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Y7, BTP-4Cl

CAS Number 2414918-25-3

Non-Fullerene Acceptors


Product Code M2212A1-50mg
Price $263 ex. VAT

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High purity, low price Y7 (BTP-4Cl) non-fullerene acceptor

Achieve record breaking NFA organic photovoltaic solar cell power conversion efficiencies


Y7, also known as BTP-4Cl, is the chlorinated version of Y6 (BTP-4F). It has an absorption range that extends to the near infrared (NIR) and has demonstrated a power conversion efficiency (PCE) up to 15.7% with PBDB-T-2F (PM6) as the polymer donor.

Like Y6, Y7 is a highly conjugated organic semiconductor and is composed of a fused thienothienopyrrolo-thienothienoindole (TTP-TTI) core base and 2-(5,6-dichloro-3-oxo-2,3-dihydro-1H-inden-1-ylidene)malononitrile (2ClIC) end units. Y7 has an A-DAD-A structure and is therefore electron deficient and hence suitable for use as a n-type non-fullerene electron acceptor (NFA) in OPV devices.

Compared to Y6, the chlorinated acceptor Y7 shows a redshift of about 20 nm in optical absorption and about 100 meV downshift in the LUMO level. Device film containing Y7 has a higher electroluminescence quantum efficiency (EQE = 3.47 × 10-4) than that of Y6 (1.40 × 10-4) with reduced non-radiative energy loss of ~ 24 meV. This reduced non-radiative energy loss yields a higher VOC of 0.867 V compared with that of the Y6 based device (0.834 V).

High efficient non-flullerene acceptor

High efficient non-flullerene acceptor

with highly conjugated core

Expanded absorption range to near infrared

Expanded absorption range to near infrared

Large dipole moment induced by chloride substituents

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High purity

High purity

>99% High purity

Record PCEs of 16.5% and 15.3% for OPV cells with 0.09 and 1 cm2 active areas were achieved when PBDB-T-2F (PM6) was used as the polymer donor and Y7 as the acceptor with the following device structure.

Device structure: ITO/ZnO/PM6:Y7/MoO3/Al.

Thickness (nm) VOC (V) JSC (mA cm-2) FF (%) PCE (%)
100 ± 4 0.867 25.4 75.0 16.5 (16.1 ± 0.2)

Characterisation (1H NMR)

Y7, BTP-4Cl 1H NMR Characterisation
1H-NMR spectrum of Y7 (BTP-4Cl) in CDCl3

Chemical Structure

BTP-4Cl, Y7, Y6Cl chemical structure
Chemical structure of Y7 (BTP-4Cl)

Literature and Reviews

  1. Over 16% efficiency organic photovoltaic cells enabled by a chlorinated acceptor with increased open-circuit voltages, Y Cui et al., Nat. Commun., 10, 2515 (2019)  doi: 10.1038/s41467-019-10351-5
  2. Single-Junction Organic Solar Cell with over 15% Efficiency Using Fused-Ring Acceptor with Electron-Deficient Core, J. Yuan et al., Joule (2019); doi: 10.1016/j.joule.2019.01.004.
  3. Achieving over 16% efficiency for single-junction organic solar cells, B. Fan et al., Sci. China Chem., 62, 6 746-752 (2019); doi: 10.1007/s11426-019-9457-5.

General Information

CAS Number 2414918-25-3
Chemical Formula C82H86Cl4N8O2S5
Purity >99% (1H NMR)
Full Name 2,2'-((2Z,2'Z)-((12,13-bis(2-ethylhexyl)-3,9-diundecyl-12,13-dihydro-[1,2,5]thiadiazolo[3,4-e]thieno[2",3’':4’,5']thieno[2',3':4,5]pyrrolo[3,2-g]thieno[2',3':4,5]thieno[3,2-b]indole-2,10-diyl)bis(methanylylidene))bis(5,6-dichloro-3-oxo-2,3-dihydro-1H-indene-2,1-diylidene))dimalononitrile
Molecular Weight 1517.75 g/mol
HOMO / LUMO HOMO = -5.65 eV, LUMO = -3.63 eV [1]
Form Solid powder: Dark blue to black
Synonyms BTP-4Cl, Y6Cl, TTPTTI-4Cl
Classification / Family NFAs, n-type non-fullerene electron acceptors, Organic semiconducting materials, Low band-gap small molecule, Small molecular acceptor, Organic photovoltaics, Polymer solar cells, NF-PSCs.

MSDS Documentation

BTP-4Cl MSDSBTP-4Cl MSDS Sheet

Pricing

Batch Quantity Price
M2212A1 50 mg £210
M2212A1 100 mg £370
M2212A1 250 mg £740
M2212A1 500 mg £1250
M2212A1 1 g £2300

To the best of our knowledge the information provided here is accurate. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. Products may have minor cosmetic differences (e.g. to the branding) compared to the photos on our website. All products are for laboratory and research and development use only.

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