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BTP-eC9


Product Code M2249A1
Price

BTP-eC9 is a family member of the Y series of n-type non-fullerene semiconducting acceptors. It has been proven that these NFAs can achieve high device performance in non-fullerene polymer solar cells (NF-PSCs).

With a fused thienothienopyrrolo-thienothienoindole (TTP-TTI) core, BTP-eC9 is a modified version of Y7 but with better solubility. Comparing to Y6, chlorination at the peripheral end-groups can efficiently lower HOMO/LUMO energy levels. C–Cl bond also has a large dipole moment, expanding the absorption range further to near infrared (NIR) region.

A device efficiency approaching 18% has been reported using BTP-eC9 as the electron acceptor and PBDB-T-2F (PM6) as electron donor in single junction organic photovoltaic cells.

Device structure: ITO/PEDOT:PSS/PBDB-T-2F:BTP-eC9 (1:1.2)/PFN-Br/Al

Thickness (nm) VOC (V) JSC (mA cm-2) FF (%) PCE (%)
100 0.839 26.2 81.1 17.8

General Information

Full name 2,2'- [[12,13-Bis(2-butyloctyl)-12,13-dihydro-3,9-dinonylbisthieno[2'',3'':4',5']thieno[2',3':4,5]pyrrolo[3,2-e:2',3'-g][2,1,3]benzothiadiazole-2,10-diyl]bis[methylidyne(5,6-chloro-3-oxo-1H-indene-2,1(3H)-diylidene) ]]bis[propanedinitrile]
Synonyms BTP-eC9
Chemical formula C86H94Cl4N8O2S5
Molecular weight 1573.89 g/mol
CAS number n.a.
HOMO / LUMO HOMO = -5.64 eV, LUMO = -4.05 eV [1]
Solubility Chloroform, chlorobenzene and dichlorobenzene
Form Dark blue powder/crystal
Classification / Family BTP series NFAs, n-type non-fullerene electron acceptors, Organic semiconducting materials, Low band-gap small molecule, Small molecular acceptor, Organic photovoltaics, Polymer solar cells, NF-PSCs.

Chemical Structure

BTP-eC9 chemical structure
Chemical structure of BTP-eC9

MSDS Documentation

BTP-eC9 MSDS sheet

Pricing

Batch Quantity Price
M2249A1 100 mg £340.00
M2249A1 250 mg £680.00
M2249A1 500 mg £1200.00
M2249A1 1 g £2200.00
M2249A1 5 g / 10 g* Please contact us for details

*for 5 - 10 grams order quantity, the lead time is 4-6 weeks.

Literature and Reviews

  1. Single-Junction Organic Photovoltaic Cells with Approaching 18% Efficiency, Y. Cui et al., Adv. Mater., 32 (19), 1908205 (2020); DOI: 10.1002/adma.201908205.
  2. Self-assembled Monolayer Enables Hole Transport Layer-Free Organic Solar Cells with18% Efficiency and Improved Operational Stability, Y. Lin et al., ACS Energy Lett., 5, 9, 2935–2944 (2020); DOI: 10.1021/acsenergylett.0c01421.
  3. Chlorination: An Effective Strategy for High-Performance. Organic Solar Cells, Q. Zhao et al., Adv. Sci., 7, 2000509 (2020); DOI: 10.1002/advs.202000509.

To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.