PNDI(2OD)T (PCE8, high-mobility n-type polymer)


Order Code: M2087A1
Not in stock

 PNDI(2OD)T (PCE8) is now available, featuring:

  • Higher molecular weights, high purity and high solubility - PNDI(2OD)T is purified by Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere
  • Larger-quantity orders (so you can plan your experiments with polymers from the same batch) 

 

Pricing

Batch Quantity Price
M2087A1 100 mg £300.00
M2087A1 250 mg £599.00
M2087A1 500 mg £1080.00
M2087A1 1 g £1970.00

Batch details

Batch Mn Mw PDI Stock Info
M2087A1 77,791 174,105 2.23 In stock

General Information

Full name Poly [[1,​2,​3,​6,​7,​8-​hexahydro-​2,​7-​bis(2-​octyldodecyl)​-​1,​3,​6,​8-​tetraoxobenzo[lmn]​[3,​8]​phenanthroline-​4,​9-​diyl]​-​2,​5-​thiophenediyl]
Synonyms
  • PCE8
  • PNDI-T
  • P(NDI2OD-T)
  • Poly{[N,N'-bis(2-octyldodecyl)naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-2,5-thiophene}
Chemical formula (C58H86N2O4S)n
CAS number 1236111-76-4
HOMO / LUMO HOMO = -6.52 eV, LUMO = -4.04 eV [1]
Classification / Family PNDI polymers, Organic n-type semiconducting materials, PNDI polymers, Organic photovoltaics, All-Polymer solar cells (all-PSCs), Electron-acceptor polymers, OFETs, Perovskite solar cells.
Solubility Soluble in chloroform, chlorobenzene, dichlorobenzene
pndi(2od)t chemical structure, p(ndi2od-t), pndi-t, pce8
Chemical structure of PNDI(2OD)T (PCE8).

Applications

PNDI(2OD)T (also known as PCE8) is a family member of polynaphthalene diimide. It has successfully been used as an electron acceptor in highly-efficient all-polymer solar cells (all-PSCs), achieving a record performance with PCE of 8% [1].

Compared to PC71BM, PNDI(2OD)T has lower-lying HOMO and higher-lying LUMO energy levels, which could potentially lead to higher open voltages in all-PSC devices.

PNDI(2OD)T also exhibits n-channel characteristics in organic field-effect transistor (OFET) devices, with its electron mobility (μe,FET) value being up to 0.25 cm2V−1 s-1 [2].

 

Literature and Reviews

  1. 8.0% Efficient All-Polymer Solar Cells with High Photovoltage of 1.1 V and Internal Quantum Efficiency near Unity, X Xu et al.,, Adv. Energy Mater., 8, 1700908 (2018); DOI: 10.1002/aenm.201700908.
  2. Importance of Electron Transport Ability in Naphthalene Diimide-Based Polymer Acceptors for High-Performance, Additive-Free, All-Polymer Solar Cells, J. Choi et al., Chem. Mater., 27 (15), 5230–5237 (2015); DOI: 10.1021/acs.chemmater.5b01274.

 

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To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.