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Product Code M2234A1-250mg
Price $400 ex. VAT

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PDINN, used to improve device stability in non-fullerene OSCs

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PDINN, while compared with PDINO, can provide better contact with the electrodes and non-fullerene active layers to give higher conductivity. PDINN also can reduce the work functions (WFs) of the metal cathode, making it a better candidate to use as cathode interlayer materials (CIMs) in non-fullerene OSCs with air stable metal cathode, such as Ag and Cu, to improve the device stability.

With solubility of 26.7 mg/ml in methanol without any assistance from acetic acid, PDINN has better solubility than most of the CIMs such as PFN and PDIN which needs acetic acid to make a clear solution. PDINN also shows a better interfacial compatibility to a wider range of active layer materials to form better quality films for OSCs devices than PDINO.

Cathode interlayer molecule

Cathode interlayer molecule

For high efficient OPV applications

Perfect for non-fullerene solar cells

Perfect for non-fullerene solar cells

Compatible with high work function cathodes

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Enhanced 1020180-01-1 solubility

Enhanced solubility

Compatible with wider range of active layer materials

With PDINN/Ag as the top electrode, the OSCs based on PM6:Y6 demonstrates a high PCE of 17.23%, the device has the following structure.

Device structure: ITO/PEDOT:PSS/PM6:Y6/PDINN (9 nm)/Ag [2]

Thickness (nm) VOC (V) JSC (mA cm-2) FF (%) PCE (%)
N/A 0.847 25.89 78.59 17.23

General Information

CAS Number 1020180-01-1
Chemical Formula C40H46N6O4
Purity >98% (1H NMR)
Full Name N,N'-Bis{3-[3-(Dimethylamino)propylamino]propyl}perylene-3,4,9,10-tetracarboxylic diimide
Molecular Weight 674.83 g/mol
HOMO / LUMO HOMO = -6.02 eV LUMO = -3.78 eV [2]
Melting Point (DSC) 240.1 °C (TGA, 5% weight loss)
Form Deep red powder/crystals
Absorption λmax 473 nm (film)
Solubility/Processing Solvents Methanol, ethanol, trifluoroethanol
Synonyms

BDMAPAP-PDI

2,9-Bis(3-((3-(dimethylamino)propyl)amino)propyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone

Classification / Family Perylene diimide (PDI), Cathode interlayer materials (CIMs), Organic semiconducting materials, Organic Photovoltaics, OLED, Small molecule electrolyte

Chemical Structure

pdinn - pdino
Chemical structure of PDINN, CAS 1020180-01-1

MSDS Documentation

PDIN MSDSPDINN MSDS Sheet

Pricing

Batch Quantity Price
M2234A1 250 mg £320
M2234A1 500 mg £500
M2234A1 1 g £850
M2234A1 5 g £3500

Literature and Reviews

  1. Cathode engineering with perylene-diimide interlayer enabling over 17% efficiency single-junction organic solar cells, J. Yao et al., Nat. Commun., 11, 2726 (2020); DOI: 10.1038/s41467-020-16509-w.
  2. Perylene diimides: a thickness-insensitive cathode interlayer for high performance polymer solar cells, Z. Zhang et al., Environ. Sci., 7, 1966 (2014); DOI: 10.1039/c4ee00022f.
  3. N,N'-bis[3,3'-(dimethylamino)propylamine]-3,4,9, 10-perylenetetracarboxylic Diimide, a Dicationic Perylene Dye for Rapid Precipitation and Quantitation of Trace Amounts of DNA, Z. Liu et al., Anal. Biochem, 5; 236(1):139-45 (1996); DOI: 10.1006/abio.1996.0142.
  4. Layer-by-layer deposited multilayer films of oligo(pyrenebutyric acid) and a perylene diimide derivative: structure and photovoltaic properties, L. Zhao et al., Langmuir 24 (8), 4380-7 (2008); doi: 10.1021/la703884d.
  5. A non-fullerene small molecule processed with green solvent as an electron
    transporting material for high efficiency p-i-n perovskite solar cells, J. Miao et al., Org. Electonics, 52, 200-205 (2018); DOI: 10.1016/j.orgel.2017.10.028.

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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