PNDI(2OD)T (PCE8, high-mobility n-type polymer)

Order Code: M2087A1
MSDS sheet

Price

(excluding Taxes)

£299.70


 PNDI(2OD)T (PCE8) is now available, featuring:

  • Higher molecular weights, high purity and high solubility - PNDI(2OD)T is purified by Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere
  • Larger-quantity orders (so you can plan your experiments with polymers from the same batch)

 

Pricing

Batch Quantity Price
M2087A1 100 mg £299.7
M2087A1 250 mg £599.4
M2087A1 500 mg £1083.8
M2087A1 1 g £1966.6

Batch details

Batch Mw PDI Stock Info
M2087A1 >60.000 <=3 In stock

General Information

Full name Poly[[1,​2,​3,​6,​7,​8-​hexahydro-​2,​7-​bis(2-​octyldodecyl)​-​1,​3,​6,​8-​tetraoxobenzo[lmn]​[3,​8]​phenanthroline-​4,​9-​diyl]​-​2,​5-​thiophenediyl]
Synonyms
  • PCE8
  • PNDI-T
  • P(NDI2OD-T)
  • Poly{[N,N'-bis(2-octyldodecyl)naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-2,5-thiophene}
Chemical formula (C58H86N2O4S)n
CAS number 1236111-76-4
HOMO / LUMO HOMO = -6.52 eV, LUMO = -4.04 eV [1]
Classification / Family PNDI polymers, Organic n-type semiconducting materials, PNDI polymers, Organic photovoltaics, All-Polymer solar cells (all-PSCs), Electron-acceptor polymers, OFETs, Perovskite solar cells.
Solubility Soluble in chloroform, chlorobenzene, dichlorobenzene
pndi(2od)t chemical structure, p(ndi2od-t), pndi-t, pce8
Chemical structure of PNDI(2OD)T (PCE8).

Applications

PNDI(2OD)T (also known as PCE8) is a family member of polynaphthalene diimide. It has successfully been used as an electron acceptor in highly-efficient all-polymer solar cells (all-PSCs), achieving a record performance with PCE of 8% [1].

Compared to PC71BM, PNDI(2OD)T has lower-lying HOMO and higher-lying LUMO energy levels, which could potentially lead to higher open voltages in all-PSC devices.

PNDI(2OD)T also exhibits n-channel characteristics in organic field-effect transistor (OFET) devices, with its electron mobility (μe,FET) value being up to 0.25 cm2V−1 s-1 [2].

 

Literature and Reviews

  1. 8.0% Efficient All-Polymer Solar Cells with High Photovoltage of 1.1 V and Internal Quantum Efficiency near Unity, X Xu et al.,, Adv. Energy Mater., 8, 1700908 (2018); DOI: 10.1002/aenm.201700908.
  2. Importance of Electron Transport Ability in Naphthalene Diimide-Based Polymer Acceptors for High-Performance, Additive-Free, All-Polymer Solar Cells, J. Choi et al., Chem. Mater., 27 (15), 5230–5237 (2015); DOI: 10.1021/acs.chemmater.5b01274.

 


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