J52-Cl
CAS Number 1887136-01-7
Luminosyn™ Polymers, Materials, OPV Polymers, Semiconducting Polymers
Enhanced Crystallinity Compared to J52
Achieve outstanding PCE when blended with IT-4Fa as active layer materials
Specifications | MSDS | Literature and Reviews | Technical Support
J52-Cl is the chlorinated version of J52, with chlorine atoms introduced on the side chain of the polymer. It is believed that chlorination can down-shift the energy levels more effectively, modify the inter-molecular aggregation to enhance the crystallinity of polymer, and tune the surface energy for film morphology optimization.
Contact us for large orders of 5-10 grams with a lead time of 4-6 weeks.
Optimize Film Morphology
Through tuned surface energy
Large Batch Luminosyn™
High purity with batch-specific GPC data
Simple Worldwide Shipping
Reliable delivery via tracked courier
Efficient NFA Solar Cells
Record device performance >12%
The Luminosyn™ Range
High Purity Materials: Purified by Soxhlet extraction with methanol, hexane, and chlorobenzene under argon atmosphere.Batch-Specific Data: Confidence in your materials with batch-specific GPC data for your thesis or publications.Large Quantity Orders: Plan your experiments with confidence using polymers from the same batch.General Information
| Full Name | Poly[[5,6-difluoro-2-(2-hexyldecyl)-2H-benzotriazole-4,7-diyl]-2,5-thiophenediyl[4,8-bis[5-(2-ethylhexyl)-4-chloro-2-thienyl]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl]-2,5-thiophenediyl] |
|---|---|
| Synonyms | J52-2Cl, PJ52-Cl |
| Chemical Formula | (C64H75Cl2F2N3S6)n |
| CAS Number | 1887136-01-7 |
| HOMO / LUMO | HOMO = 5.38 eV, LUMO = 3.44 eV [1] |
| Soluble In | Chloroform, chlorobenzene and dichlorobenzene |
| Recommended Processing Solvents at 10mg/ml | Chloroform |
| Classification or Family | Organic semiconducting materials, Low band-gap polymers, Organic Photovoltaics, Polymer solar cells, NF-PSCs, All-polymer solar cells (all-pscs). |
Batch Details
| Batch | Mw | Mn | PDI | Stock Info |
|---|---|---|---|---|
| M2297A1 | 150,452 | 49,950 | 3.01 | In stock |
Chemical Structure
Device Structure
NFA solar cell devices with an outstanding device performance PCE of 12.18% have been achieved by using J52-Cl:IT-4F blend as active layer materials with ferrocene as an additive, with the device structure: ITO/ZnO/J52-Cl:IT-4F (6 wt% Ferrocene)/MoO3/Ag [2].
| Thickness (nm) | VOC (V) | JSC (mA cm-2) | FF (%) | PCE (%) |
|---|---|---|---|---|
| n.a. | 0.836 | 20.39 | 69 | 12.18 |
MSDS Documentation
J52-Cl MSDS sheetLiterature and Reviews
- Chlorinated Wide Bandgap Donor Polymer Enabling Annealing Free Non-fullerene Solar Cells with the Efficiency of 11.5%, Z. Liu et al., J. Phys. Chem. Lett., 9, 24, 6955–6962 (2018); DOI: 10.1021/acs.jpclett.8b03247..
- Ferrocene as a highly volatile solid additive in non-fullerene organic solar cells with enhanced photovoltaic performance, L. Ye et al., Energy Environ. Sci., 13, 5117-5125 (2020); DOI: 10.1039/d0ee02426k.
- Benzotriazole-Based Acceptor and Donors, Coupled with Chlorination, Achieve High Voc of 1.24 V and Efficiency of 10.5% in Fullerene-Free Organic Solar Cells, A. Tang et al., Chem. Mater., 31, 11, 3941–3947 (2019); DOI: 10.1021/acs.chemmater.8b05316.