PffBT4T-C9C13 (PCE12)


Order Code: M2083A1
Not in stock

Pricing

Batch Quantity Price
M2083A1 100 mg £332.00
M2083A1 250 mg £747.00
M2083A1 500 mg £1360.00
M2083A1 1 g £2430.00
M2083A1 5 - 10 g* Please enquire
*For order quantities of 5-10 grams, the lead time is 4-6 weeks.

 

General Information

Full name Poly[(5,6-difluoro-2,1,3-benzothiadiazol-4,7-diyl)-alt-(3,3’’’-di(2-nonyltridecyl)-2,2’;5’,2’’;5’’,2’’’-quaterthiophen-5,5’’’-diyl)]
Synonyms PffBT4T-C9C13, PCE12
Chemical formula (C66H97F2N2S5)n
CAS number n/a
HOMO / LUMO HOMO = -5.34 eV LUMO = -3.69 eV [1]
Solubility/processing solvents Trimethylbenzene (TMB), chlorobenzene
Classification / Family Benzothiadiazole, Fluorinated benzothiadiazole, Heterocyclic five-membered ring, Organic semiconducting materials, Low band gap polymers, Organic photovoltaics, All polymer solar cells, NFA-polymer solar cells

 Batch details

Batch number MW MN PDI Stock Info
M2083A1 123,796 73,818 1.68 In Stock
pce12, pffBT4T-C9C13
Chemical structure of PFFBT4T-C9C13 (PCE12).

 

Applications

Compared to PffBT4T-2OD (PCE11), PffBT4T-C9C13 has larger side chains which help promote better solubility and film morphology. When using PffBT4T-C9C13 as a polymer donor and PC71BM as electron acceptor (with trimethylbenzene (TMB) as host solvent), a higher device performance of 11.7% was achieved [2].

Due to its broader absorption of the solar spectrum in the visible light region (with an absorption edge at about 800 nm), PffBT4T-C9C13 is also ideal for use as a donor material for all-polymer solar cells and NFA-polymer solar cells 

Additionally, its higher solubility means that PffBT4T-C9C13 can be processed with non-halogenated solvents. There are great opportunities with this polymer for inkjet printing on an industrial scale - an environment-friendly approach for alternative renewable energy.

 

Literature and Reviews

  1. Towards a bright future: polymer solar cells with power conversion efficiencies over 10%, Z Hu et al., Sci. China Chem, 60 (5), 571-582 (2017); doi: 10.1007/s11426-016-0424-9.
  2. Efficient organic solar cells processed from hydrocarbon solvents, J. Zhao et al, Nat. Energy 1, 15027 (2016); doi:10.1038/nenergy.2015.27.

 


To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.