) M2338A1 250 mg £500
Sublimed (>99.0% purity) M2338A1 500 mg £850
Sublimed (>99.0% purity) M2338A1 1 g £1400

MSDS Documentation

DCzTRZ MSDSDCzTRZ MSDS Sheet

Literature and Reviews

  1. Stable Blue Thermally Activated Delayed Fluorescent Organic Light-Emitting Diodes with Three Times Longer Lifetime than Phosphorescent Organic Light-Emitting Diodes, M. Kim et al., Adv. Mater., 27 (15), 2515-2520 (2015); DOI: 10.1002/adma.201500267.
  2. Efficient and Stable Deep Blue Thermally Activated Delayed Fluorescence Molecules Based on a Bipyridine Acceptor Core, C. Cheng et al., J. Mater. Chem. C, 9, 3088-3095 (2021); DOI: 10.1039/D0TC05395C.
  3. Design Strategy for 25% External Quantum Efficiency in Green and Blue Thermally Activated Delayed Fluorescent Devices, D. Lee et al., Adv. Mater., 27 (39), 5861-5867 (2015); DOI: 10.1002/adma.201502053.
Return to the top