2,7-Bis(9,9-spirobifluoren-2-yl)-9,9-spirobifluorene (TSBF) has three spirobifluorene joined at 2,7-positions. Exhibiting high glass transition temperatures (Tg = 231 °C), excellent thermal and color stabilities, spirobifluorene derivatives, such as Spiro-OMeTAD, are well sought for in OLED devices.
Being sterically hindered, TSBF is normally used as fluorescent host material in OLED devices. With low threshold of amplified spontaneous emission(ASE) and suppressed electroluminescence efficiency roll-off, TSBF is also a promising candidate for realising electrically pumped organic semiconductor laser diodes.
|Molecular weight||945.15 g/mol|
|Absorption||350 nm in THF|
|Fluorescence||415 nm in THF|
|HOMO/LUMO||HOMO = 6.1 eV, LUMO = 3.0 eV |
|Classification / Family||Spirobifluorene, Blue emitter, Fluorescent host materials, Electron transport layer (ETL), OLED materials, OFET materials, Laser diodes, Materials science|
|Melting point||457 °C (DSC, lit.), Tg = 231 °C (lit.)|
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.
|Sublimed (>99% purity)||M2213A1||500 mg||£220.00|
|Sublimed (>99% purity)||M2213A1||1 g||£352.00|
Literature and Reviews
Optical Properties of Oligo(9,9-diarylfluorene) Derivatives in Thin Films and Their Application for Organic Light-Emitting Field-Effect Transistors,
T. Oyamada et al., J. Phys. Chem. C 2007, 111, 1, 108-115 (2007); doi: 10.1021/jp0654056.
- Low amplified spontaneous emission threshold and suppression of electroluminescence efficiency roll-off in layers doped with ter(9,9′-spirobifluorene), M. Inoue et al., Appl. Phys. Lett. 108, 133302 (2016); dio: 10.1063/1.4945596.
Ter(9,9-diarylfluorene)s: Efficient Blue Emitter with High Electrochemical,
Morphological and Thermal Stability, K. Wong et al., J. Am. Chem. Soc., 124, 39, 11576-11577 (2002); doi: 10.1021/ja0269587.
To the best of our knowledge the information provided here is accurate. However, Ossila assume no liability for the accuracy of this page. The values provided are typical at the time of manufacture and may vary over time and from batch to batch. All products are for laboratory and research and development use only, and may not be used for any other purpose including health care, pharmaceuticals, cosmetics, food or commercial applications.