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Product Code M2087A1-100mg
Price £400 ex. VAT

PCE8, electron acceptor in highly-efficient all-PSCs

High quality polymer available with free shipping on qualifying orders

Specifications | Pricing and Options | MSDS | Literature and Reviews

PNDI(2OD)T (also known as PCE8), CAS number 1236111-76-4, is a family member of polynaphthalene diimide. It has successfully been used as an electron acceptor in highly-efficient all-polymer solar cells (all-PSCs), achieving a record performance with PCE of 8% [1].

Compared to PC71BM, PNDI(2OD)T has lower-lying HOMO and higher-lying LUMO energy levels, which could potentially lead to higher open voltages in all-PSC devices.

PNDI(2OD)T also exhibits n-channel characteristics in organic field-effect transistor (OFET) devices, with its electron mobility (μe,FET) value being up to 0.25 cm2V−1 s-1 [2].

Luminosyn™ PNDI(2OD)T

Luminosyn™ PNDI(2OD)T is now available.

High molecular weight and high purity
PNDI(2OD)T is purified by Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere

Large quantity orders
Plan your experiments with confidence with polymers from the same batch

General Information

Full name Poly[[1,​2,​3,​6,​7,​8-​hexahydro-​2,​7-​bis(2-​octyldodecyl)​-​1,​3,​6,​8-​tetraoxobenzo[lmn]​[3,​8]​phenanthroline-​4,​9-​diyl]​-​2,​5-​thiophenediyl]
  • PCE8
  • PNDI-T
  • P(NDI2OD-T)
  • Poly{[N,N'-bis(2-octyldodecyl)naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-2,5-thiophene}
Chemical formula (C58H86N2O4S)n
CAS number 1236111-76-4
HOMO / LUMO HOMO = -6.52 eV, LUMO = -4.04 eV [1]
Classification / Family PNDI polymers, Organic n-type semiconducting materials, PNDI polymers, Organic photovoltaics, All-Polymer solar cells (all-PSCs), Electron-acceptor polymers, OFETs, Perovskite solar cells.
Solubility Soluble in chloroform, chlorobenzene, dichlorobenzene

Chemical Structure

Chemical structure of PNDI(2OD)T (PCE8)
Chemical structure of PNDI(2OD)T (PCE8)


Batch Quantity Price
M2087A 100 mg £400
M2087A 250 mg £800
M2087A 500 mg £1450
M2087A 1 g £2600

Batch details

Batch Mn Mw PDI Stock Info
M2087A1 77,791 174,105 2.23 In stock
M2087A2 25,298 43,113 1.70 In stock

MSDS Documentation


Literature and Reviews

  1. 8.0% Efficient All-Polymer Solar Cells with High Photovoltage of 1.1 V and Internal Quantum Efficiency near Unity, X Xu et al.,, Adv. Energy Mater., 8, 1700908 (2018); DOI: 10.1002/aenm.201700908.
  2. Importance of Electron Transport Ability in Naphthalene Diimide-Based Polymer Acceptors for High-Performance, Additive-Free, All-Polymer Solar Cells, J. Choi et al., Chem. Mater., 27 (15), 5230–5237 (2015); DOI: 10.1021/acs.chemmater.5b01274.
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