|Sublimed (>99.0% purity)||M681||1 g||£127.00|
|Unsublimed (>98.0% purity)||M682||5 g||£88.00|
|Sublimed (>99.0% purity)||M681||5 g||£509.00|
|Molecular weight||204.19 g/mol|
|HOMO/LUMO||LUMO = 4.5 eV|
|Classification / Family||
Electron acceptor, Hole-injection materials, Hole transport layer material, Light-emitting diodes, Polymer solar cells, OFETs.
>99.0% (sublimed)>98.0% (unsublimed)
|Melting point||289 °C (dec.)|
|Appearance||Dark yellow to brown crystals/powder|
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.
7,7,8,8-tetracyanoquinodimethane (TCNQ), with a LUMO at 4.5 eV, is known for the charge-transfer salts formed by its radical anion TCNQ in photovoltaic, light-emitting diodes, and organic field-effect transistor devices. TCNQ and its derivatives have been used as dopants, leading to an increase in hole mobility or to the lowering of injection barriers. One classic example of such is the treatment of tetrathiafulvene (TTF), an electron donor with TCNQ. TFF and TCNQ form an ion pair, the TTF-TCNQ complex. This process of doping leads to the crystallisation of the ion pair into a one-dimensionally stacked polymer. This polymer consists of segregated stacks of cations and anions of the donors and the acceptors, respectively. The complex crystal is an organic semiconductor that exhibits metallic electric conductivity [1, 2].
It also has been shown that TCNQ can effectively modify Cu or Ag surfaces. The formation of Cu-TCNQ and Ag-TCNQ enhances the work function of such electrodes and reduces the hole injection barrier dramatically. Furthermore, it improves electrode/organic layer contact, hence the reduction of contact resistances .
Tetracyanoquinodimethane (TCNQ) is also found to act as a p-type doping agent of graphene films due to its powerful electron-accepting capacity .
|Device structure||ITO/0.4 wt% F4TCNQ doped α NPD (30 nm)/ 5 wt% Ir (ppy)3 doped CBP (50 nm)/BPhen (30 nm)/20 wt% TCNQ mixed BPhen (1.5 nm)/Al |
|Luminance@15 V||1,320 cd/m2|
|Power Efficiency@14 V||56.6 lm W−1|
|Current Efficiency@14 V||23.17 cd/A|
|Device structure||ITO/F4TCNQ (3 nm)/MeO-Spiro-TPD (27 nm)/CBP + BCzVbi* (50 nm)/BPhen (10 nm)/TCNQ mixed BPhen (1.5 nm)/Al |
|Luminance@ 10 mA/cm2||1,790 cd/m2|
|Power Efficiency@ 10 mA/cm2||4.65 lm W−1|
|Current Efficiency@ 10 mA/cm2||18.0 cd/A|
*For chemical structure information, please refer to the cited references.
Literature and Reviews
- The Difference between Metallic and Insulating Salts of Tetracyanoquinodimethane (TCNQ): How to Design an Organic Metal, J. B. Torrance, Acc. Chem. Res., 12 (3), 79-86 (1979).
- Organic electronics: When TTF met TCNQ, J. R. Kirtley et al., Nat. Mater., 7, 520-521 (2008). doi:10.1038/nmat2211.
Interface Engineering: An Effective Approach toward High-Performance Organic Field-Effect
Transistors, C-A. Di et al., Acc. Chem. Res., 42 (10), 1573-1581 (2009).
Layer-by-Layer Graphene/TCNQ Stacked Films as Conducting Anodes for Organic Solar Cells,
C-L. Hsu et al., ACS. Nano., 6 (6), 5031-5039 (2012). DIO: 10.1021/nn301721q.
- Novel organic electron injection layer for efficient and stable organic light emitting diodes, R. Grover et al., J. Luminescence, 146, 53–56 (2014). http://dx.doi.org/10.1016/j.jlumin.2013.09.004.
- Light outcoupling efficiency enhancement in organic light emitting diodes using an organic scattering layer, R. Grover et al., Phys. Status Solidi RRL 8 (1), 81–85 (2014). DOI: 10.1002/pssr.201308133.
- Photoconductive response in organic charge transfer interfaces with high quantum efficiency, H. Alves et al., Nat. Commu., 4:1842 (2012). DOI: 10.1038/ncomms2890.
- Formation of an intermolecular charge-transfer compound in UHV codeposited tetramethoxypyrene and tetracyanoquinodimethane, K. Medjanik et al., Phys. Rev., 82, 245419 (2010).
To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.